journal article·2000-05

Hydroxyl groups in phosphosilicate glasses for fibre optics

V.G. Plotnichenko, V.O. Sokolov, E.B. Kryukova, E.M. Dianov

Journal of Non-Crystalline Solids· Volume 270· Issue 1-3
Publisher page

Abstract

Abstract IR absorption spectra of phosphosilicate glasses containing 1–19 mol% of P2O5 are measured and analyzed. Interaction of hydroxyl groups with the phosphorus centres in the phosphosilicate glass is investigated in cluster models using PM3 and MNDO quantum-chemical methods. An explanation of the experimentally observed change of vibrational absorption bands caused by the hydroxyl groups is proposed.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Glass properties and applications · Luminescence Properties of Advanced Materials · Crystal Structures and Properties

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