Dynamics of orientationally disordered mixed crystal sharing Cl-adamantane and CN-adamantane
Source abstract
Abstract
Orientationally disordered (OD) mixed crystals formed between cyanoadamantane (CN-A) and chloroadamantane (Cl-A) have been thermodynamically characterized by means of thermal analysis and X-ray diffraction. The dynamics of these OD mixed crystals has been studied by means of broad band dielectric spectroscopy. Results evidence that dynamics of the α-relaxation process associated with the overall molecular tumbling slows down when molecules of CN-A are substituted by molecules of Cl-A.
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Research context
OpenAlex topics: Thermodynamic properties of mixtures · Chemical Thermodynamics and Molecular Structure · Phase Equilibria and Thermodynamics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (37)
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