journal article·2009-10Open access

Photoconductive organic materials based on N-vinylcarbazole copolymers with higher alkenes as recording media in photonics

Stefan Robu, Dmitri Mitcov, Galina Dragalina, Agnes Rivaton, Benedicte Mailhot, Michele Bolte, Igor Dementiev, Ion Andrieş

Journal of Non-Crystalline Solids· Volume 355· Issue 37-42

Abstract

With the purpose to obtain novel photoconductive organic materials with improved complex of physical–mechanical properties and high sensitivity value, the possibility of N-vinylcarbazole copolymerization with higher alkenes was studied. The deposited films were 1.0–2.0 pm thin after drying in vacuum. The photosensitivity of the copolymer films is one order of magnitude greater than other carbazole containing copolymers. The investigation of spectral sensitivity was realized. Photosensitivity reaches its maximal value in 400–800 nm wave band. A photothermoplastic information registration medium was developed using synthesized copolymers. On the prepared photothermoplastic film, were recorded diffraction gratings with diffractional efficiency of 8–10% and resolution of 1000 mm−1, using electrophotographic method. Photographical sensitivity of obtained films allows real time (1–3 s) photographical and holographic image recording.
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Research context

OpenAlex topics: Photochromic and Fluorescence Chemistry · Photonic and Optical Devices · Photonic Crystals and Applications

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