Structure of amorphous NaCl–glucose system studied by X-ray diffraction and IR methods

Abstract X-ray diffraction and diffuse reflection IR spectroscopic measurements have been carried out on amorphous NaCl–glucose mixtures, a-(NaCl)x(glucose)1−x, with x = 0, 0.05, 0.1 and 0.15, in order to obtain structural information on the intermolecular hydrogen-bonded interaction between glucose molecules affected by the presence of NaCl. The difference distribution function Δginter(r) was derived from the Fourier transform of the difference intermolecular interference term Δiinter(Q) between X-ray intermolecular interference terms observed from amorphous NaCl-glucose and pure glucose samples. A negative peak appears at r ≈ 2.5 A in the Δginter(r) observed for the 10 mol% NaCl sample, while, the Δginter(r) for the 15 mol% NaCl sample does not show pronounced negative peak. On the other hand, the IR spectra for the O–H stretching region (2300 ⩽ ν ⩽ 3800 cm−1) indicate that hydrogen bonds between glucose molecules are significantly collapsed in the samples containing 5–15 mol% NaCl. These results imply that the contribution from the Na+⋯Cl− contact ion pair is dominated in the 15 mol% NaCl sample.