journal article·2022-05

Tailoring metalloid elements in Fe-C-P-B amorphous/nanocrystalline alloys with high saturated magnetization and heat-treatable bending ductility

Zhiguang Shi, Xuan Li, Ruijun Cao, Xingcheng Xie, Kaishen Li, Zhongkun Lin, Jian Yang, Tao Zhang

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Abstract

A family of Fe-C-P-B amorphous alloys with high Fe containing, high saturated magnetization and consistent bending ductility even enduring high-temperature annealing at near crystallization temperature ( T x) was fabricated. The effects of the tunable concentration of metalloid elements on the glass forming range, thermal properties, soft magnetic properties and bending ductility were ascertained in the quaternary model system. For the Fe-C-P-B system, B addition is beneficial for glass formation with high Fe content (up to 87 at.% Fe for Fe 87C 2P 2B 9), C addition can improve the saturated magnetization (up to 1.67 T for Fe 82C 14P 2B 2), and P addition is beneficial for reducing the coercivity (low to 5.6 A/m for Fe 85C 2P 11B 2). Meanwhile, the optimal amorphous alloys can maintain good bending ductility even after annealing treatment close to sub- T x. The results related with the optimal tailoring of metalloid element are significant for materials design with good soft magnetic and mechanical properties in Fe-based amorphous alloys.
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Research context

OpenAlex topics: Metallic Glasses and Amorphous Alloys · Magnetic properties of thin films · Magnetic Properties of Alloys

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (39)

Show source-provided references
1. New Fe-based soft magnetic alloys composed of ultrafine grain structure10.1063/1.342149 ↗
2. Amorphous and nanocrystalline materials for applications as soft magnets10.1016/S0079-6425(99)00002-X ↗
3. Ternary Fe–P–C bulk amorphous alloys with good soft-magnetic and mechanical properties10.1016/j.scriptamat.2011.06.020 ↗
4. Fe content dependence of magnetic properties and bending ductility of FeSiBPC amorphous alloy ribbons10.1016/j.jallcom.2016.10.107 ↗
5. Fe-based amorphous soft magnetic alloys with high saturation magnetization and good bending ductility10.1016/j.jallcom.2014.06.093 ↗
7. A brief overview of bulk amorphous alloys10.1038/asiamat.2011.30 ↗
8. Roles of minor additions in formation and properties of bulk amorphous alloys10.1016/j.pmatsci.2006.07.003 ↗
9. Amorphous ferromagnetic phase in iron-carbon- phosphorus alloys10.1063/1.1709084 ↗
10. Fe-based bulk amorphous alloys: brittle or ductile?10.1063/1.4899124 ↗
11. Magnetic properties of nanocrystalline Fe82.65Cu1.35SixB16-x alloys (x = 0-7)10.1063/1.2769956 ↗
12. Metglass, http://www.metglas.com/, 2021 (accessed 10 January 2021).
13. Core loss in toroidal cores based on Fe-based amorphous Metglas 2605HB1 alloy10.1109/TMAG.2011.2152370 ↗
14. Fe-B-C amorphous alloys with room-temperature saturation induction over 17.5kG10.1063/1.90601 ↗
15. Composition design of high Bs Fe-based amorphous alloys with good amorphous-forming ability10.1016/j.jallcom.2015.09.216 ↗
16. Syntheses and corrosion behaviors of Fe-based amorphous soft magnetic alloys with high-saturation magnetization bear 1.7 T10.1557/jmr.2014.389 ↗
17. Nanocrystallization, good soft magnetic properties and ultrahigh mechanical strength for Fe82-85B13-16Si1Cu1 amorphous alloys10.1016/j.jallcom.2019.01.150 ↗
18. Thermal and magnetic properties of Fe(Co)BCCu amorphous alloys with high saturation magnetization of 1.77 T10.1016/j.jallcom.2020.157071 ↗
19. Tunable magnetic properties and heat-treatable bending ductility of Fe-Co-B-P-C amorphous alloys with a high saturated magnetization up to 1.79 T10.1016/j.jallcom.2018.11.147 ↗
20. Fe(Co) SiBPCCu nanocrystalline alloys with high Bs above 1.83 T10.1016/j.jmmm.2017.05.072 ↗
21. Soft magnetic Fe-Co-based amorphous alloys with extremely high saturation magnetization exceeding 1.9 T and low coercivity of 2 A/m10.1016/j.jallcom.2017.06.192 ↗
22. Softening and good ductility for nanocrystal-dispersed amorphous Fe-Co-B alloys with high saturation magnetization above 1.7 T10.1016/j.jallcom.2015.10.066 ↗
23. Tuning glass formation and brittle behaviors by similar solvent element substitution in (Mn, Fe)-based bulk amorphous alloys10.1016/j.msea.2014.12.048 ↗
24. Enhancement of plastic deformability in Fe-Ni-Nb-B bulk glassy alloys by controlling the Ni-to-Fe concentration ratio
25. Effects of metalloid B addition on the glass formation, magnetic and mechanical properties of FePCB bulk amorphous alloys10.1016/j.jmst.2014.10.009 ↗
26. Reductilization of an embrittled amorphous La55Al25Ni20 alloy by water quenching from supercooled liquid10.2320/matertrans1989.32.201 ↗
27. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set10.1016/0927-0256(96)00008-0 ↗
28. Generalized gradient approximation made simple10.1103/PhysRevLett.77.3865 ↗
29. Mössbauer study of the crystallization of Fe100-xBx amorphous alloys (14≤x≤25)10.1063/1.344384 ↗
30. Local atomic structure in amorphous Fe-P alloys10.1063/1.340516 ↗
31. Magnetic properties of amorphous FeC thin films10.1063/1.324705 ↗
32. On the role of Sm in solidification of Al-Sm amorphous alloys10.1016/j.scriptamat.2016.06.045 ↗
33. Effects of solute-solute avoidance on amorphous alloys formation10.1016/j.jnoncrysol.2012.06.017 ↗
34. The devitrification of a Zr65Cu22Ni5Al8 amorphous alloys10.1007/BF00592726 ↗
35. Stability and transformation to crystalline phases of amorphous Zr-Al-Cu alloys with significant supercooled liquid region10.1016/0921-5093(94)90551-7 ↗
36. Grain structure and magnetism of nanocrystalline ferromagnets10.1109/20.42292 ↗
37. Effect of primary α-Fe on soft magnetic properties of FeCuNbSiB amorphous/nanocrystalline alloy10.1016/j.jnoncrysol.2021.121079 ↗
38. Embrittlement of Fe, Ni, Co amorphous alloys containing metalloid elements by crystallization
39. Crystallization kinetics of Ni-P glass-activation energies for nucleation and growth of nuclei10.1007/BF00547482 ↗