Optical absorption and structure of impurity Ni2+ center in tungstate–tellurite glass

Absorption spectra of Ni$²⁺$ ions in 22WO$_3$--78TeO$_2$ tungstate-tellurite glass were studied and Ni$²⁺$ extinction coefficient spectral dependence was derived in the 450 -- 2700 nm wavelength range. Computer modeling of the glass structure proved Ni$²⁺$ ions to be in trigonal-distorted octahedral environment in the tungstate-tellurite glass. Tanabe-Sugano diagram for such an environment was calculated and good description of the observed spectrum of Ni$²⁺$ ion was obtained. Basing on both absorption spectral range width and the extinction coefficient, nickel should be considered among the most strongly absorbing impurities in the tellurite glasses.