Decontamination of Mustard Gas with Processable Dry Reactive Polymers via Oxidation–Chlorination
Source abstract
Abstract
In this study, an N-chloramide-modified reactive copolymer, chlorinated poly (4-vinylbenzenesulfonamide-co-methyl methacrylate) (PVMCl), was designed and synthesized for rapid and efficient detoxification of sulfur mustard (HD, 2-bis(2-chloroethyl) sulfide) under ambient conditions. The detoxification rate of HD was up to 95% in 1 h, and HD was decomposed completely within 5 h by PVMCl both in aqueous solution and solid phase. The product characterization revealed the essential role of surface N-chloramide groups for the selective oxidation of HD. Furthermore, the self-decontamination nonwoven mat was successfully fabricated by electrospinning, which showed a satisfactory decontamination rate and long-term effect against HD.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Pesticide Exposure and Toxicity · Toxic Organic Pollutants Impact · Flame retardant materials and properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
State Key Laboratory of NBC Protection for Civilian, Beijing 102205, P. R. China
Research Institute of Chemical Defense, Beijing 102205, P. R. China
School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, P. R. China
Funding
National Natural Science Foundation of China
References (59)
Show source-provided references
1. 10.1021/acs.chemrev.5b0040210.1021/acs.chemrev.5b00402 ↗
2. 10.1016/j.tox.2005.06.01110.1016/j.tox.2005.06.011 ↗
3. 10.1039/B705025A10.1039/B705025A ↗
4. 10.1016/j.ijpharm.2020.11937310.1016/j.ijpharm.2020.119373 ↗
5. 10.1016/j.envpol.2018.12.03610.1016/j.envpol.2018.12.036 ↗
6. 10.3390/molecules2603069210.3390/molecules26030692 ↗
7. 10.1021/acscatal.9b0187710.1021/acscatal.9b01877 ↗
8. 10.1002/biot.20060016610.1002/biot.200600166 ↗
9. 10.1016/bs.mie.2020.04.07210.1016/bs.mie.2020.04.072 ↗
10. 10.1002/anie.20170274410.1002/anie.201702744 ↗
11. 10.1021/acs.inorgchem.8b0010610.1021/acs.inorgchem.8b00106 ↗
12. 10.1016/j.apcatb.2020.11970310.1016/j.apcatb.2020.119703 ↗
13. 10.1021/acs.chemmater.0c0316010.1021/acs.chemmater.0c03160 ↗
14. 10.1039/C6RA23826B10.1039/C6RA23826B ↗
15. 10.1021/acsami.0c0004210.1021/acsami.0c00042 ↗
16. 10.1039/c2jm16605d10.1039/c2jm16605d ↗
17. 10.1007/s10853-008-3114-z10.1007/s10853-008-3114-z ↗
18. 10.1039/C7RA01278K10.1039/C7RA01278K ↗
19. 10.1039/b412803f10.1039/b412803f ↗
20. 10.1002/app.2425810.1002/app.24258 ↗
21. 10.1021/jacs.9b0730110.1021/jacs.9b07301 ↗
22. 10.1039/C8OB02475H10.1039/C8OB02475H ↗
23. 10.1039/C9CP05109K10.1039/C9CP05109K ↗
24. 10.1016/j.snb.2021.12980410.1016/j.snb.2021.129804 ↗
25. 10.1111/j.1751-1097.2011.01052.x10.1111/j.1751-1097.2011.01052.x ↗
26. 10.1016/j.jhazmat.2012.05.00710.1016/j.jhazmat.2012.05.007 ↗
27. 10.1002/marc.20180019410.1002/marc.201800194 ↗
28. 10.1021/acsami.6b0524110.1021/acsami.6b05241 ↗
29. 10.1016/j.biomaterials.2010.02.00410.1016/j.biomaterials.2010.02.004 ↗
30. 10.1016/j.taap.2004.03.01310.1016/j.taap.2004.03.013 ↗
31. 10.1016/j.tox.2009.01.01910.1016/j.tox.2009.01.019 ↗
32. 10.1021/acsami.8b0457610.1021/acsami.8b04576 ↗
33. 10.1021/jo01176a00710.1021/jo01176a007 ↗
34. 10.1021/jo00249a02910.1021/jo00249a029 ↗
35. 10.1021/cr00016a00310.1021/cr00016a003 ↗
36. 10.1016/j.polymer.2018.01.06610.1016/j.polymer.2018.01.066 ↗
37. 10.1021/acsanm.9b0217610.1021/acsanm.9b02176 ↗
38. 10.1021/la010334h10.1021/la010334h ↗
39. 10.1080/1042650070124710210.1080/10426500701247102 ↗
40. 10.1021/acsapm.0c0065110.1021/acsapm.0c00651 ↗
41. 10.1016/j.mtadv.2020.10008510.1016/j.mtadv.2020.100085 ↗
42. 10.1039/C9CY00094A10.1039/C9CY00094A ↗
43. 10.1021/acs.inorgchem.0c0289010.1021/acs.inorgchem.0c02890 ↗
44. 10.1021/ie030846m10.1021/ie030846m ↗
45. 10.1021/ie800790210.1021/ie8007902 ↗
46. 10.1021/ie060253m10.1021/ie060253m ↗
47. 10.1021/acsami.7b0705510.1021/acsami.7b07055 ↗
48. 10.1021/acsami.7b0549410.1021/acsami.7b05494 ↗
49. 10.1021/acs.inorgchem.1c0005310.1021/acs.inorgchem.1c00053 ↗
50. 10.1021/am100018k10.1021/am100018k ↗
51. 10.1039/C7NJ00525C10.1039/C7NJ00525C ↗
52. 10.1055/s-0029-121688910.1055/s-0029-1216889 ↗
53. 10.1039/C5RA27178A10.1039/C5RA27178A ↗
54. 10.1016/j.poly.2007.03.00510.1016/j.poly.2007.03.005 ↗
55. 10.1016/j.molstruc.2020.12968010.1016/j.molstruc.2020.129680 ↗
56. 10.1021/ie801150y10.1021/ie801150y ↗
57. 10.1021/jp302887910.1021/jp3028879 ↗
58. 10.1002/app.2708110.1002/app.27081 ↗
59. 10.1021/acs.jpcb.0c0932210.1021/acs.jpcb.0c09322 ↗