journal article·2018-03

Experimental investigation and thermodynamic analysis of glass forming ability of the Al–Co–Sm ternary system

Siyuan Peng, Zhiyu Xiao, Tungwai Leo Ngai, Zhongqiang Liu, Weiwen Zhang

Publisher page

Abstract

Abstract Based on an effective atomic radius instead of a nominal atomic radius in the efficient atomic packing cluster method, the best glass forming composition in the new Al–Co–Sm ternary system was forecasted. Thermodynamic description of the Al-rich corner of Al–Co–Sm system was performed using the CALPHAD approach. Results show that the effective atomic radii of Sm and Al are approximately equal to the nominal radii, but the effective atomic radius of Co atom is obviously smaller than its nominal radius. From thermodynamic calculation, the composition dependencies of glass forming ability (GFA) in the Al-rich corner of the system were forecasted by finding the relatively low driving forces for crystalline phases, and the forecast of GFA agrees well with the experimental data.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Metallic Glasses and Amorphous Alloys · Phase-change materials and chalcogenides · Glass properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (45)

Show source-provided references
1. Aluminum-based amorphous alloys with tensile strength above 980 MPa (100 kg/mm2)10.1143/JJAP.27.L479 ↗
2. Glass forming ability and primary crystallization behavior of Al–Ni–Ce alloys10.1016/j.intermet.2012.01.005 ↗
3. Prediction of glass forming compositions in Al-Fe-Si alloy system by thermodynamic approach10.1016/j.jnoncrysol.2017.09.044 ↗
4. On the fracture toughness of bulk metallic glasses under Berkovich nanoindentation10.1016/j.jnoncrysol.2017.11.008 ↗
5. Synthesis and properties of metallic glasses that contain aluminum10.1126/science.241.4873.1640 ↗
6. Formation of metal-metal type aluminum-based amorphous alloys10.1007/BF02662599 ↗
7. Stability of Al-rich glasses in the Al–La–Ni system10.1016/j.intermet.2005.06.009 ↗
8. Synthesis and properties of Al-Ni-La bulk metallic glass10.1002/adem.200900100 ↗
9. Developing aluminum-based bulk metallic glasses10.1080/14786435.2010.484401 ↗
10. Designing aluminum-rich bulk metallic glasses via electronic-structure-guided microalloying10.1016/j.actamat.2016.02.012 ↗
11. Melt fluxing to elevate the forming ability of Al-based bulk metallic glasses
12. Effect of Ag addition on the glass-forming ability and thermal stability of Mg–Cu–Y alloys10.1016/j.msea.2003.10.302 ↗
13. La-based bulk metallic glasses with critical diameter up to 30 mm10.1016/j.actamat.2007.04.021 ↗
14. Zr–(Cu, Ag)–Al bulk metallic glasses10.1016/j.actamat.2007.12.030 ↗
15. Structural evolution and thermophysical properties of ZrxNi100−x metallic liquids and glasses10.1016/j.jnoncrysol.2014.10.026 ↗
16. A new Cu–Hf–Al ternary bulk metallic glass with high glass forming ability and ductility10.1016/j.scriptamat.2006.02.042 ↗
17. An experimental investigation on the notch toughness of Cu-Zr-based bulk metallic glasses with in-situ crystallization10.1016/j.jnoncrysol.2017.04.040 ↗
18. Thermal stability and crystallization phenomena of low cost Ti-based bulk metallic glass10.1016/j.jnoncrysol.2009.08.005 ↗
19. A development of Ti-based bulk metallic glass10.1016/j.msea.2003.10.115 ↗
20. Development of quaternary Fe-based bulk metallic glasses10.1016/j.msea.2008.03.019 ↗
21. Microstructure and mechanical properties of Al–Ni–Ce amorphous matrix composites enhanced with Ti-based glassy particles prepared by powder metallurgy10.1016/j.matlet.2014.05.215 ↗
22. A structural model for metallic glasses10.1038/nmat1219 ↗
23. Glass forming ability and crystallization behavior of Al–Ni–RE metallic glasses10.1016/j.intermet.2013.05.003 ↗
24. Al-rich bulk metallic glasses with plasticity and ultrahigh specific strength10.1016/j.scriptamat.2009.04.035 ↗
25. XAFS study of amorphous Al–RE alloys10.1016/j.scriptamat.2005.11.033 ↗
26. Local atomic order in Al-based metallic glasses studied using XAFS method10.1016/j.jallcom.2008.01.037 ↗
27. Electronic structure of NiAl10.1103/PhysRevB.42.1582 ↗
28. Prediction of composition dependency of glass forming ability of Mg–Cu–Y alloys by thermodynamic approach10.1016/j.scriptamat.2005.01.038 ↗
29. Correlation between thermodynamics and glass forming ability in the Al–Ce–Ni system10.1016/j.intermet.2009.12.027 ↗
30. Thermodynamic assessment of the phase equilibria and prediction of glass-forming ability of the Al–Cu–Zr system10.1016/j.jnoncrysol.2016.09.031 ↗
31. Thermodynamic analysis of the La–Mg–Ni bulk metallic glass system10.1016/j.jallcom.2009.10.155 ↗
32. Thermodynamic analysis of glass-forming ability in a Ca-Mg-Zn ternary alloy system10.1103/PhysRevB.73.224202 ↗
33. Regular-solution model for stoichiometric phases and ionic melts10.3891/acta.chem.scand.24-3618 ↗
34. SGTE data for pure elements10.1016/0364-5916(91)90030-N ↗
35. Algebraic representation of thermodynamic properties and the classification of solutions10.1021/ie50458a036 ↗
36. A model for alloying in ferromagnetic metals10.1016/0364-5916(78)90011-1 ↗
37. Phase separation of the B2 structure accompanied by an ordering in Co-Al and Ni-Al binary systems10.2320/matertrans.45.1489 ↗
38. Thermodynamic assessment of the Al–Mg–Sm system10.1016/j.jallcom.2007.05.035 ↗
39. A thermodynamic assessment of the Co–Sm system10.1016/S0925-8388(97)00540-9 ↗
40. The PANDAT software package and its applications10.1016/S0364-5916(02)00034-2 ↗
41. Atomic structure of amorphous Al100−2xCoxCex (x = 8, 9, and 10) and Al80Fe10Ce10 alloys: an XAFS study10.1103/PhysRevB.50.12401 ↗
42. Characterization of structural inhomogeneity in Al88Ce8Co4 metallic glass10.1016/j.actamat.2016.04.009 ↗
43. The influence of efficient atomic packing on the constitution of metallic glasses10.1080/1478643031000098828 ↗
44. Reaction kinetics in differential thermal analysis10.1021/ac60131a045 ↗
45. On the crystallization behavior of amorphous Fe–Cr–Mo–B–P–Si–C powder prepared by mechanical alloying10.1016/j.matlet.2010.02.008 ↗