journal article·2025-12

Non-linear elastic-plastic behavior of the invert glass lithium phosphorous oxynitride (LiPON)

S. Kalnaus, A.S. Westover, G.M. Veith, K.D. Owensby, W-Y. Tsai, T. Egami

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Abstract

Micro and nano-scale mechanical behavior of network/ionic glasses is dictated by their composition and the number of constraints per structural unit. From this perspective, the glass LiPON presents the opportunity for enhancement of the microscale ductility due to its rather unconstrained orthophosphate structure. We use instrumented nanoindentation with different tip geometries to investigate the mechanical response of LiPON glass. The results reveal that the elastic modulus of LiPON is not constant and depends on pressure. With the method utilizing spherical nanoindentation and continuous stiffness measurement (CSM) we determine the yield point of LiPON. We propose the Drucker-Prager type of yield criterion for LiPON and estimate its yield stress in compression as 2.4 GPa. There exists another stress threshold, however, around 490 MPa, at which the elastic deformation becomes non-linear, and this can be mistaken for the yield stress.
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Research context

OpenAlex topics: Glass properties and applications · Phase-change materials and chalcogenides · Ferroelectric and Piezoelectric Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (54)

Show source-provided references
1. Plastic flow in glass, Proceedings of the Royal Society of London, Series A
2. Indentation of glasses10.1016/j.pmatsci.2021.100834 ↗
3. The atomic arrangement in glass10.1021/ja01349a006 ↗
4. Ionic glasses: structure, properties and classification
5. The structure of CaO-Na2O-MgO-P2O5 invert glass10.1016/S0022-3093(01)00912-7 ↗
6. Effect of TiO2 addition on structure, solubility, and crystallisation of phosphate invert glasses for biomedical applications10.1016/j.jnoncrysol.2010.03.022 ↗
7. Mixed alkaline earth effect on nanomechanical properties of glass10.1016/j.jnoncrysol.2023.122808 ↗
8. Multicomponent phosphate invert glasses with improved processing10.1016/j.jnoncrysol.2012.04.027 ↗
9. Fabrication and characterization of amorphous lithium electrolyte thin films and rechargeable thin-film batteries
10. A stable thin-film lithium electrolyte: lithium phosphorus oxynitride10.1149/1.1837443 ↗
11. Structural and compositional factors that control the Li-ion conductivity in LiPON electrolytes10.1021/acs.chemmater.8b02812 ↗
12. A geometrical approach to the structure of liquids10.1038/183141a0 ↗
13. LiPON and NaPON glasses: a study of the ammonolysis of lithium and sodium metaphosphate melts10.1111/ijag.13508 ↗
14. Structure-mechanical properties correlation in bulk LiPON glass produced by nitridation of metaphosphate melts
15. Prediction of glass hardness using temperature-dependent constraint theory10.1103/PhysRevLett.105.115503 ↗
16. Compositional effects on the properties of high nitrogen alkaline-earth silicon oxynitride glasses, AE=Mg, Ca, Sr, Ba10.1016/j.jeurceramsoc.2010.11.005 ↗
17. Toward glasses with better indentation cracking resistance10.1016/j.crme.2013.10.008 ↗
18. Mechanical characterization of LiPON films using nanoindentation10.1016/j.tsf.2011.07.068 ↗
19. Resistance to fracture in the glassy solid electrolyte Lipon10.1557/s43578-020-00098-x ↗
20. Thermo-mechanical characterization and stress engineering of LiPON solid electrolyte
21. D. Tabor, The hardness of metals. Oxford University Press, Oxford, UK, 1951.
22. Room temperature viscous flow of amorphous silica induced by electron beam irradiation
23. Measurement of hardness and elastic modulus by instrumented indentation: advances in understanding and refinements to methodology10.1557/jmr.2004.19.1.3 ↗
24. Calculation of elastic constants of bulk metallic glasses from indentation tests10.1016/j.jmrt.2024.01.046 ↗
25. Determination of hardness to elastic modulus ratios using Knoop indentation measurements and a model based on loading and reloading half-cycles10.1007/BF01114301 ↗
26. Glass transition in metallic glasses: a microscopic model of topological fluctuations in the bonding network10.1103/PhysRevB.76.024203 ↗
27. Elastic properties and short-to-medium range order in glasses10.1111/j.1551-2916.2007.01945.x ↗
28. Structure of vitreous P2O5 and alkali phosphate glasses
29. Complete elastic characterization of lithium phosphorous oxynitride films using picosecond ultrasonics10.1016/j.tsf.2013.08.080 ↗
30. Elastic properties and surface damage resistance of nitrogen-rich (Ca,Sr)-Si-ON glasses10.1016/j.jnoncrysol.2010.07.043 ↗
31. Elastic properties and hardness of mixed alkaline earth silicate oxynitride glasses10.3390/ma15145022 ↗
32. Spherical indentation and implementation of S3/P for yield stress determination of brittle materials10.1016/j.jmps.2024.105645 ↗
33. Finite elastic strain of cubic crystals10.1103/PhysRev.71.809 ↗
34. On the measurement of stress-strain curves by spherical indentation
35. Local deformation of glasses is mediated by rigidity fluctuations on nanometer scale10.1002/advs.201800916 ↗
36. The Drucker-Prager criterion-based plasticity theory of amorphous alloys under the complex stress states10.1016/j.jnoncrysol.2023.122453 ↗
37. Yielding and intrinsic plasticity of Ti-Zr-Ni-Cu-Be bulk metallic glass10.1016/j.ijplas.2008.11.002 ↗
38. Spherical indentation response of metallic glasses10.1016/j.actamat.2004.03.028 ↗
39. Plastic response of amorphous silicates, from atomistic simulations to experiments – a general constitutive relation10.1016/j.mechmat.2017.07.002 ↗
40. Evaluation of hardness-yield strength relationships for bulk metallic glasses10.1080/09500830600788935 ↗
41. Soil mechanics and plastic analysis or limit design10.1090/qam/48291 ↗
42. Oxynitride glasses: areview10.1016/j.bsecv.2016.09.004 ↗
43. S. Kalnaus, G. Yang, E. Herbert, A. Westover, Unveiling the structural transformations in glassy solid electrolyte adapted to high-stress cycles, Material. Today https://doi.org/10.1016/j.mattod.2025.03.023.10.1016/j.mattod.2025.03.023 ↗
44. Knoop hardness-apparent yield stress relationship in ceramics10.1111/j.1744-7402.2011.02686.x ↗
45. Shear deformation of glassy metals: breakdown of cauchy relationship and anelasticity10.1016/0022-3093(85)90242-X ↗
46. How thermally activated deformation starts in metallic glas10.1038/ncomms6083 ↗
47. Revealing the ultra-low-temperature relaxation peak in a model metallic glass10.1016/j.actamat.2020.05.067 ↗
48. Ripples in the bottom of the potential energy landscape of metallic glass10.1038/s41467-024-45640-1 ↗
49. Ductile bulk metallic glass10.1103/PhysRevLett.93.255506 ↗
50. Crossover from localized to cascade relaxations in metallic glasses10.1103/PhysRevLett.115.045501 ↗
51. Curie-Weiss behavior of liquid structure and ideal glass state
52. Nonaffine strains control ductility of metallic glasses10.1103/PhysRevLett.128.155501 ↗
53. Westover · Chem. Mater. · 2023 · 35 · 273010.1021/acs.chemmater.2c02380 ↗
54. Metallic glasses: elastically stiff yet flowing at any stress10.1016/j.mattod.2024.11.015 ↗