journal article·2016-08

Transport properties of the sodium-yttrium-silicate glasses

G.V. Nechaev, S.G. Vlasova, I.S. Kovyazina, O.G. Reznitskich

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Abstract

Abstract The influence of yttrium oxide on the transport properties and chemical stability of sodium silicate glasses is investigated. The seven sodium-yttrium silicate glass compositions were synthesised. There are three composition with Na 2 O/Y 2 O 3 = 6.5 and four with permanent Na 2 O content with 5 to 8 mol% of Y 2 O 3 . The thermal behaviour of the glasses was studied with dilatometric and DSC methods. The research into the electrical characteristics of the glass has shown that their electrical conductivity is in the range of 5 × 10 − 8 –10 − 6 S/cm at 25 °C and 10 − 3 S/cm at 300 °C. It is shown that the hydrolytic resistance increases when growing the Y 2 O 3 concentration in the glass composition at constant Na 2 O content.
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Research context

OpenAlex topics: Glass properties and applications · Microwave Dielectric Ceramics Synthesis · Recycling and utilization of industrial and municipal waste in materials production

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References (18)

Show source-provided references
1. Ellis · Curr. Opinion Solid State Mater. Sci. · 2012 · 16 · 16810.1016/j.cossms.2012.04.002 ↗
2. Development of sodium–sulfur batteries10.1111/j.1744-7402.2004.tb00179.x ↗
3. Na+-Ion conducting glasses10.1016/0167-2738(84)90007-9 ↗
4. Tuller · J. Non-Cryst. Solids · 1980 · 40 · 9310.1016/0022-3093(80)90096-4 ↗
5. Pat. 3829331 US. Sodium borate glass compositions and batteries containing same. F.Y. Tsang. Appl. (30.12.71.; Publ. 13.08.74).
6. Hayashi · Nat. Commun. · 2012 · 3 · 85610.1038/ncomms1843 ↗
7. Okura · J. Electroceram. · 2010 · 24 · 8310.1007/s10832-008-9456-8 ↗
8. Okura · Solid State Ionics · 2000 · 136–137 · 104910.1016/S0167-2738(00)00526-9 ↗
9. Yamashita · Solid State Ionics · 1989 · 35 · 29910.1016/0167-2738(89)90312-3 ↗
10. Peled · J. Power Sources · 2011 · 196 · 683510.1016/j.jpowsour.2010.09.104 ↗
11. Electrochemical properties of room-temperature sodium – air batteries with non-aqueous electrolyte10.1016/j.elecom.2011.12.019 ↗
12. Structure and properties of high Li2O-containing aluminophosphate glasses10.1016/j.jeurceramsoc.2008.12.016 ↗
13. Extremal Li-ion conductivity behavior in the Li2O-Al2O3-P2O5 glass system10.1016/j.jnoncrysol.2015.10.003 ↗
14. Ravaine · Phys. Chem. Glasses · 1977 · 18 · 27
15. Ion conducting glasses in Na2O–Y2O3–SiO2 and Li2O–Y2O3–SiO2 systems10.1016/0167-2738(86)90163-3 ↗
16. Effect of modifier cations on Na+ conductivity in sodium silicate glasses10.1016/0167-2738(87)90042-7 ↗
17. Electrical properties of (Na2O)35.7(RE2O3)7.2(SiO2)57.1 (RE=Y, Sm, Gd, Dy, Ho, Er and Yb) glasses and ceramics10.1016/j.jeurceramsoc.2005.03.245 ↗
18. Ingram · J. Am. Ceram. Soc. · 1980 · 63 · 24810.1111/j.1151-2916.1980.tb10713.x ↗