journal article·2006-11

Relaxational features of supercooled and glassy m-toluidine

Andrea Mandanici, Ranko Richert, Maria Cutroni, Xiangfu Shi, Stephen A. Hutcheson, Gregory B. McKenna

Journal of Non-Crystalline Solids· Volume 352· Issue 42-49
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Abstract

Recent investigations performed by dielectric and mechanical spectroscopy have provided detailed information about the dynamical response of m-toluidine in the supercooled and glassy states. In the present work we analyze the properties of the α-relaxation process on the basis of dielectric and shear mechanical data, discussing the unusual behavior of this fragile glass-former. The nature of the secondary relaxation is elucidated by high resolution dielectric measurements and discussed in terms of the Coupling Model and literature results on other small molecule glass-forming liquids.
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Research context

OpenAlex topics: Material Dynamics and Properties · Liquid Crystal Research Advancements · Thermodynamic properties of mixtures

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