journal article·2016-12

Migration behavior of alkali and alkaline-earth cations in soda-lime silicate glass surface by electrical nanoimprint

Sadatatsu Ikeda, Keiichiro Uraji, Toshio Suzuki, Kiyoshi Yamamoto, Junji Nishii

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Abstract

Abstract One dimensional pattern of 500 nm period was formed on a soda-lime silicate glass by the electrical nanoimprint below the glass transition temperature. The imprinted glass surface was analyzed using a transmission electron microscopy and an energy-dispersive X-ray spectroscopy with the cryogenic system. The concentrated parabolic layers of Ca 2 + and Mg 2 + were formed separately in the Na + deficient layer. The deficient area both of such alkali and alkaline-earth cations was preferentially removed in an alkali etchant, resulting the enhancement of the aspect ratio of the one-dimensional relief pattern. Therefore, the distribution control of alkaline-earth cations was important for the fabrication of sub-micron scale patterns with high aspect ratio on the glass surface.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Photonic Crystals and Applications · Glass properties and applications · Surface Roughness and Optical Measurements

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. Large second-order nonlinearity in poled fused silica10.1364/OL.16.001732 ↗
2. Thermally poled glass: frozen-in electric field or oriented dipoles?10.1016/0030-4018(94)90260-7 ↗
3. Effect of poling temperature on optical second-harmonic intensity of lithium sodium tellurite glass10.1111/j.1151-2916.1998.tb02688.x ↗
4. Model of charge migration during thermal poling in silica glasses: evidence of a voltage threshold for the onset of a second-order nonlinearity10.1103/PhysRevA.65.043816 ↗
5. Large second-harmonic generation of thermally poled sodium borophosphate glasses10.1364/OPEX.13.004064 ↗
6. Formation of silver nanoparticles under anodic surface of tellurite glass via thermal poling-assisted ion implantation across solid-solid interface10.1063/1.2770829 ↗
7. Surface modification of tellurite glass by thermal poling accompanied with ion implantation in a solid-state phase
8. How does thermal poling affect the structure of soda-lime glass?10.1021/jp1033905 ↗
9. Enhancement of optical birefringence in tellurite glasses containing silver nanoparticles induced via thermal poling10.1016/j.jnoncrysol.2010.11.089 ↗
10. Poling-assisted fabrication of plasmonic nanocomposite devices in glass10.1002/adma.201001222 ↗
11. Electrostatic imprint process for glass10.1143/APEX.1.024003 ↗
12. Surface patterning of glass via electrostatic imprinting using a platinum mold10.1166/jnn.2012.5608 ↗
13. Fine pattern fabrication on glass surface by imprint lithography10.1016/S0167-9317(03)00077-7 ↗
14. Nanoimprint of glass materials with glassy carbon molds fabricated by focused-ion-beam etching10.1143/JJAP.44.5600 ↗
15. Imprinted optical pattern of low-softening phosphate glass10.1364/OL.32.002750 ↗
16. Antireflective structure imprinted on the surface of optical glass by SiC mold10.1016/j.apsusc.2008.11.020 ↗
17. Low-temperature fabrication of fine structures on glass using electrical nanoimprint and chemical etching10.1063/1.4819321 ↗
18. Electron-probe microanalysis of alkali metals in glasses10.1063/1.1657825 ↗
19. Changes in composition during electron micro-probe analysis of K2O-SrO-SiO2 glass10.1063/1.1708778 ↗
20. Oxygen outgassing caused by electron bombardment of glass10.1063/1.1702680 ↗
21. Characterization of intra-cellular ionic concentrations of monocytes in contact with bioactive glasses and hydroxyapatite particles. A TEM Cryo-X-ray analysis of diffusible ions10.1081/CI-200029800 ↗
22. Cryo-X-ray analysis-a novel tool to better understand the physicochemical reactions at the bioglass/biological fluid interface10.1002/jemt.20617 ↗
23. Electric field distribution and near-surface modifications in soda-lime glass submitted to a dc potential10.1016/0022-3093(93)90224-L ↗
24. Bleaching versus poling: comparison of electric field induced phenomena in glasses and glass-metal nanocomposites10.1063/1.3511746 ↗
25. Polarization of glass containing fast and slow ions10.1063/1.4742975 ↗
26. The effect of diffusion processes on the interaction in multicomponent silicate systems10.3103/S1063457608020056 ↗
27. How does thermal poling produce interstitial molecular oxygen in silicate glasses?10.1021/acs.jpcc.5b04513 ↗
28. Nanoprofiling of alkali-silicate glasses by thermal poling10.1016/j.jnoncrysol.2014.11.007 ↗
29. Trapped molecular and ionic species in poled borosilicate glasses: toward a rationalized description of thermal poling in glasses10.1021/jp4101015 ↗
30. Submicron-resolved relief formation in poled glasses and glass–metal nanocomposites10.1134/S1063785008120122 ↗