A new fluorozirconate glass-ceramic X-ray storage phosphor

A new fluorozirconate glass-ceramic has been discovered that displays an X-ray storage phosphor effect with an efficiency of up to 8% of that observed in the established crystalline storage phosphor, BaFBr:Eu 2+ . The glass-ceramic is based on the well-known ZBLAN20 formulation, but the replacement of Na by Rb and Li, partial substitution of F by Br, as well as doping with Eu 2+ , results in the formation of RbBa 2 Br 5 :Eu 2+ microcrystallites. X-ray diffraction, photostimulated luminescence and EPR measurements on the as-made glass and the annealed glass-ceramic show that the X-ray storage phosphor effect arises from the RbBa 2 Br 5 :Eu 2+ microcrystallites.