journal article·2015-02

EXAFS studies of the local structure of bismuth centers in multicomponent silica glass based optical fiber preforms

S. Torrengo, M.C. Paul, A. Halder, S. Das, A. Dhar, J.K. Sahu, S. Jain, A.V. Kir'yanov, F. d'Acapito

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Abstract

An Extended X-ray Absorption Fine Structure (EXAFS) analysis of the local structure of bismuth in silicate-glass based opticalfiber preforms exhibiting broadband near-infrared luminescence is presented. The valence state of the bismuth ions in alumino-silicate and yttria-alumino-silicate glass hosts is revealed to be Bi 3+ and the local geometry is suggested to be a trigonal oxygen pyramid with the electron lone pair positioned opposite to the oxygen atom plane. Furthermore we found that the incorporation of Y2O3into alumino-silicate glass host does not result in any change in the surrounding Bi structure
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Glass properties and applications · Luminescence Properties of Advanced Materials · Phase-change materials and chalcogenides

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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