Phase transformations in Co–B–Si alloys induced by high-energy ball milling

X-ray diffraction analysis, differential scanning calorimetry and magnetization measurements were used to determine the structural changes of the Co 78 B 11 Si 11 alloys prepared by a ball milling of amorphous, crystallized ribbons and a mixture of elemental crystalline powders in vibratory mill. For all starting materials the high-energy ball milling of Co 78 B 11 Si 11 alloy produces a crystalline structure with nanometer sized crystals. The average crystallite size is about 5 nm. Three series of Co 78 B 11 Si 11 alloys are the ferromagnetic materials. Milling of amorphous alloys causes an increase of the room temperature magnetic moment from 0.90 to 1.08 μ B . A similar tendency is observed for alloys produced by milling of the initially crystallized ribbons for which the magnetic moment increases from 0.73 μ B at t = 0 to 1.17 μB after 250 h. Somewhat different dependence is found for alloys milled from powders since magnetization of the alloy subjected to longer milling is reduced by 10% due to structural disorder introduced during a formation of the crystalline Co(Si,B) phase with nanometer sized crystals.