journal article·2004-11

The fused silicate route to protoimogolite and imogolite

Ji Hu, G.S. Kamali Kannangara, Michael A. Wilson, Narsimha Reddy

Journal of Non-Crystalline Solids· Volume 347· Issue 1-3
Publisher page

Abstract

Abstract The formation of imogolite from protoimogolite from fused sodium silicate and aluminum perchlorate has been investigated. It is shown that the initial solutions prepared by this method are different from those from hydrolyzed solutions of tetraethoxysilane, so the mechanism of protoimogolite formation is different. Species with isolated silicon tetrahedral (Q33Al) are present much earlier in the fused silicate process than in the tetraethoxysilane reaction. Kinetic studies do show however that once protoimogolite is formed the two reaction mixtures crystallize imogolite in the same way.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Clay minerals and soil interactions · Crystal Structures and Properties · Iron oxide chemistry and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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