journal article·2024-12

Excellent magnetocaloric effect near the hydrogen liquefaction temperature of a binary Er67.5Co32.5 metallic glass

P.J. Wang, Q. Wang, J.M. Yuan, T.G. Zhai, Z.B. Li, D. Ding, L. Xia

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Abstract

We reported the excellent magnetocaloric effect of a binary Er 67.5Co 32.5 metallic glass (MG) near the hydrogen liquefaction temperature. The binary MG ribbon was fabricated by a melt-spinning method. The Er 67.5Co 32.5 alloy exhibits a better glass formability than most of other rare earth (RE)-Co binary alloys. The maximum magnetic entropy change ( −Δ Smpeak) and refrigeration capacity ( RC) of the Er 67.5Co 32.5 amorphous ribbon under 0–5 T reach to 17.47 J/(kg × K) near its Curie temperature ( Tc, ∼ 11 K) and 472 J/kg, both of which are rather high among the RE-based MGs with a Tc around 10 K and imply the potential application perspective as magnetic refrigerants for hydrogen liquefaction. The magnetization as well as magnetocaloric behaviors of the binary MG were observed, and the mechanism involved was investigated.
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Research context

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Magnetic Properties of Alloys · Metallic Glasses and Amorphous Alloys

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. Theoretical aspects of the magnetocaloric effect10.1016/j.physrep.2009.12.006 ↗
2. Magnetocaloric effect and magnetic refrigeration10.1016/S0304-8853(99)00397-2 ↗
3. Developments in magnetocaloric refrigeration10.1088/0022-3727/38/23/R01 ↗
4. Magnetic refrigeration in the temperature range from 10 K to room temperature: the ferromagnetic refrigerants10.1016/0011-2275(81)90254-X ↗
5. Magnetocaloric effect: from materials research to refrigeration devices10.1016/j.pmatsci.2017.10.005 ↗
6. Recent developments in magnetocaloric materials10.1088/0034-4885/68/6/R04 ↗
7. Recent progress in exploring magnetocaloric materials10.1002/adma.200901072 ↗
8. Magnetic refrigerator for hydrogen liquefaction10.1016/j.cryogenics.2014.03.016 ↗
9. Large reversible magnetocaloric effects in ErFeSi compound under low magnetic field change around liquid hydrogen temperature
10. Enhanced magnetocaloric effect in Gd3Ga5−xFexO1210.1063/1.352443 ↗
11. Magnetic method of magnetocaloric effect determination in high pulsed magnetic fields10.1016/S0304-8853(96)00688-9 ↗
12. Magnetic nanocomposites for magnetic refrigeration10.1016/0965-9773(93)90027-9 ↗
13. New application of complex magnetic materials to the magnetic refrigerant in an Ericsson magnetic refrigerator10.1063/1.339232 ↗
14. Specific heat and entropy of RNi2 (R: Rare Earth Heavy Metals) in magnetic field
15. Low-temperature reversible giant magnetocaloric effect in the HoCuAl compound
16. Large reversible magnetocaloric effect in DyCuAl compound10.1063/1.3122598 ↗
17. Magnetic properties and magnetocaloric effects in amorphous and crystalline GdCuAl ribbons10.1016/j.ssc.2008.12.006 ↗
18. Magnetism and large magnetocaloric effect in GdNiBC compound
19. Recent progresses in exploring the rare earth based intermetallic compounds for cryogenic magnetic refrigeration10.1016/j.jallcom.2020.153810 ↗
20. Rare earth based bulk metallic glasses10.1016/j.jnoncrysol.2009.02.006 ↗
21. Magnetocaloric effect in rare earth-based bulk metallic glasses10.1016/j.jallcom.2010.01.125 ↗
22. Giant magnetocaloric effect in Tm-based bulk metallic glasses10.1016/j.jnoncrysol.2012.09.020 ↗
23. Magnetocaloric effect of Ho-, Dy-, and Er-based bulk metallic glasses in helium and hydrogen liquefaction temperature range10.1063/1.2741120 ↗
24. Under what conditions can a glass be formed?10.1080/00107516908204405 ↗
25. A new glass-forming ability criterion for bulk metallic glasses10.1016/S1359-6454(02)00166-0 ↗
26. Formability and magnetic properties of Dy-Co binary amorphous alloys10.1063/1.5037357 ↗
27. Magnetoelastic and magnetocaloric properties of Tb62.5Co37.5 amorphous alloy10.1016/j.jallcom.2017.09.052 ↗
28. Formability and magnetic properties of the binary Nd- Co amorphous alloys10.3390/met11111730 ↗
29. Irreversible and reversible magnetic entropy change in a Dy-based bulk metallic glass10.1016/j.intermet.2012.03.034 ↗
30. Giant irreversible positive to large reversible negative magnetic entropy change evolution in Tb-based bulk metallic glass10.1103/PhysRevB.82.024204 ↗
31. Tuning the magnetocaloric response of Er-based metallic glasses by varying structural order in disorder10.1016/j.jmmm.2015.10.063 ↗
32. Generalized Curie-Weiss law10.1103/PhysRevB.31.2851 ↗
33. New model for amorphous magnetism10.1103/PhysRevLett.31.160 ↗
34. On a generalized approach to first and second order magnetic transitions10.1016/0031-9163(64)91158-8 ↗
35. Weak exchange effect and large refrigerant capacity in a bulk metallic glass Gd0.32Tb0.26Co0.20Al0.22
36. A Dy-based bulk metallic glass with high thermal stability and excellent magnetocaloric properties10.1016/j.jallcom.2007.09.041 ↗
37. Magnetocaloric effect in Er-Al-Co bulk metallic glasses10.1007/s11434-011-4855-7 ↗
38. High-entropy bulk metallic glasses as promising magnetic refrigerants10.1063/1.4908286 ↗
39. Cryogenic magnetic properties of Er60Ni30Co10 amorphous ribbon10.1016/j.jnoncrysol.2018.01.010 ↗
40. Scaling laws for the magnetocaloric effect in second order phase transitions: from physics to applications for the characterization of materials10.1016/j.ijrefrig.2009.12.019 ↗
41. Field dependence of the magnetocaloric effect in materials with a second order phase transition: a master curve for the magnetic entropy change10.1063/1.2399361 ↗
42. Magnetocaloric materials10.1146/annurev.matsci.30.1.387 ↗