Effect of the Na/Mg mixing on the structure and properties of aluminosilicate melts
Source abstract
Abstract
Na/Mg mixing in aluminosilicates causes non-linear variations in their properties. Entropy is not modelled by an ideal mixing law but by a sub-regular solution model. Na and Mg are preferably arranged in sub-networks, reducing structural disorder. Preferential role-sharing as network modifier and charge compensator between Na/Mg. Extending sub-regular model and role-sharing to all alkaline/alkaline-earth mixing.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Glass properties and applications · Clay minerals and soil interactions · Recycling and utilization of industrial and municipal waste in materials production
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Dynamics of magma ascent in the volcanic conduit
2. 2019
3. On the vesicularity of pumice
4. Fragmentation of magma during Plinian volcanic eruptions10.1007/s004450050132 ↗
5. Magma Fragmentation10.1146/annurev-earth-060614-105206 ↗
6. Industrial Glass Processing and Fabrication10.1007/978-3-319-93728-1_34 ↗
7. The viscosity of magmatic silicate liquids : a model for calculation10.2475/ajs.272.5.438 ↗
8. Viscosity of magmatic liquids: a model10.1016/j.epsl.2008.03.038 ↗
9. Topological model for the viscosity of multicomponent glass-forming liquids10.1111/ijag.12009 ↗
10. Molecular structure, configurational entropy and viscosity of silicate melts: link through the Adam and Gibbs theory of viscous flow10.1016/j.jnoncrysol.2017.02.010 ↗
11. Revealing the relationship between liquid fragility and medium-range order in silicate glasses10.1038/s41467-022-35711-6 ↗
12. The mixed alkali effect in glass10.1016/0022-3093(69)90003-9 ↗
13. Mixed alkali glasses - Their properties and uses10.1016/0022-3093(76)90026-0 ↗
14. Neutralization reduction of electrical conductivity in silica glasses
15. Empirical relation between self-diffusion and electrical conduction in mixed-alkali glasses10.1111/j.1151-2916.1974.tb11359.x ↗
16. The mixed alkali effect in the Na20-Cs20-SiO2 glasses10.1016/0022-3093(71)90051-2 ↗
17. Effect of Na2O/K2O ratio on chemical durability of alkali-lime-silica glasses10.1111/j.1151-2916.1955.tb14924.x ↗
18. Mixed alkaline earth effect in sodium aluminosilicate glasses10.1016/j.jnoncrysol.2013.03.015 ↗
19. Mechanical properties of mixed modified oxide glasses
20. Improved apparatus for measuring viscosity of glasses in annealing range of temperature10.1111/j.1151-2916.1949.tb18950.x ↗
21. Viscosity and configurational entropy of silicate melts10.1016/0016-7037(84)90275-8 ↗
22. Structure and properties in (Sr, Na) silicate glasses and melts
23. Viscosity, structure and mixing in (Ca, Na) silicate melts10.1016/j.chemgeo.2006.01.008 ↗
24. Resolving the mixed-alkali effect on the viscoelastic behavior of supercooled liquids10.1016/j.actamat.2022.118447 ↗
25. Silicate Glasses10.1007/978-3-319-93728-1_13 ↗
26. Viscosity and mixing in molten (Ca, Mg) pyroxenes and garnets10.1016/0016-7037(91)90159-3 ↗
27. On the temperature dependence of cooperative relaxation properties in glass forming liquids10.1063/1.1696442 ↗
28. Variation of viscosity with temperature and composition in the plagioclase system10.1007/BF00373044 ↗
29. Link between medium and long-range order and macroscopic properties of silicate glasses and melts10.2138/rmg.2022.87.03 ↗
30. Méthodes d'analyse des verres10.1051/mattech/2022041 ↗
31. Anorthite, andesine, wollastonite, diopside, cordierite and pyrope: thermodynamics of melting, glass transitions, and properties of the amorphous phases10.1016/0012-821X(84)90179-1 ↗
32. P. Richet, Y. Bottinga, Glass transitions and thermodynamie properties of amorphous Si02, NaA1Sin02n+2 and KAlSi308, (1984).
33. Heat capacity of aluminium-free liquid silicates10.1016/0016-7037(85)90039-0 ↗
34. Heat capacity of silicate glasses10.1016/0009-2541(87)90062-3 ↗
35. Heat capacity of magnesium aluminosilicate melts10.1016/0016-7037(93)90063-3 ↗
36. Viscosité et entropie des silicates fondus
37. Thermodynamics of silicate melts: configurational properties
38. Cation distribution in mixed alkali disilicate glasses10.1021/ja953918c ↗
39. Ca-Mg and K-Mg mixing around non-bridging O atoms in silicate glasses: an investigation using 17O MAS and 3QMAS NMR10.2138/am-2004-5-611 ↗
40. Structure and the extent of disorder in quaternary (Ca-Mg and Ca-Na) aluminosilicate glasses and melts10.2138/am.2005.1843 ↗
41. Effect of the Na/K mixing on the structure and the rheology of tectosilicate silica-rich melts10.1016/j.chemgeo.2012.09.009 ↗
42. Percolation channels: a universal idea to describe the atomic structure and dynamics of glasses and melts10.1038/s41598-017-16741-3 ↗
43. Structure and properties of alkali aluminosilicate glasses and melts: insights from deep learning10.1016/j.gca.2021.08.023 ↗
44. Chemical order in mixed-cation silicate glasses and melts10.1103/PhysRevB.68.214206 ↗
45. The effect of network-modifying cations on the structure and disorder in peralkaline Ca–Na aluminosilicate glasses: O-17 3QMAS NMR study10.1016/j.chemgeo.2008.07.019 ↗
46. Field strength of network-modifying cation dictates the structure of (Na-Mg) Aluminosilicate Glasses10.3389/fmats.2020.00267 ↗
47. Probing the structure of Fe-free model basaltic glasses: a view from a solid-state 27Al and 17O NMR study of Na-Mg silicate glasses, Na2O-MgO-Al2O3-SiO2 glasses, and synthetic Fe-free KLB-1 basaltic glasses10.1016/j.gca.2018.07.032 ↗
48. C. Le Losq, Rampy: a Python library for processing spectroscopic (IR, Raman, XAS...) data., (2018). https://doi.org/10.5281/zenodo.4715040.
49. PyTorch: an imperative style, high-performance deep learning library
50. D.P. Kingma, J. Ba, Adam: a method for stochastic optimization, (2017). http://arxiv.org/abs/1412.6980 (accessed July 20, 2023).
51. High-resolution aluminum-27 NMR of aluminosilicates10.1021/ja00268a002 ↗
52. Iterative baseline correction algorithm for dead time truncated one-dimensional solid-state MAS NMR spectra10.1016/j.ssnmr.2020.101699 ↗
53. Modelling one- and two-dimensional solid-state NMR spectra10.1002/mrc.984 ↗
54. General models for the distributions of electric field gradients in disordered solids
55. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides10.1107/S0567739476001551 ↗
56. Universal link between the boson peak and transverse phonons in glass10.1038/nmat2293 ↗
57. Low-frequency modes in vitreous silica10.1103/PhysRevB.34.5665 ↗
58. Equivalence of the boson peak in glasses to the transverse acoustic van hove singularity in crystals10.1103/PhysRevLett.106.225501 ↗
59. Hyper-raman scattering observation of the boson peak in vitreous silica10.1103/PhysRevLett.84.5355 ↗
60. Nature of the Boson peak of silica glasses from hyper-Raman scattering10.1016/S0022-3093(02)01444-8 ↗
61. The nature of boson peak in Raman scattering in glasses10.1016/0038-1098(86)90854-9 ↗
62. Low-frequency Raman scattering in binary silicate glass: boson peak frequency and its general expression10.2109/jcersj2.121.1012 ↗
63. Phonons in AX2 glasses: from molecular to band-like modes10.1103/PhysRevB.15.4030 ↗
64. Theory for the first-order vibrational spectra of disordered solids10.1103/PhysRevB.17.1928 ↗
65. Structural studies of silicate glasses and melts-applications and limitations of Raman spectroscopy
66. Raman spectroscopic investigation of sodium borosilicate glass structure10.1007/BF02402831 ↗
67. Raman response of network modifier cations in alumino-silicate glasses10.1021/jp5116299 ↗
68. Non network-former cations in oxide glasses spotted by Raman scattering10.1039/D0CP00630K ↗
69. Raman spectroscopic investigation of the structure of silicate glasses. I. The binary alkali silicates10.1063/1.431671 ↗
70. Raman spectroscopic investigation of the structure of silicate glasses (II). Soda-alkaline earth-alumina ternary and quaternary glasses10.1016/0022-3093(77)90009-6 ↗
71. Anionic constitution of 1-atmosphere silicate melts: implications for the structure of igneous melts10.1126/science.208.4450.1371 ↗
72. Curve-fitting of Raman spectra of silicate glasses
73. The structure of silicate melts: implications for chemical and physical properties of natural magma10.1029/RG020i003p00353 ↗
74. A Raman spectroscopic study of glasses along the joins silica-calcium aluminate, silica-sodium aluminate, and silica-potassium aluminate10.1016/0016-7037(82)90182-X ↗
75. A Raman spectroscopic study of glasses in the system CaO-MgO-Si02
76. Al coordination and speciation in calcium aluminosilicate glasses: effects of composition determined by 27Al MQ-MAS NMR and Raman spectroscopy10.1016/j.chemgeo.2006.01.019 ↗
77. Atomic structure and physical properties of peridotite glasses at 1 bar10.3389/feart.2023.1040750 ↗
78. The structural groups of alkali silicate glasses determined from 29Si MAS-NMR10.1016/0022-3093(91)90400-Z ↗
79. Vibrational properties of silica species in MgO–SiO2 glasses obtained from ab initio molecular dynamics10.1016/j.chemgeo.2012.08.020 ↗
80. Water solution mechanism in calcium aluminosilicate glasses and melts: insights from in and ex situ Raman and 29 Si NMR spectroscopy10.5802/crgeos.127 ↗
81. Intensity of raman band in silicate glasses10.1016/0022-3093(90)90302-3 ↗
82. The influence of modifier cations on the Raman stretching modes of Qn species in alkali silicate glasses10.1111/jace.17081 ↗
83. Spectral resolution and Raman Q3 and Q2 cross sections in ∼40 mol% Na2O glasses10.1016/j.chemgeo.2020.120040 ↗
84. Role of Al in depolymerized, peralkaline aluminosilicate melts in the systems Li2O-AlrO3-SiO2o NarO-AlrO3-SiO2, and K2O-AI2O3-SiO2
85. Role of aluminium in the silicate network: in situ, high-temperature study of glasses and melts on the join SiO2-NaAlO210.1016/0016-7037(96)00049-X ↗
86. Advances in Raman spectroscopy applied to Earth and material sciences10.2138/rmg.2013.78.13 ↗
87. From short to medium range order in glasses and melts by diffraction and Raman spectroscopy10.2138/rmg.2022.87.02 ↗
88. Effects of temperature on the structures of silicate liquids: 29Si NMR results10.1016/0016-7037(88)90034-8 ↗
89. Structure of silicate melts at high temperature: in-situ measurements in the system BaO-SiO2 to 1669°C
90. Structure of Aluminosilicate Melts10.2355/isijinternational.ISIJINT-2021-100 ↗
91. Determination of the aluminium coordination in aluminium-oxygen compounds by solid-state high-resolution 27AI NMR10.1016/0009-2614(81)85288-8 ↗
92. 27Al NMR studies of aluminosilicate solutions. Influences of the second coordination sphere on the shielding of aluminium10.1016/0009-2614(81)85362-6 ↗
93. Solid-state high-resolution silicon-29 chemical shifts in silicates10.1021/j150652a015 ↗
94. Investigation of the structure of zeolites by solid-state high-resolution silicon-29 NMR spectroscopy10.1021/ja00407a002 ↗
95. A “sub-regular” solution model and its application to some binary alloy systems10.1016/0001-6160(53)90059-5 ↗
96. Prausnitz · 1998
97. A Mathematical Theory of Communication10.1002/j.1538-7305.1948.tb01338.x ↗
98. Modification of silicate structural units by K2O for enhancing automobile windshield glass properties10.1016/j.jpcs.2023.111523 ↗
99. Extent of disorder in magnesium aluminosilicate glasses: insights from 27Al and 17O NMR10.1021/acs.jpcc.5b10799 ↗
100. 23Na NMR chemical shifts and local Na coordination environments in silicate crystals, melts and glasses10.1007/BF00215100 ↗