A simple spin model for three step relaxation and secondary processes in glass formers
Source abstract
Abstract
A number of general trends are known to occur in systems displaying secondary processes in glasses and glass formers. Universal features can be identified as components of large and small cooperativeness whose competition leads to excess wings or apart peaks in the susceptibility spectrum. To the aim of understanding such rich and complex phenomenology we analyze the behavior of a model combining two apart glassy components with a tunable different cooperativeness. The model salient feature is, indeed, based on the competition of the energetic contribution of groups of dynamically relevant variables, e.g., density fluctuations, interacting in small and large sets. We investigate how the model is able to reproduce the secondary processes physics without further ad hoc ingredients, displaying known trends and properties under cooling or pressing.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Material Dynamics and Properties · Theoretical and Computational Physics · Glass properties and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (43)
Show source-provided references
1. Viscous liquids and the glass transition. III. Secondary relaxations in aliphatic alcohols and other nonrigid molecules10.1063/1.1676742 ↗
2. Classification of secondary relaxation in glass-formers based on dynamic properties10.1063/1.1630295 ↗
3. From strong to fragile glass formers: secondary relaxation in polyalcohols10.1103/PhysRevLett.88.095701 ↗
4. Dielectric spectroscopy of glass-forming materials: alpha-relaxation and excess wing10.1016/S0301-0104(02)00549-9 ↗
5. High-frequency dynamics of type b glass formers investigated by broadbanddielectric spectroscopy10.1016/j.jnoncrysol.2010.06.074 ↗
6. Beta relaxation versus high frequency wing in the dielectric spectra of a binary molecular glass former10.1103/PhysRevLett.92.225701 ↗
7. Two glass transitions and secondary relaxations of methyltetrahydrofuran in a binary mixture10.1021/jp110506z ↗
8. Excess wing and Johari–Goldstein relaxation in binary mixtures of glass formers10.1080/14786430600986111 ↗
9. The Johari–Goldstein beta-relaxation of glass-forming binary mixtures10.1016/j.jnoncrysol.2010.08.007 ↗
10. Glassy dynamics in mono-, di- and tri-propylene glycol: From the α- to the fast β-relaxation10.1016/j.jnoncrysol.2009.07.029 ↗
11. Ngai · 2011
12. Is there an excess wing in the dielectric loss of plastic crystals?10.1103/PhysRevLett.82.1951 ↗
13. Excess wing in the dielectric loss of glass formers: further evidence for a beta-relaxation
14. Wong · 1974
15. An extended coupling model description of the evolution of dynamics with time in supercooled liquids and ionic conductors10.1088/0953-8984/15/11/332 ↗
16. Dynamics-of supercooled liquid: excess wings, ss peaks, and rotation–translation coupling10.1088/0953-8984/17/10/003 ↗
17. Nearly logarithmic decay of correlations in glass-forming liquids10.1103/PhysRevLett.92.105701 ↗
18. A universal origin for secondary relaxations in supercooled liquids and structural glasses10.1038/nphys1432 ↗
19. Fast and slow relaxation processes in glasses10.1088/0953-8984/11/10A/010 ↗
20. Diffusion of impurities in a dense fluid near the glass transition10.1103/PhysRevA.33.1254 ↗
21. β relaxation near glass transition singularities10.1088/0953-8984/1/26/014 ↗
22. Leuzzi · 2007
23. Spherical 2+p spin-glass model: an exactly solvable model for glass to spin-glass transition10.1103/PhysRevLett.93.217203 ↗
24. Spherical 2+p spin-glass model: an analytically solvable model with a glass-to-glass transition10.1103/PhysRevB.73.014412 ↗
25. Static and dynamic glass–glass transitions: a mean-field study10.1080/14786430802481911 ↗
26. Amorphous–amorphous transition and the two-step replica symmetry breaking phase10.1103/PhysRevB.76.184417 ↗
27. The complexity of the spherical p-spin spin glass model, revisited10.1140/epjb/e2003-00325-x ↗
28. Equilibrium dynamics of spin-glass systems10.1103/PhysRevB.75.144301 ↗
29. Comment on “spherical 2+p spin-glass model: an analytically solvable model with a glass-to-glass transition”10.1103/PhysRevB.76.136401 ↗
30. The spherical p-spin interaction spin-glass model — the statics10.1007/BF01309287 ↗
31. Reply to “comment on ‘spherical 2+p spin-glass model: an analytically solvable model with a glass-to-glass transition’”10.1103/PhysRevB.76.136402 ↗
32. Statistical dynamics of classical systems10.1103/PhysRevA.8.423 ↗
33. Dynamics as a substitute for replicas in systems with quenched random impurities10.1103/PhysRevB.18.4913 ↗
34. Long time limit of equilibrium glassy dynamics and replica calculation10.1016/j.nuclphysb.2007.11.039 ↗
35. The spherical p-spin interaction spin-glass model — the dynamics10.1007/BF01312184 ↗
36. Mode-coupling approximations, glass theory and disordered systems10.1016/0378-4371(95)00423-8 ↗
37. Götze · 2009
38. Mode coupling as a landau theory of the glass transition10.1209/0295-5075/88/16001 ↗
39. Dynamical model of the liquid–glass transition10.1103/PhysRevA.29.2765 ↗
40. Dynamics of supercooled liquids and the glass transition10.1088/0022-3719/17/33/005 ↗
41. Some aspects of phase transitions described by the self consistent current relaxation theory10.1007/BF01469695 ↗
42. Mean-field soft-spin Potts glass model: statics and dynamics10.1103/PhysRevB.37.5342 ↗
43. Donth · 2001