Non-ergodicity in a locally ordered fragile glass former

We measure the dynamic structure factor of m-toluidine through inelastic X-ray scattering in the mesoscopic Q range between 1 and 10 nm(-1), where the static structure factor exhibits a prepeak resulting from a molecular spatial organization in nanometer size clusters, due to the formation of hydrogen bonds. We present experimental evidence of the square-root cusp in the temperature behavior of the non-ergodicity factor of in-toluidine which supports the view that the mode-coupling theory succeeds in describing the dynamics of supercooled molecular liquids, even for liquids with a local order, notwithstanding the cage formation is controlled by a mechanism different from the packing constraints typical of simple liquids. Moreover, we report on the behavior of the non-ergodicity factor in the low-temperature and wavevector regimes, finding a confirmation of the phenomenologic law proposed by Scopigno et al. [T. Scopigno, G. Ruocco, F. Sette; G. Monaco, Science 302 (2003) 849] which correlates the vibrational dynamics of the glass to the fragility of the supercooled liquid. (c) 2006 Published by Elsevier B.V.