journal article·2023-04

Pressure-driven relaxation processes in nanocomposite ionic glass LiFe0.75V0.10PO4

Szymon Starzonek, Aleksander Szpakiewicz-Szatan, Sylwester J. Rzoska, Aleksandra Drozd-Rzoska, Michał Boćkowski, Tomasz K. Pietrzak, Jerzy E. Garbarczyk

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Abstract

This paper presents results for systems formed in a solid glassy state after nanocrystallization process above the glass temperature. We analyze electric conductivity and relaxation processes after such treatment under high temperature (HT) and high pressure (HP-HT) as well. The latter leads to ca. 8% increase of density, two decades (100) increase of electric conductivity as well as qualitative changes in relaxation processes. The previtreous-type changes of the relaxation time on cooling is analyzed by the use of critical-like and the 'critical-activated' description. Presented results correspond well with obtained for this material and shown in ref. [8]. The evidence for pressure evolution of the glass and crystallization temperatures, indicating the unique possibility of maxima and crossovers is also reported.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Glass properties and applications · Metallic Glasses and Amorphous Alloys · Material Dynamics and Properties

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