journal article·2020-11

The rejuvenation and relaxation around the glass transition of a Ce-based metallic glass controlled by annealing, quenching and cryogenic treatments

Wei Zhang, Kelong Li, Qingchun Xiang, Yinglei Ren, Qingfeng Li, Keqiang Qiu

Publisher page

Abstract

Abstract Ce69Al10Cu20Co1 bulk metallic glass (BMG) samples were annealed at different temperatures ranging from sub-Tg to super-Tg. Some of the samples were cooled to room temperature in air to obtain the relaxed ones, while the others were directly quenched in liquid nitrogen. Then the quenched samples were either withdrawn directly from the liquid nitrogen or subjected to cryogenic treatments (CTs) for different time intervals. The glass transition behaviors and heat flow of the samples in different states, including the as-cast, relaxed, quenched and Quenching+CT states, were investigated by using the differential scanning calorimeter (DSC). The work aims to study the tendency of the rejuvenation and relaxation behaviors of MG around the glass transition that were caused by the annealing, quenching and subsequent cryogenic treatments. The results show that the annealing temperature, cooling rate and cryogenic time play key roles in the rejuvenation and relaxation of MG around the glass transition.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Metallic Glasses and Amorphous Alloys · Material Dynamics and Properties · Glass properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (53)

Show source-provided references
1. Supercooled liquids and the glass transition10.1038/35065704 ↗
2. Unveiling the structural arrangements responsible for the atomic dynamics in metallic glasses during physical aging10.1038/ncomms10344 ↗
3. Atomic-level structure and structure-property relationship in metallic glasses10.1016/j.pmatsci.2010.12.002 ↗
4. Direct observation of local atomic order in a metallic glass10.1038/nmat2897 ↗
5. Evolution of structural and dynamic heterogeneities and activation energy distribution of deformation units in metallic glass10.1063/1.4795522 ↗
6. Structural instability of metallic glass under radio-frequency-ultrasonic perturbation and its correlation with glass-to-crystal transition of less-stale metallic glasses10.1063/1.2346672 ↗
7. Roles of icosahedral and crystal-like order in hard spheres transition10.1038/ncomms1974 ↗
8. Structural feature of Cu64Zr36 metallic glass on nanoscale: densely-packed clusters with loosely-packed surroundings10.1016/j.scriptamat.2015.12.038 ↗
9. Elastic fluctuations and structural heterogeneities in metallic glasses
10. Relaxation in glassforming liquids and amorphous solid10.1063/1.1286035 ↗
11. Thermal rejuvenation in metallic glasses10.1080/14686996.2017.1280369 ↗
12. Modulating heterogeneity and plasticity in bulk metallic glasses: role of interfaces on shear banding10.1016/j.ijplas.2019.03.007 ↗
13. Controlled rejuvenation of amorphous metals with thermal processing10.1038/srep10545 ↗
14. Mechanical relaxation of metallic glasses: an overview of experimental data and theoretical models10.3390/met5021073 ↗
15. Recovering compressive plasticity of bulk metallic glasses by high-temperature creep10.1016/j.scriptamat.2013.06.020 ↗
16. Thermomechanical processing of metallic glasses: extending the range of the glassy state10.1038/natrevmats.2016.39 ↗
17. Extreme rejuvenation and softening in a bulk metallic glass10.1038/s41467-018-02943-4 ↗
18. Cryogenic treatment induced hardening of Cu45Zr45Ag7Al3 bulk metallic glass10.1016/j.physb.2013.10.003 ↗
19. Enhanced strength and plasticity of a Ti-based metallic glass at cryogenic temperatures10.1016/j.msea.2008.08.010 ↗
20. Correlation between atomic structure evolution and strength in a bulk metallic glass at cryogenic temperature10.1038/srep03897 ↗
21. Cryogenic-temperature-induced structural transformation of a metallic glass10.1080/21663831.2016.1263687 ↗
22. Changes in the short-range order and magnetic properties of the amorphous magnetic metal alloy Fe78Cu1Nb4B3.5Si13.5 following cryogenic treatment10.1016/j.physb.2005.07.020 ↗
23. Rejuvenation and plasticization of metallic glass by deep cryogenic cycling treatment10.1016/j.intermet.2017.11.015 ↗
24. Rejuvenation and plasticization of Zr-based bulk metallic glass with various Ta content upon deep cryogenic cycling10.1016/j.jallcom.2019.04.340 ↗
25. The effect of thermal cycling on the fracture toughness of metallic glasses10.1016/j.actamat.2019.11.046 ↗
26. Rejuvenation of metallic glasses by non-affine thermal strain10.1038/nature14674 ↗
27. Microscopic characterization of structural relaxation and cryogenic rejuvenation in metallic glasses10.1016/j.actamat.2018.10.036 ↗
28. Relaxation-to-rejuvenation transition of a Ce-based metallic glass by quenching/cryogenic treatment performed at sub-Tg10.1016/j.jallcom.2020.153997 ↗
29. Formation of cerium-based bulk metallic glasses10.1016/j.actamat.2006.02.044 ↗
30. Thermodynamics and structural relaxation in Ce-based bulk metallic glass-forming liquids10.1016/j.jallcom.2011.01.106 ↗
31. Ehthalpy relaxation and its relation to the thermodynamics and crystallization of the Zr58.5Cu15.6Ni12.8Al10.3Nb2.8 bulk metallic glass-formaing alloy10.1016/j.actamat.2006.09.040 ↗
32. The effect of cooling rates on the apparent fragility of Zr-based bulk metallic glasses10.1063/1.3452381 ↗
33. The viscosity of the Zr46.75Ti8.25Cu7.5Ni10Be27.5 bulk metallic glass forming alloy in the supercooled liquid10.1063/1.114891 ↗
34. Increasing the kinetic stability of bulk metallic glasses10.1016/j.actamat.2015.11.048 ↗
35. Properties of Ce-based bulk metallic glass-forming alloys10.1103/PhysRevB.70.224208 ↗
36. Correlation between relaxations and plastic deformation, and elastic model of flow in metallic glasses and glass-forming liquids
37. Spectroscopy simulation and scattering, and the medium range order problem in glass10.1016/0022-3093(85)90334-5 ↗
38. Formation of glasses from liquids and biopolymers10.1126/science.267.5206.1924 ↗
39. Correlation between enthalpy change and free volume reduction during structural relaxation of Zr55Cu30Al10Ni5 metallic glass10.1016/j.scriptamat.2003.09.038 ↗
40. Abnormal behavior of supercooled liquid region in bulk-forming metallic glasses10.1063/1.3465310 ↗
41. Hidden amorphous phase and reentrant supercooled liquid in Pd-Ni-P metallic glasses10.1038/ncomms14679 ↗
42. Correlation of atomic cluster symmetry and glass-forming ability of metallic glass10.1103/PhysRevLett.99.095501 ↗
43. Correlation between structural relaxation and connectivity of icosahedral clusters in CuZr metallic glass-forming liquids10.1103/PhysRevB.88.054202 ↗
44. Heterogeneous structural changes correlated to local atomic order in thermal rejuvenation process of Cu-Zr metallic glass10.1080/14686996.2019.1624140 ↗
45. Relationship between the enthalpies of structural relaxation, crystallization and melting in metallic glass-forming systems10.1016/j.scriptamat.2019.02.030 ↗
46. The effect of cryogenic thermal cycling on aging, rejuvenation, and mechanical properties of metallic glasses10.1016/j.jnoncrysol.2018.09.041 ↗
47. Atomic origin for rejuvenation of a Zr-based metallic glass at cryogenic temperature10.1016/j.jallcom.2017.05.124 ↗
48. Gamma relaxation in bulk metallic glasses10.1016/j.scriptamat.2017.04.034 ↗
49. Cu45Zr45Al5Ag5 bulk glassy alloy with enhanced compressive strength and plasticity at cryogenic temperature10.2320/matertrans.MRP2007161 ↗
50. Effects of cryogenic temperatures on mechanical behavior of a Zr60Ni25Al15 bulk metallic glass10.1016/j.msea.2013.06.063 ↗
51. Reaction kinetics in differential thermal analysis10.1021/ac60131a045 ↗
52. β relaxation and low-temperature aging in a Au-based bulk metallic glass: from elastic properties to atomic-scale structure10.1103/PhysRevB.89.174204 ↗
53. The effect of low-temperature structural relaxation on free volume and chemical short-range ordering in a Au49Cu26.9Si16.3Ag5.5Pd2.3 bulk metallic glass10.1016/j.scriptamat.2015.02.026 ↗