Synthesis optimization of guest/host poly(styrene sulphonate) doped neodymium (III) films
Source abstract
Abstract
Abstract In the present paper, we optimize the chemical synthesis of guest/host poly(styrene sulphonate) (PSS) doped with neodymium ions (Nd 3 + ) using chemometric and univariate procedure for volume variables of acid form of PSS and neodymium chloride (NdCl 3 ) confirmed by FTIR experiment. In optimization procedure, the exchange counter-ions H + by Nd 3 + increases, substantially, the luminescence quantum yield, up to 75%, to 4 F 3/2 → 4 I 11/2 transition of Nd 3 + . Results show the possibility of using the present material as an efficient optical emission material, in the near infrared range, by adding polymer mechanical properties.
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Research context
OpenAlex topics: Luminescence Properties of Advanced Materials · Lanthanide and Transition Metal Complexes · Silicone and Siloxane Chemistry
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