journal article·2001-09

Free volumes in UV-cured polymers based on acrylate oligomers

M. Hyla, J. Filipecki, J. Świątek, R.I. Mervinskii, L.A. Gudzowska, V. Savitsky

Journal of Non-Crystalline Solids· Volume 290· Issue 1
Publisher page

Abstract

Abstract Polymerization in polymers based on acrylate oligomers was caused by exposure to ultraviolet light. Polymer specimens with different ultraviolet light exposure times have been investigated by positron annihilation lifetime spectroscopy (PALS). The longest lifetime, τ 3 , in observed lifetime spectra for positrons was associated with the pick-off annihilation of ortho -positronium ( o -Ps) trapped by free volume in the structure. The aim of this paper was to investigate the influence of the time of UV exposure on free volume sizes in two different polymers based on acrylate oligomers. UV exposure time influences the free volume size: longer time reduces it. The concentration of the free volumes is independent of UV exposure time.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Muon and positron interactions and applications · Copper Interconnects and Reliability · Synthesis and characterization of novel inorganic/organometallic compounds

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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