Application of confocal laser scanning microscopy to investigation of micro crystals in transparent amorphous media: Photoluminescence tomography and spectroscopy of CdZnSSe crystallites in historical silicate glass
Source abstract
Abstract
This article presents the use of the tomography to investigate luminescent micro inclusions in transparent amorphous media such as silicate glass. Studies of CdZnSSe crystals synthesized in a silicate glass melt have been carried out using the tomography with both two-photon and single-photon excitation of luminescence. Zn-rich glass manufactured in the 19th century has been found to contain micron-sized crystals of CdξZn1−ξSζSe1−ζ (ξ ≈ 0.5, ζ ≈ 0.5) of hexagonal crystal system exhibiting intense photoluminescence. The photoluminescence band of these crystals has been found to peak at about 2.1 eV at 300 K. Minor shifts in the maximum of bands and changes in their shape in individual crystals or at tomogram points are associated with variations in their composition. Changes in the photoluminescence band shape and maximum due to the excitation of luminescence in CdZnSSe crystallites by laser radiation of different energies have also been observed in this study.
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Research context
OpenAlex topics: Cultural Heritage Materials Analysis · Mineralogy and Gemology Studies · Conservation Techniques and Studies
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