Thermal, chemical properties and structure evolution of medical neutral glasses modified by transition metal oxides
Source abstract
Abstract
Against the endless new pandemics, market prospect of medical neutral glasses unprecedentedly enlarged. To obtain instructive guidance for optimizing neutral glass, the different effects of transition metal oxides (TiO 2 and Fe 2O 3) on glasses properties and structure were studied in this work. Based on X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy, and performance analysis, Ti and Fe were certified as modifiers uniformly; but they showed selective influence on network structural units for the diverse adjustments on free oxygen and compensation cations: Fe 2O 3 is associated with arising of [BO 4], and TiO 2 promoted formation of [AlO 4]. In general, TiO 2 and Fe 2O 3 weakened thermal stability and partial chemical properties for altered network linkage and compactness, however, they enhanced water resistance due to a unique blocking function. With them co-doped, amber neutral glasses were acquired, which possessed the high thermal stability but lower chemical resistance. All glasses satisfy the related requirements for medical package application.
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Research context
OpenAlex topics: Glass properties and applications · Pigment Synthesis and Properties · Luminescence Properties of Advanced Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
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