Eu3+ ion distribution in oxyfluoride glass nanocomposites
Source abstract
Abstract
Abstract Assessment of activator distribution in lanthanide doped nanocomposites is an important and challenging task. Oxyfluoride glass ceramics have been chosen as a model system to characterize incorporation efficiency of Eu3+ ions in CaF2 nanocrystals using a combination of X-ray diffraction (XRD) and electron paramagnetic resonance (EPR) techniques. Lattice constant changes induced by size mismatch of Eu3+ and Ca2+ ions have been used to evaluate Eu3+ content in CaF2. The distortion of CaF2 lattice due to incorporation of europium ions can be detected from EPR investigations via Gd3+ paramagnetic probe spectra. It is shown that ratio of different symmetry CaF2:Gd3+ centres and linewidth of EPR transitions can be used to monitor europium content in the crystalline phase of glass ceramics.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Luminescence Properties of Advanced Materials · Lanthanide and Transition Metal Complexes · Glass properties and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (62)
Show source-provided references
1. Luminescence of Eu3+ activated CaF2 and SrF2 nanoparticles: effect of the particle size and co-doping with alkaline ions10.1021/acs.cgd.7b01050 ↗
2. Electrical conduction in CaF2 and CaF2-Al2O3 nanocomposite films on Al2O3 substrates10.1063/1.354657 ↗
3. Assembly of shell/core CDs@CaF2 nanocomposites to endow polymer with multifunctional properties10.1088/1361-6528/aafcd4 ↗
4. Optical properties of a transparent CaF2:Er3+ fluoropolymer nanocomposite10.1063/1.1947891 ↗
5. Preparation and luminescent properties of CaF2:Ln3+ (Ln:Er, Er/Yb)/Nafion composite films10.1016/j.jre.2018.05.020 ↗
6. Cooperative luminescence mediated near infrared photocatalysis of CaF2:Yb@BiVO4 composites10.1016/j.apcatb.2016.12.027 ↗
7. Morphology and photoluminescence properties of Er3+-doped CaF2 nanocrystals patterned by laser irradiation in oxyfluoride glasses10.1016/j.jfluchem.2012.10.007 ↗
8. Transparent oxyfluoride glass ceramics10.1016/j.jfluchem.2015.01.009 ↗
9. Nanofluorides10.1016/j.jfluchem.2011.06.025 ↗
10. A neutron scintillator based on transparent nanocrystalline CaF2:Eu glass ceramic10.1063/1.4945999 ↗
11. Eu2+ ions and CaF2 -containing transparent glass-ceramics10.1016/S0025-5408(02)00862-0 ↗
12. Europium doped transparent glass ceramics containing CaF2 micron-sized crystals: structural and optical characterization10.1039/C6RA10288C ↗
13. Local vibration around rare earth ions in alkaline earth fluorosilicate transparent glass and glass ceramics using Eu3+ probe10.1016/S1002-0721(09)60026-0 ↗
14. Time-resolved luminescence study of CaF2:Eu2+ nanocrystals in glass-ceramics10.1016/j.jlumin.2004.09.017 ↗
15. Crystallization and spectroscopic properties of Eu-doped CaF2 nanocrystals in transparent oxyfluoride glass-ceramics10.1016/j.jnoncrysol.2009.04.062 ↗
16. Eu3+-doped CaF2 nanocrystals in sol–gel derived glass–ceramics10.1016/j.optmat.2010.11.016 ↗
17. Spectroscopic ellipsometry investigations of Eu-doped oxy-fluoride glass and glass-ceramics10.1016/j.optmat.2012.03.015 ↗
18. Preparation and luminescence properties of Eu3+ doped oxyfluoride borosilicate glass ceramics10.1016/S1002-0721(12)60204-X ↗
19. New transparent glass – ceramics containing large grain Eu3+:CaF2 nanocrystals10.1016/j.matlet.2012.01.016 ↗
20. Preparation of transparent oxyfluoroborate glass-ceramics containing CaF2〈Eu〉 crystals10.1134/S0020168513100026 ↗
21. Structural characterization and temperature-dependent luminescence of CaF2:Tb3+/Eu3+ glass ceramics10.1016/S1002-0721(17)60945-1 ↗
22. Composition dependence of the optical and structural properties of Eu-doped oxyfluoride glasses10.1016/j.jallcom.2015.01.207 ↗
23. Ordering of fluorite-type phases in erbium-doped oxyfluoride glass ceramics10.1016/j.jeurceramsoc.2017.08.037 ↗
24. Spectroscopic properties of Er3+ and Yb3+ co-doped glass ceramics containing SrF2 nanocrystals10.1088/0022-3727/42/5/055103 ↗
25. Intense ultraviolet upconversion luminescence of Yb3+ and Tb3+ co-doped glass ceramics containing SrF2 nanocrystals10.1016/j.jlumin.2011.05.012 ↗
26. Cubic and rhombohedral Ba4Lu3F17:Er3+ in transparent glass ceramics: crystallization and upconversion luminescence10.1016/j.jlumin.2018.04.016 ↗
27. Scherrer after sixty years: a survey and some new results in the determination of crystallite size10.1107/S0021889878012844 ↗
28. Indexing of powder diffraction patterns for low-symmetry lattices by the successive dichotomy method10.1107/S0021889891006441 ↗
29. Powder pattern indexing and the dichotomy algorithm10.1524/zksu.2007.2007.suppl_26.191 ↗
30. EasySpin, a comprehensive software package for spectral simulation and analysis in EPR10.1016/j.jmr.2005.08.013 ↗
31. The effect of fluorine anions on the luminescent properties of Eu-doped oxyfluoride aluminosilicate glasses10.1111/j.1551-2916.2010.04067.x ↗
32. Electron paramagnetic resonance and photoluminescence investigation of europium local structure in oxyfluoride glass ceramics containing SrF2 nanocrystals10.1016/j.optmat.2017.07.024 ↗
33. Ultraviolet-to-visible luminescent conversion in CaF2:Eu2+ and SrF2:Eu2+ crystals10.1149/1.2097035 ↗
34. Triboluminescence of fluorites10.1088/0022-3719/16/28/021 ↗
35. Interpretation of europium(III) spectra10.1016/j.ccr.2015.02.015 ↗
36. Defect chemistry in CaF2:Eu3+10.1063/1.443882 ↗
37. Phase diagrams of the CaF2-(Y,Ln) F3 systems II. A discussion10.1016/0022-5088(79)90206-6 ↗
38. Association of point defects in non-stoichiometric M1-xRxF2+x fluorite-type solid solutions
39. Laser spectroscopic measurement of point-defect dynamics in Eu3+:CaF210.1103/PhysRevB.41.10799 ↗
40. Localized fluoride diffusion and defect equilibrium in CaF2:Eu3+ using site-selective spectroscopy and high-pressure techniques10.1103/PhysRevB.53.14135 ↗
41. Polarized laser selective excitation and Zeeman infrared absorption of C4v and C3v symmetry centers in Eu3+-doped CaF2, SrF2 and BaF2 crystals10.1103/PhysRevB.64.035102 ↗
42. Vegard’s law10.1103/PhysRevA.43.3161 ↗
43. Concentration dependence of unit-cell parameters of phases M1− xRxF2+x with the fluorite structure
44. Darstellung und Eigenschaften der festen Lösungen (Ca,SE)F2,33 mit SE = Y, La, Ln und der korrespondierenden Ordnungsphasen Ca2SEF7 mit SE = Er – Lu und Y
45. A survey of the EPR spectra of Gd3+ in single crystals10.1002/pssa.2210120202 ↗
46. Electron paramagnetic resonance and magnetic circular dichroism of Gd3+ ions in oxyfluoride glass–ceramics containing CaF2 nanocrystals10.1016/j.jnoncrysol.2015.08.036 ↗
47. Effect of a Ce3+ Codopant on the Gd3+ EPR Spectrum of SrF2 at room temperature10.1063/1.1678385 ↗
48. Paramagnetic centers and dipolar defects in CaF2:Gd3+ and CaF2:Gd3++Lu3+10.1103/PhysRevB.46.11415 ↗
49. Defect structure and defect-defect interactions in solid solutions of AF2 and RF3 doped with Gd3+ probes10.1103/PhysRevB.27.20 ↗
50. Pulsed EPR spectroscopy of Gd3+ centers in Ca1-xRxF2+x (R=La, Y) mixed crystals10.1007/BF03162203 ↗
51. Defect structure and charge transport in solid solutions Ba1-xLaxF2+x10.1103/PhysRevB.28.6031 ↗
52. Electron paramagnetic resonance and luminescence of Gd3+ in the mixed fluorides Ca1-xLaxF2+x and Ca1-xYxF2+x10.1080/10420159108224883 ↗
53. Clustering of Y3+ in BaF2 using Gd3+ as paramagnetic probes10.1016/0167-2738(90)90233-H ↗
54. Local structure of gadolinium in oxyfluoride glass matrices containing SrF2 and BaF2 crystallites10.1016/j.jnoncrysol.2016.07.015 ↗
55. Crystalline phase detection in glass ceramics by EPR spectroscopy10.1063/1.5030462 ↗
56. The EPR spectra of Gd3+ and Eu2+ in glassy systems10.1063/1.449041 ↗
57. The local field distribution of Gd3+ in transition metal fluoride glasses investigated by electron paramagnetic resonance10.1088/0953-8984/8/23/023 ↗
58. Al’tshulter · 1974
59. Multisite formation in gadolinium doped SrF2 nanoparticles10.1016/j.jallcom.2018.05.283 ↗
60. Electron paramagnetic resonance of transition ions
61. Weil · 2007
62. Electron paramagnetic resonance of Gd3+ ions in powders of LaF3:Gd3+ nanocrystals10.1134/S0021364014030084 ↗