Formation and physical and structural properties of Sb2S3-PbI2 chalcogenide glasses
Source abstract
Abstract
Abstract Novel chalcogenide glasses of the pseudo-binary (100-x)Sb2S3-xPbI2 system were synthesized by traditional melt-quenching method, and its glass-forming region was determined from x = 20 to 55 mol%. Compared to traditional sulfide glasses, the long-wave infrared (LWIR) cut-off edge of Sb2S3-PbI2 glasses is extended up to 14 μm. The physical properties of these glasses, including their Tg, ΔT (= Tx − Tg), Vickers hardness, density, and Abbe number, were characterized and analyzed using their compositional dependent Raman spectra. [SbI3] structural units could promote the forming ability (ΔT) of the Sb2S3-PbI2 glasses because of the broken connectivity of the network structure. The results of this research provide useful knowledge for developing novel LWIR chalcogenide glasses.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Phase-change materials and chalcogenides · Glass properties and applications · Chalcogenide Semiconductor Thin Films
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (37)
Show source-provided references
1. Chalcogenide glass-fiber-based mid-IR sources and applications10.1109/JSTQE.2008.2010245 ↗
2. Fabrication of molded chalcogenide-glass lens for thermal imaging applications10.1364/AO.51.005649 ↗
3. Ga-La-S-Se glass for visible and thermal imaging10.1515/aot-2016-0069 ↗
4. Chalcogenide glass: Fabrication techniques, properties and applications10.1080/00150193.2017.1412187 ↗
5. Klocek · 2017
6. Glasses for seeing beyond visible10.1002/chem.200700993 ↗
7. Infrared transmitting glasses and glass-ceramics10.1016/j.jnoncrysol.2006.03.029 ↗
8. Evaluation of micronucleus frequencies and DNA damage in glass workers exposed to arsenic10.1002/em.20229 ↗
9. Arsenic and selenium toxicity and their interactive effects in humans10.1016/j.envint.2014.04.019 ↗
10. Glass formation and properties of glasses based on Ga2S3-Sb2S3 systems incorporated with CsX (X = Cl, Br, I) and AgCl10.2109/jcersj2.18014 ↗
11. Ga2S3-Sb2S3-CsI chalcohalide glasses for mid-infrared applications10.1111/jace.15056 ↗
12. Structure and ionic conductivity of new Ga2S3-Sb2S3-NaI chalcogenide glass system10.1016/j.physb.2019.05.026 ↗
13. Thermal and optical properties of GeS2-based chalcogenide glasses10.1016/j.mseb.2004.02.008 ↗
14. Compositional dependence of physical and structural properties in (Ge1−xGax) S2 chalcogenide glasses10.1016/j.jnoncrysol.2018.03.030 ↗
15. Wang · 2014
16. Relationship between composition, crystallization, and phase separation behavior of GeS2–Sb2S3–CsCl chalcogenide glasses10.1016/j.infrared.2019.102978 ↗
17. Crystallization behavior of 80GeS2⋅20Ga2S3 chalcogenide glass10.1007/s00339-009-5304-1 ↗
18. IR impurity absorption in Sb2S3–GeS2(Ge2S3) chalcogenide glasses10.1016/S1350-4495(99)00055-9 ↗
19. Glass formation in Sb2Se3-MXn (metal halides)10.1016/0022-3093(94)90368-9 ↗
20. New chalcohalide glasses from the Sb2S3-MXn system10.1016/0022-3093(94)00593-1 ↗
21. Glass formation and the phase diagram of crystalline components in the Sb2S3-PbI2 system10.1007/s10720-005-0007-y ↗
22. Phase Diagram and Glass Formation in the Sb2S3-AgI System10.1007/s10720-005-0110-0 ↗
23. Theoretical investigation of the structural properties of Sb2S3-As2S3 and Sb2Te3-As2S3 glasses
24. Structure of amorphous and glassy Sb2S3 and its connection with the structure of As2X3 arsenic chalcogenide glasses10.1016/0022-3093(82)90164-8 ↗
25. Chalcogenide glass-ceramics: functional design and crystallization mechanism10.1016/j.pmatsci.2017.11.001 ↗
26. Preparation and thermal properties of novel Li2S–Sb2S3 glassy system10.1016/S0022-3093(02)01323-6 ↗
27. Investigations on glasses in the Sb2S3-Agl system10.1016/0022-3093(88)90432-2 ↗
28. PbCl2 conducting glasses with mixed glass formers10.1088/0953-8984/7/8/005 ↗
29. High-purity chalcogenide glasses for fiber optics10.1134/S0020168509130019 ↗
30. Preparation of Ge-S glass fibers with reduced OH, SH content10.1143/JJAP.20.L13 ↗
31. Poisson's ratio and the densification of glass under high pressure10.1103/PhysRevLett.100.225501 ↗
32. Correlation between acousto-optic and structural properties of Ge–Sb–S chalcogenide glasses10.1016/j.ceramint.2020.01.036 ↗
33. Fast Ag-Ion-conducting GeS2–Sb2S3–AgI glassy electrolytes with exceptionally low activation energy10.1021/acs.jpcc.7b10630 ↗
34. Color correction in the infrared using gradient-index materials10.1117/1.OE.52.11.112109 ↗
35. The Raman spectrum of ferroelectric SbSI10.1016/0038-1098(70)90634-4 ↗
36. Optimization of glass properties by substituting AgI with Ag2S in chalcogenide system10.1016/j.ceramint.2019.07.305 ↗
37. Structure of GeS2-SbSI glasses by Raman spectroscopy10.1111/j.1551-2916.2010.03903.x ↗