journal article·2026-05Open access

Are limited viscosity data enough to estimate the whole viscosity-temperature curves of borosilicate melts?

Rafael B. Rosante, Ricardo F. Lancelotti, Donald B. Dingwell, Edgar D. Zanotto, Luiz Pereira

Abstract

Borosilicate glasses and glass-ceramics are widely used in laboratory, optical, display, and nuclear technologies. Their viscosity–temperature relationship governs key processing steps such as melting, sintering, and crystallization. Here, viscosity–temperature data for various borosilicate compositions were compiled and analyzed using three models: Vogel–Fulcher–Tammann (VFT), Avramov–Milchev (AM), and Mauro–Yue–Ellison–Gupta–Allan (MYEGA). Statistical evaluation shows that AM and MYEGA outperform VFT in extrapolating partial datasets, with low-temperature data yielding superior predictions at higher temperatures. We also determine the infinite-temperature viscosity value for each model and identify compositions whose partial datasets successfully reproduce the full viscosity–temperature curve. A new dimensionless parameter ( φ ) is introduced to assess extrapolation reliability. Including the calorimetric glass transition temperature significantly improves the accuracy of extrapolated data. These findings provide a practical framework for optimizing viscosity experiments and predicting the complete viscosity–temperature behavior of borosilicate melts.
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Research context

OpenAlex topics: Glass properties and applications · Metallurgical Processes and Thermodynamics · Material Dynamics and Properties

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