journal article·2021-01Open access

Crystallization mechanism of BaO-CaO-Al2O3-SiO2 (BCAS) glass thin-films

T. Carlier, R. Podor, S. Saitzek, L. Montagne, P. Roussel, F.O. Méar

Abstract

Abstract Crystallization pathways of BaO CaO-Al2O3-SiO2 (BCAS) glass were determined as a function of time and temperature, using a set of adapted and in-situ characterization techniques such as differential thermal analysis, high-temperature X-ray diffraction, nuclear magnetic resonance and high-temperature environmental scanning electron microscopy. Glass systems are a melted quenched bulk form and a deposited thin-film form (Pulsed Laser Deposition technique was used to obtain a coating on Si-substrate with a thickness up to 100 nm). The composition of the crystallized phases depends on the geometry of the glass, and of the applied geometrical constraints. These constraints control the volume fraction of crystallized glass melt as a function of time and temperature, and thus modify the reactional pathways.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Glass properties and applications · Metallic Glasses and Amorphous Alloys · Cultural Heritage Materials Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (48)

Show source-provided references
1. Biocompatible and bioactive glass-ceramics – state of the art and new directions10.1016/S0022-3093(97)00329-3 ↗
3. Bioactive glass in tissue engineering10.1016/j.actbio.2011.03.016 ↗
4. Bioactive glass and glass-ceramic scaffolds for bone tissue engineering10.3390/ma3073867 ↗
5. Optical fabrication of micro lenses in chalcogenide glasses10.1364/OL.20.000958 ↗
6. Recent advances in chalcogenide glasses10.1016/j.jnoncrysol.2004.08.096 ↗
7. Active and passive chalcogenide glass optical fibers for IR applications: a review10.1016/S0022-3093(99)00484-6 ↗
8. Chalcogenide glass optical waveguides for infrared bio-sensing10.3390/s90907398 ↗
9. Chalcogenide photonics10.1038/nphoton.2011.309 ↗
10. Thin-film solar cells: review of materials, technologies and commercial status10.1007/s10854-007-9177-9 ↗
11. Glass-ceramic protective coating for titanium alloys10.1111/j.1151-2916.2002.tb00547.x ↗
12. Preparation methods and application of silicon oxide films
13. A.K. Varshneya, Fundamentals of Inorganic Glasses, first ed., Academic PressBoston, 1994.10.1016/B978-0-08-057150-8.50025-2 ↗
14. Strong UV absorption and visible luminescence in ytterbium-doped aluminosilicate glass under UV excitation10.1364/OL.32.003352 ↗
15. Pulsed laser deposition of Ga-La-S chalcogenide glass thin film optical waveguides10.1063/1.110730 ↗
16. Growth and characterization of pulsed laser deposited lead germanate glass optical waveguides10.1016/S0925-3467(98)00065-2 ↗
17. Thin films of glass and their application to biomedical sensors10.1007/BF02474087 ↗
18. Li2OB2O3-P2O5 solid electrolyte for thin film batteries10.1016/j.jpowsour.2006.02.011 ↗
19. Novel fabrication method of metallic glass thin films using carousel type sputtering system10.1117/12.581811 ↗
20. Bioactive glass thin films deposited by magnetron sputtering technique: the role of working pressure10.1016/j.apsusc.2010.05.035 ↗
21. Adherent glass-ceramic thin layers with bioactive potential deposited by magnetron sputtering techniques
22. Study of the stoichiometry transfer in pulsed laser deposition of bioactive silica-based glasses10.1016/j.tsf.2003.11.123 ↗
23. The role of the reactive atmosphere in pulsed laser deposition of bioactive glass films10.1016/j.tsf.2003.11.258 ↗
24. Pulsed Laser Ablation and Deposition of Bioactive Glass as Coating Material for Biomedical Applications10.1016/S0169-4332(98)00610-2 ↗
25. S. Ishikawa, A. Urano, H. Aikawa, C. Hirose, H. Kanamori, M. Saitoh, Method for Producing Glass Thin Film, Patent US5660611, 1997.
26. Properties of thin-film glass coatings produced by laser deposition in vacuum10.1007/BF02681370 ↗
27. Particulates generated by pulsed laser ablation
28. D.B. Chrisey, G.K. Hubler, Pulsed laser deposition of thin films, firth ed., Wiley-Interscience, New York, 1994.
29. Autonomic self-repairing glassy materials10.1002/adfm.201000147 ↗
30. Characterization of self-healing glassy composites by high-temperature environmental scanning electron microscopy (HT-ESEM)10.1093/jmicro/dfq018 ↗
31. Influence of the active particles on the self-healing efficiency in glassy matrix10.1002/adem.201100002 ↗
32. Self-healing glassy thin coating for high-temperature applications10.1021/acsami.5b12049 ↗
33. Kinetics of phase change. I general theory10.1063/1.1750380 ↗
34. Crystallization kinetics of a solid oxide fuel cell seal glass by differential thermal analysis10.1016/j.jpowsour.2005.01.010 ↗
35. Phase separation and nanocrystallization behavior above crystallization temperature in Mg-Cu-Y metallic glass thin film10.1016/j.tsf.2013.06.092 ↗
36. Crystallization kinetics of As-Sb-S glass in bulk and thin film form10.1016/0022-3093(88)90200-1 ↗
37. Aluminosilicate glass thin films elaborated by pulsed laser deposition10.1016/j.apsusc.2016.11.115 ↗
38. NIH Image to ImageJ: 25 years of image analysis10.1038/nmeth.2089 ↗
39. Distinctive image features from scale-invariant keypoints10.1023/B:VISI.0000029664.99615.94 ↗
40. Trainable Weka Segmentation: a machine learning tool for microscopy pixel classification10.1093/bioinformatics/btx180 ↗
41. A Barium-Calcium Silicate Glass for Use as Seals in Planar SOFCs
42. Sealants for solid oxide fuel cells10.1016/j.jpowsour.2005.05.002 ↗
43. Structural investigations of celsian glass derived from Ba-LTA zeolite10.1039/b009384j ↗
44. Some recent studies on glass/glass-ceramics for use as sealants with special emphasis for high temperature applications10.1007/s40145-012-0009-x ↗
45. 29Si and 27Al MAS-NMR spectroscopy of glasses in the system CaSiO3-MgSiO3-Al2O310.1016/0009-2541(92)90067-F ↗
46. Structure, phase formation, and wetting behaviorof BaO-SiO2-B2O3 based glass-ceramics as sealants for solid oxide fuel cells10.1007/s11581-013-0934-x ↗
47. Crystallization kinetics of a solid oxide fuel cell seal glass by differential thermal analysis, J10.1016/j.jpowsour.2005.01.010 ↗
48. The structure of silicate melts: implications for chemical and physical properties of natural magma10.1029/RG020i003p00353 ↗