journal article·2022-01

Electrochemical response in physiological environments and mechanical properties of Ti51Si24Ni14Nb11 and Fe40Ti30Al18Si12 thin film metallic glasses

Nahid Sultan Al-Mamun, Akib Jabed, Mohammed Noor-A-Alam, Waseem Haider, Ishraq Shabib

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Abstract

Abstract This work investigates electrochemical response and mechanical properties of quaternary Ti51Si24Ni14Nb11 and Fe40Ti30Al18Si12 (at.%) thin film metallic glasses (TFMGs) developed using magnetron co-sputtering. Both TFMGs demonstrate superior corrosion resistance registering ∼7 to 10 times smaller corrosion current density, ∼200 to 800 mV higher break-down potential, and ∼4 to 6 times higher charge transfer resistance in phosphate buffer saline (PBS) and 0.9% sodium chloride (NaCl) compared to conventional Ti- and Fe-based biomaterials, e.g., commercially pure Ti (cp-Ti) and 316L stainless steel (SS). The enhanced anti-corrosive behavior of the quaternary films is attributed to their amorphous structures and relatively more protective passive oxide films. In addition, nano-indentation experiment reveals more than 2 times higher hardness and ∼10 to 40 GPa lower elastic modulus of the TFMGs compared to conventional biomaterials. The combination of obtained anti-corrosive behavior and mechanical properties promotes the fabricated films as potential candidates for future bio-implant applications.
Source: openaire · Quality: candidate unverified · Source record ↗

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OpenAlex topics: Metallic Glasses and Amorphous Alloys · High Entropy Alloys Studies · Electrodeposition and Electroless Coatings

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References (69)

Show source-provided references
1. A brief overview of bulk metallic glasses10.1038/asiamat.2011.30 ↗
2. Bulk metallic glasses with functional physical properties10.1002/adma.200901053 ↗
3. Recent advancements in bulk metallic glasses and their applications: a review10.1080/10408436.2017.1358149 ↗
4. Enhancement in bio-corrosion resistance of metallic glass by severe surface deformation10.1016/j.apsusc.2019.05.158 ↗
5. Metallic glasses…on the threshold10.1016/S1369-7021(09)70037-9 ↗
6. Bulk metallic glasses for biomedical applications10.1007/s11837-009-0128-1 ↗
7. Combinatorial development and in vitro characterization of the quaternary Zr–Ti–X–Y (X–Y = Cu–Ag/Co–Ni) metallic glass for prospective bioimplants10.1002/adem.201900726 ↗
8. Sputtered Mg100-xZnx (0 ≤ x ≤ 100) systems as anode materials for a biodegradable battery aimed for transient bioelectronics10.1016/j.electacta.2019.135129 ↗
9. Controlling the dissolution of iron through the development of nanostructured Fe-Mg for biomedical applications10.1016/j.actbio.2020.06.014 ↗
10. Metallic implant biomaterials10.1016/j.mser.2014.10.001 ↗
11. In vitro corrosion behavior of bioceramic, metallic, and bioceramic–metallic coated stainless steel dental implants10.1016/S0109-5641(02)00029-5 ↗
12. Enhancement of wear and corrosion resistance of beta titanium alloy by laser gas alloying with nitrogen10.1016/j.apsusc.2016.01.091 ↗
13. Wear and corrosion resistance of anti-bacterial Ti–Cu–N coatings on titanium implants10.1016/j.apsusc.2014.08.163 ↗
14. Tribocorrosion behavior of beta titanium biomedical alloys in phosphate buffer saline solution10.1016/j.jmbbm.2015.02.016 ↗
15. A combinatorially developed Zr-Ti-Fe-Al metallic glass with outstanding corrosion resistance for implantable medical devices10.1016/j.scriptamat.2018.11.011 ↗
16. Property optimization of Zr-Ti-X (X = Ag, Al) metallic glass via combinatorial development aimed at prospective biomedical application10.1016/j.surfcoat.2019.05.036 ↗
17. Attempt to develop Ti-based amorphous alloys for biomaterials10.1016/j.msea.2006.02.307 ↗
18. Investigation of glass-forming ability, deformation and corrosion behavior of Ni-free Ti-based BMG alloys designed for application as dental implants10.1016/j.msec.2008.07.009 ↗
19. Metallic glasses as structural materials10.1016/j.scriptamat.2005.09.051 ↗
20. Enhanced mechanical properties and in vitro corrosion behavior of amorphous and devitrified Ti40Zr10Cu38Pd12 metallic glass10.1016/j.jmbbm.2011.05.028 ↗
21. Microstructure, mechanical and anti-corrosion property evaluation of iron-based thin film metallic glasses10.1016/j.surfcoat.2014.07.039 ↗
22. A Ni-free ZrCuFeAlAg bulk metallic glass with potential for biomedical applications10.1016/j.actbio.2013.02.019 ↗
23. Corrosion behavior and in vitro biocompatibility of Zr–Al–Co–Ag bulk metallic glasses: aAn experimental case study10.1016/j.jnoncrysol.2012.04.022 ↗
24. New Ti-based Ti–Cu–Zr–Fe–Sn–Si–Ag bulk metallic glass for biomedical applications10.1016/j.jallcom.2014.07.021 ↗
25. In vitro biocompatibility assessment of Ti40Cu38Zr10Pd12 bulk metallic glass10.1007/s10856-013-5041-z ↗
26. Formation and properties of Ti-based Ti–Zr–Cu–Fe–Sn–Si bulk metallic glasses with different (Ti + Zr)/Cu ratios for biomedical application10.1016/j.intermet.2016.01.007 ↗
27. Development of Fe-based bulk metallic glasses as potential biomaterials10.1016/j.msec.2015.03.041 ↗
28. Exceptionally high glass-forming ability of an FeCoCrMoCBY alloy10.1063/1.1897426 ↗
29. Effects of Cr contents in Fe-based bulk metallic glasses on the glass forming ability and the corrosion resistance10.1016/j.matchemphys.2008.08.057 ↗
30. Formation, mechanical properties and corrosion resistance of Ti–Pd base glassy alloys10.1016/j.jnoncrysol.2007.10.025 ↗
31. Microstructures and age hardening of rapidly quenched Ti-Zr-Si alloys10.1007/BF00720529 ↗
32. In vitro biocompatibility response of Ti–Zr–Si thin film metallic glasses10.1016/j.apsusc.2014.09.204 ↗
33. Promising Ta-Ti-Zr-Si metallic glass coating without cytotoxic elements for bio-implant applications10.1016/j.apsusc.2017.08.065 ↗
34. Designing biocompatible Ti-based metallic glasses for implant applications10.1016/j.msec.2012.11.015 ↗
35. Combinatorial development and assessment of a Zr-based metallic glass for prospective biomedical applications10.1016/j.jnoncrysol.2019.119544 ↗
36. Improved plasticity and corrosion behavior in Ti–Zr–Cu–Pd metallic glass with minor additions of Nb: An alloy composition intended for biomedical applications10.1016/j.msea.2012.08.058 ↗
37. Effect of Nb content on corrosion behavior of Ti-based bulk metallic glass composites in different solutions10.1016/j.apsusc.2018.11.190 ↗
38. Surface microstructures and corrosion resistance of Ni-Ti-Nb shape memory thin films10.1016/j.apsusc.2017.04.070 ↗
39. Formation and properties of centimeter-size Zr–Ti–Cu–Al–Y bulk metallic glasses as potential biomaterials10.1016/j.jallcom.2015.09.254 ↗
40. Mechanical strength and thermal stability of Ti-based amorphous alloys with large glass-forming ability10.1016/0921-5093(94)90294-1 ↗
41. Effect of thermal stability of the amorphous substrate on the amorphous oxide growth on Zr–Al–(Cu,Ni) metallic glass surfaces10.1016/j.corsci.2013.04.009 ↗
42. Identifying the role of nanoscale heterogeneities in pitting behaviour of Al-based metallic glass10.1016/j.corsci.2011.05.047 ↗
43. Biosafety, stability, and osteogenic activity of novel implants made of Zr70Ni16Cu6Al8 bulk metallic glass for biomedical application10.1016/j.actbio.2018.05.020 ↗
44. In vitro and in vivo studies on Ti-based bulk metallic glass as potential dental implant material10.1016/j.msec.2013.04.038 ↗
45. Measurement of hardness and elastic modulus by instrumented indentation: advances in understanding and refinements to methodology10.1557/jmr.2004.19.1.3 ↗
46. Stabilization of metallic supercooled liquid and bulk amorphous alloys10.1016/S1359-6454(99)00300-6 ↗
47. Effect of the atomic size distribution on glass forming ability of amorphous metallic alloys10.1016/S0025-5408(01)00715-2 ↗
48. Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element10.2320/matertrans.46.2817 ↗
49. Corrosion resistance of Fe-Cr-based amorphous alloys: an overview10.1016/j.jnoncrysol.2016.04.009 ↗
50. Evaluation of model and dispersion parameters and their effects on the formation of constant-phase elements in equivalent circuits10.1016/S0022-0728(98)00471-9 ↗
51. Electrochemical and passive layer characterizations of 304L, 316L, and Duplex 2205 stainless steels in thiosulfate gold leaching solutions10.1149/2.0841614jes ↗
52. Dielectric properties of materials showing Constant-Phase-Element (CPE) impedance response10.1149/2.033306jes ↗
53. Corrosion assessment of Ni60 Nb30Ta10 metallic glass and its partially crystallized alloy in concentrated nitric acid environment10.1016/j.jallcom.2019.152172 ↗
54. Electrochemical behaviour of passive film formed on the surface of Ti-6Al-4V alloys fabricated by electron beam melting10.1016/j.corsci.2018.09.010 ↗
55. Influence of yttrium as a minority alloying element on the corrosion behavior in Fe-based bulk metallic glasses10.1016/j.electacta.2008.08.017 ↗
56. Wear behavior and corrosion properties of Fe-based thin film metallic glasses10.1016/j.jallcom.2015.07.256 ↗
57. Electrochemical behavior of a Ti-based bulk metallic glass10.1016/j.jnoncrysol.2007.03.012 ↗
58. Relationship between amorphous structure and corrosion behaviour in a Zr–Ni metallic glass10.1016/j.corsci.2012.02.017 ↗
59. Effect of atomic mobility on the electrochemical properties of a Zr58Nb3Cu16Ni13Al10 bulk metallic glass10.1016/j.electacta.2018.02.071 ↗
60. Crystallization and corrosion resistance of (Fe0.78Si0.09B0.13)100-xNix (x=0, 2 and 5) Glassy Alloys10.1016/S1005-0302(12)60014-0 ↗
61. Nanoindentation study of size effect and loading rate effect on mechanical properties of a thin film metallic glass Cu49.3Zr50.710.1016/j.physb.2011.10.050 ↗
62. Plastic deformation and mechanical softening of Pd 40 Cu 30 Ni 10 P 20 bulk metallic glass during nanoindentation10.1557/JMR.2005.0331 ↗
63. New regime of homogeneous flow in the deformation map of metallic glasses: elevated temperature nanoindentation experiments and mechanistic modeling10.1016/j.actamat.2004.09.005 ↗
64. S. Cao, J. Liang, J. Zhou, L. Wang, Microstructure evolution and wear resistance of in-situ nanoparticles reinforcing Fe-based amorphous composite coatings, Surf. Interfaces. 21 (2020) 100652. 10.1016/j.surfin.2020.100652.10.1016/j.surfin.2020.100652 ↗
65. Mechanical characterization of nano-reinforced silica based sol–gel hybrid coatings on AISI 316L stainless steel using nanoindentation techniques10.1016/j.surfcoat.2009.04.014 ↗
66. Nanoindentation and wear properties of Ti and Ti-TiB composite materials produced by selective laser melting10.1016/j.msea.2017.01.096 ↗
67. On the significance of the H/E ratio in wear control: a nanocomposite coating approach to optimised tribological behaviour10.1016/S0043-1648(00)00488-9 ↗
68. Evaluation of modulus of elasticity, nano-hardness and fracture toughness of TiB2–TiC–Al2O3 composite coating developed by SHS and laser cladding10.1016/j.msea.2011.03.057 ↗
69. Nanoindentation of metallic glasses10.1016/S1369-7021(09)70039-2 ↗