journal article·2018-10

High pressure torsion of a Vitreloy bulk metallic glass near the glass transition temperature

Zsolt Kovács, Erhard Schafler, Viktória Kovács Kis, Péter J. Szommer, Ádám Révész

Publisher page

Abstract

Abstract Disk shaped specimens of commercial Zr44Ti11Cu10Ni10Be25 bulk metallic glass (Vitreloy 1b) were subjected to extreme hydrostatic pressure and simultaneous plastic shear deformation by high pressure torsion method at elevated temperatures below (610 K and 620 K) and around the glass transition (630 K). Coupled calorimetric and X-ray diffraction experiments revealed that the amorphous structure of the alloy is very stable up to 620 K, however, destabilization takes place close to the glass transition (Tg) at 630 K. Series of hardness measurements were performed by depth-sensing nanoindentation for the as-cast and the thermo-mechanically treated samples. The shape and the mean value of the hardness distribution of the disks processed below Tg are similar to that of the as-cast glass, nevertheless the hardness distribution becomes broader accompanied with a significant overall increase when the Vitreloy 1b glass is subjected to extreme shear deformation close to Tg.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Metallic Glasses and Amorphous Alloys · High Entropy Alloys Studies · Phase-change materials and chalcogenides

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (51)

Show source-provided references
1. High strength bulk amorphous alloys with low critical cooling rates10.1016/S1359-6454(99)00300-6 ↗
2. Mechanical properties of bulk metallic glasses10.1016/j.pmatsci.2010.04.002 ↗
3. Molecular transport in liquids and glasses10.1063/1.1730566 ↗
4. Mechanical behavior of amorphous alloys10.1016/j.actamat.2007.01.052 ↗
5. Miller · 2008
6. Homogeneous flow of metallic glasses: a free volume perspective10.1016/j.scriptamat.2005.09.046 ↗
7. Yielding and shear banding of metallic glasses10.1016/j.actamat.2013.06.025 ↗
8. Evolution of shear bands, free volume and hardness during cold rolling of a Zr-based bulk metallic glass10.1016/j.actamat.2013.10.035 ↗
9. Free volume gradient effect on mechanical properties of metallic glasses10.1016/j.scriptamat.2016.11.003 ↗
10. Plastic deformation in metallic glasses10.1016/0001-6160(79)90055-5 ↗
11. Homogeneous deformation of bulk metallic glasses10.1016/j.scriptamat.2005.04.052 ↗
12. High temperature deformation of a Cu40Zr44Ag8Al8 bulk metallic glass10.1016/j.msea.2011.01.045 ↗
13. Amorphous metallic plastic10.1103/PhysRevLett.94.205502 ↗
14. High temperature deformation behaviors of Ti40Zr25Ni3Cu12Be20 bulk metallic glass10.1016/j.jallcom.2010.02.163 ↗
15. Crystallization and high-temperature deformation behavior of Cu49Zr45Al6 bulk metallic glass within supercooled liquid region10.1016/j.jnoncrysol.2013.05.036 ↗
16. Constitutive model for high temperature deformation behavior of Ti–Zr–Ni–be bulk metallic glass in supercooled liquid region10.1016/j.commatsci.2012.04.006 ↗
17. Free volume model: high-temperature deformation of a Zr-based bulk metallic glass10.1016/j.actamat.2005.10.054 ↗
18. Mechanism for microstructural evolution induced by high temperature deformation in Zr-based bulk metallic glasses10.1016/j.jallcom.2016.03.145 ↗
19. The effect of high temperature plastic deformation on the thermal stability and microstructure of Zr55Cu30Ni5Al10 bulk metallic glass10.1016/j.msea.2006.02.284 ↗
20. Deformation behavior of the Zr53.5Cu26.5Ni5Al12Ag3 bulk metallic glass over a wide range of strain rate and temperatures10.1016/j.jmst.2015.06.001 ↗
21. Bulk nanostructured materials from severe plastic deformation10.1016/S0079-6425(99)00007-9 ↗
22. A review on high-pressure torsion (HPT) from 1935 to 198810.1016/j.msea.2015.11.074 ↗
23. Using high-pressure torsion for metal processing: fundamentals and applications10.1016/j.pmatsci.2008.03.002 ↗
24. Localization of plastic deformation along shear bands in Vitreloy bulk metallic glass during high pressure torsion10.1016/j.jallcom.2014.01.079 ↗
25. Post-shear deformation of high pressure torsion-deformed nickel under hydrostatic pressure10.1016/j.scriptamat.2007.01.019 ↗
26. Accelerated diffusion and phase transformations in CoCu alloys driven by the severe plastic deformation10.2320/matertrans.MD201111 ↗
27. The evolution of the microstructure in amorphous Al85Ce8Ni5Co2 alloy during heat treatment and severe plastic deformation: a comparative study10.1016/j.intermet.2010.10.007 ↗
28. Nanocrystallization mechanisms of Al-rich glass-forming alloys10.1016/j.jnoncrysol.2007.07.067 ↗
29. High pressure torsion of amorphous Cu60Zr30Ti10 alloy10.1063/1.2964115 ↗
30. Nanocrystallization induced by severe plastic deformation of amorphous alloys10.4028/www.scientific.net/JMNM.22.21 ↗
31. Nanocrystallization and magnetic properties of amorphous Nd9Fe85B6 subjected to high-pressure torsion deformation upon annealing
32. Severe plastic deformation of amorphous alloys: I. Structure and mechanical properties10.3103/S1062873809090123 ↗
33. Révész · Appl. Phys. Lett. · 2008 · 9210.1063/1.2830992 ↗
34. Volume changes in Vitreloy bulk metallic glass during room temperature high-pressure torsion10.1557/JMR.2008.0416 ↗
35. Structural rejuvenation in a bulk metallic glass induced by severe plastic deformation10.1016/j.actamat.2009.09.021 ↗
36. An improved technique for determining hardness and elastic-modulus using load and displacement sensing indentation experiments10.1557/JMR.1992.1564 ↗
37. Indentation creep study on a Zr-based bulk metallic glass containing nano-quasicrystals10.1016/j.msea.2006.12.172 ↗
38. Bulk nanostructured Zr-based multiphase alloys with high strength and good ductility10.1016/S1359-6462(01)00779-5 ↗
39. Relation between icosahedral short-range ordering and plastic deformation in Zr–Nb–Cu–Ni–Al bulk metallic glasses10.1016/j.actamat.2011.01.020 ↗
40. Correlation between icosahedral short range order, glass forming ability, and thermal stability of Zr–Ti–Ni–Cu–(Be) glasses10.1063/1.2755924 ↗
41. Crystallization behaviour of Al-based metallic glasses below and above the glass-transition temperature10.1016/S0022-3093(02)01375-3 ↗
42. Thermal stability, crystallization kinetics, and grain growth in an amorphous Al85Ce5Ni8Co2 alloy10.1557/JMR.2002.0315 ↗
43. Crystallization kinetics and thermal stability of the Zr60Al7.5Cu17.5Ni10Si4B1 amorphous alloy studied by isothermal differential scanning calorimetry and transmission electron microscopy10.1016/j.msea.2006.02.395 ↗
44. Nanostructure controlling in Zr-based metallic glasses using icosahedral local structure10.1016/j.jallcom.2008.07.182 ↗
45. In situ synchrotron study of phase transformation behaviors in bulk metallic glass by simultaneous diffraction and small angle scattering10.1103/PhysRevLett.91.265501 ↗
46. Microstructure, decomposition, and crystallization in Zr41Ti14Cu12.5Ni10Be22.5 bulk metallic glass10.1103/PhysRevB.57.8211 ↗
47. A model of the ductile–brittle transition of partially crystallized amorphous Al–Ni–Y alloys10.1016/S1359-6454(99)00088-9 ↗
48. Influence of the wheel speed on the thermal behaviour of Cu60Zr20Ti20 alloys10.1016/j.msea.2003.10.151 ↗
49. Effect of structural relaxation on mechanical behavior of a Zr-based bulk-metallic glass10.2320/matertrans.MJ200734 ↗
50. Hydrogen storage of melt-spun amorphous Mg65Ni20Cu5Y10 alloy deformed by high-pressure torsion10.1016/j.ijhydene.2011.12.160 ↗
51. Structural modification through pressurized sub-Tg annealing of metallic glasses10.1063/1.5004058 ↗