journal article·2021-02

Formation and properties of soda lime germanate glasses

Rita Slilaty Pipes, James E. Shelby

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Abstract

Abstract The glass formation region has been determined for the soda lime germanate system. This system includes regions of both homogeneous and phase separated glass formation. The density, molar volume, refractive index, molar refractivity, thermal expansion coefficient, glass transformation temperature, and transformation range viscosity have been determined. The homogeneous glasses display behavior typical of the germanate anomaly, with little effect of the replacement of soda by lime. The phase separated glasses exhibit behavior which can be explained by considering the effect of morphology on glass properties.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Glass properties and applications · Material Dynamics and Properties · Mineralogy and Gemology Studies

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References (44)

Show source-provided references
1. Bansal · 1986
2. Shelby · 2020
3. Mazurin · 1977
4. Formation and properties of soda-lime borate glasses
5. The atomic arrangement in glass10.1021/ja01349a006 ↗
6. Study of the series of glasses containing sodium oxide, boric oxide, and silica
7. Thermal expansion of alkali borate glasses10.1111/j.1151-2916.1983.tb10023.x ↗
8. The density of sodium-borate glasses related to atomic arrangements10.1016/S0022-3093(87)80355-1 ↗
9. The density of potassium borate glasses related to atomic arrangements10.1016/S0022-3093(87)80343-5 ↗
10. The density of lithium borate glasses related to atomic arrangements10.1016/0022-3093(86)90076-1 ↗
11. X-ray diffraction study of soda-boric oxide glass10.1111/j.1151-2916.1938.tb15777.x ↗
12. New Evidence on the boron coordination in alkali borate glasses
13. Nuclear magnetic resonance absorption in glass. I. Nuclear quadrupole effects in boron oxide, soda-boric oxide, and borosilicate glasses10.1063/1.1744697 ↗
14. MNR and NQR studies of borates and borides
15. Structure of simple germanate glasses
16. Some physical properties of alkali germanate glasses10.1038/201285a0 ↗
17. Studies in Germanium Oxide Systems: II, Phase Equilibria in the System Na2O-GeO210.1111/j.1151-2916.1964.tb14433.x ↗
18. Viscosity and structure of binary germanate glasses in the range of softening temperatures
19. Viscosity and thermal expansion of alkali germanate glasses10.1111/j.1151-2916.1974.tb11376.x ↗
20. Significance of intermediate range structure for electrical conduction in alkali germanate glasses10.1016/S0022-3093(97)90137-X ↗
21. Investigation of coordination number in silicate and germanate glasses using O K-edge X-ray absorption10.1016/j.chemgeo.2004.08.029 ↗
22. The germanate anomaly: Is the presence of five- or six-fold Ge Important?
23. The structure of glass along the Na2O-GeO2 join10.1016/0022-3093(91)90384-I ↗
24. Germanium coordination and the germanate anomaly10.1127/0935-1221/2002/0014-0733 ↗
25. The germanate anomaly: what do we know?10.1016/j.jnoncrysol.2007.02.037 ↗
26. The structure of potassium germanate glasses as revealed by Raman and IR spectroscopy10.1016/j.jnoncrysol.2019.01.017 ↗
27. Effect of morphology on the properties of alkaline earth silicate glasses10.1063/1.325986 ↗
28. Phase separation and the properties of lithium calcium silicate glasses
29. Properties and structures of RO-GeO2 glasses10.1111/j.1151-2916.1983.tb10072.x ↗
30. Phase separation in germanate glasses10.1016/0022-3093(88)90422-X ↗
31. The germanate anomaly in alkaline earth germanate glasses10.1021/acs.jpcc.6b12372 ↗
32. Properties and morphology of sodium lead germanate glasses
33. Nesse · 2012
34. Non-isothermal devitrification of sodium germanate glasses10.1016/S0040-6031(03)00089-3 ↗
35. Mazurin · 1984
36. Tomozawa · 1979 · Vol. 17 · 71
37. Q speciation in alkali germanate glasses10.1016/j.jnoncrysol.2010.03.023 ↗
38. Elastic constants of homogeneous and phase separated Na2O-CaO-SiO2 Glasses
39. A systematic investigation into the influence of sodium oxide additives on the viscosity of vitreous germanium oxide
40. Ge-O coordination in cesium germanate glasses10.1021/jp066714z ↗
41. Thermal expansion of mixed alkali germanate glasses10.1063/1.321318 ↗
42. Properties and structure of lithium germanate glasses
43. Inert gas solubility in binary germania-silica glasses10.1016/j.jnoncrysol.2004.08.144 ↗
44. Shelby · 1996