Between glass and gas: Thermodynamics of liquid matter
Source abstract
Abstract
Abstract We show that disorder is not a great obstacle for calculating thermodynamic properties of liquids. We discuss recent experimental, theoretical and modelling results related to excitations in liquids, and demonstrate how these data help to understand liquid thermodynamics. An important insight is the understanding that changes of thermodynamic properties of liquids are governed only by its average interatomic separation.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Material Dynamics and Properties · Phase Equilibria and Thermodynamics · Advanced Thermodynamics and Statistical Mechanics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (37)
Show source-provided references
1. Landau · 1969
2. Ziman · 1995
3. Boon · 1980
4. March · 1990
5. March · 1991
6. Zwanzig · 2001
7. Barrat · 2003
8. Hansen · 2013
9. The specific heat of simple liquids10.1016/S0022-3093(02)01498-9 ↗
10. Elementary excitations and crossover phenomenon in liquids10.1103/PhysRevLett.110.205504 ↗
11. Landau–Placzek ratio for heat density dynamics and its application to heat capacity of liquids10.1063/1.4774406 ↗
12. Landau · 1976
13. Anharmonic decay of vibrational states in amorphous silicon10.1103/PhysRevLett.77.3839 ↗
14. Diffusons, locons and propagons: character of atomic vibrations in amorphous Si10.1080/13642819908223054 ↗
15. Frenkel · 1947
16. Colloquium: the glass transition and elastic models of glass-forming liquids10.1103/RevModPhys.78.953 ↗
17. Phonon spectroscopy by inelastic X-ray scattering10.1088/0034-4885/63/2/203 ↗
18. State dependent particle dynamics in liquid alkali metals10.1088/0953-8984/18/37/R01 ↗
19. Shear-waves through the glass–liquid transformation10.1103/PhysRevLett.62.2616 ↗
20. Fingerprints of order and disorder on the high-frequency dynamics of liquids10.1073/pnas.1006319107 ↗
21. Inelastic X-ray scattering study of liquid Ga: implications for the short-range order10.1103/PhysRevB.84.052201 ↗
22. Transverse acoustic excitations in liquid Ga10.1103/PhysRevLett.102.105502 ↗
23. High frequency dynamics in liquids and supercritical fluids: a comparative inelastic X-ray scattering study10.1088/0953-8984/11/24/202 ↗
24. Microscopic relaxation in supercritical and liquid neon10.1063/1.1334613 ↗
25. The Widom line as the crossover between liquid-like and gas-like behaviour in supercritical fluids10.1038/nphys1683 ↗
26. Evidence of anomalous dispersion of the generalized sound velocity in glasses10.1103/PhysRevB.69.100201 ↗
27. Thermal conductivity and terahertz vibrational dynamics of vitreous silica10.1103/PhysRevB.77.214309 ↗
28. Role of disorder in the thermodynamics and atomic dynamics of glasses10.1103/PhysRevLett.112.025502 ↗
29. Duality of liquids10.1038/srep02188 ↗
30. Heat capacity at the glass transition10.1103/PhysRevB.83.014201 ↗
31. Heat capacity of liquids: an approach from the solid phase10.1103/PhysRevB.78.104201 ↗
32. The phonon theory of liquid thermodynamics10.1038/srep00421 ↗
33. The heat capacity of matter beyond the Dulong–Petit value10.1088/0953-8984/25/23/235401 ↗
34. Thermodynamic behaviour of supercritical matter10.1038/ncomms3331 ↗
35. What separates a liquid from a gas?10.1063/PT.3.1796 ↗
36. Two liquid states of matter: a dynamic line on a phase diagram10.1103/PhysRevE.85.031203 ↗
37. “Liquid–gas” transition in the supercritical region: fundamental changes in the particle dynamics10.1103/PhysRevLett.111.145901 ↗