A method locating Cu-Ti-based glass formers using Ni-Zr binary clusters
Source abstract
Abstract
Formation abilities and mechanical properties are essential for the application of amorphous alloys. In this work, the concept of similar elements has been expanded to similar clusters. Firstly, taking the topologically dense packed clusters Ni-Ni 6Zr 6 from the Ni-Zr system as the basic structural unit, a series of Cu-Ti-based alloy compositions with high formation ability are parsed and designed. The best composition is Cu 46.15Ni 7.69Ti 32.70Zr 13.46 with the cluster expression of Ni-Cu 6Zr 1.75Ti 4.25 . Then, the amorphous formation abilities are analyzed from the perspective of the packing degree of clusters and the mixing entropies. Secondly, the crystallization activation energies for characteristic temperatures deduced by Kissinger`s approach are analyzed. Finally, the plasticity of Cu-Ti-based amorphous alloys is investigated and Cu 46.15Ni 7.69Ti 32.70Zr 13.46 exhibits outstanding fracture strength of 2168 MPa. The results in this paper lay the foundation for further exploration of amorphous alloys with high formation ability, good thermal stability, and high compressive plasticity.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Metallic Glasses and Amorphous Alloys
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (50)
Show source-provided references
1. Data-driven discovery of a universal indicator for metallic glass forming ability10.1038/s41563-021-01129-6 ↗
2. Atomic-scale icosahedral short-range ordering in a rejuvenated Zr-based bulk metallic glass upon deep cryogenic treatment10.1016/j.msea.2022.143565 ↗
3. Detailed structural analysis of amorphous Pd40Cu40P20: comparison with the metallic glass Pd40Cu40P20 from the viewpoint of glass forming ability10.1016/j.jnoncrysol.2020.120536 ↗
4. Thermodynamic and kinetic interpretation of the glass-forming ability of Y-containing Cu-Zr-Al bulk metallic glasses10.1016/j.jnoncrysol.2021.121266 ↗
5. A fractal structural feature related to dynamic crossover in metallic glass-forming liquids10.1039/D2CP04840J ↗
6. Composition dependence in glass-forming ability of Cu-Ag binary alloys10.1016/j.actamat.2022.118059 ↗
7. Microstructure and mechanical properties of lightweight Ti3Zr1.5NbVAlx (x = 0, 0.25, 0.5 and 0.75) refractory complex concentrated alloys10.1016/j.jmst.2022.05.005 ↗
8. Effect of Zn on glass-forming capacity and corrosion resistance of Ca-based amorphous alloys10.1016/j.jnoncrysol.2022.121713 ↗
9. Machine learning prediction of the critical cooling rate for metallic glasses from expanded datasets and elemental features10.1021/acs.chemmater.1c03542 ↗
10. Metallic glasses from “alchemy” to pure science: present and future of design, processing and applications of glassy metals10.1016/j.matdes.2011.09.028 ↗
11. The formation of glasses in Zr-Cu(Co, Ni)-Al systems: development of a combined thermodynamics and geometrical model10.1016/j.intermet.2022.107773 ↗
12. A design of Zr-rich body-centered cubic structured refractory complex concentrated alloy with outstanding tensile strength and ductility10.1016/j.msea.2023.145091 ↗
13. Calculation assisted composition design of Fe-based amorphous alloys10.1016/j.jnoncrysol.2022.122011 ↗
14. Predicting glass properties by using physics- and chemistry-informed machine learning models10.1016/j.jnoncrysol.2022.121511 ↗
15. Atomic-scale Nb heterogeneity induced icosahedral short-range ordering in metallic glasses10.1016/j.jmst.2021.08.046 ↗
16. Bulk amorphous powder cores with low core loss by spark-plasma sintering Fe76Si9.6B8.4P6 amorphous powder with small amounts of SiO210.1016/j.jallcom.2015.05.139 ↗
17. Multiscale manufacturing of amorphous alloys by a facile electrodeposition approach and their property dependence on the local atomic order10.1021/acsami.0c22153 ↗
18. Energetically deposited cluster assembly of metallic glasses10.1016/j.actamat.2022.118152 ↗
19. Cluster-based composition interpretation of dual-phase glass-crystal alloys via the example of Mg49Cu42Y910.1016/j.jnoncrysol.2021.120886 ↗
20. Deciphering how anion clusters govern lithium conduction in glassy thiophosphate electrolytes through machine learning10.1021/acsenergylett.3c00237 ↗
21. The bakerian lecture, 1962 the structure of liquids
22. Efficient local packing in metallic glasses10.1016/j.jnoncrysol.2004.05.017 ↗
23. The efficient cluster packing model – an atomic structural model for metallic glasses10.1016/j.actamat.2006.06.002 ↗
24. The influence of efficient atomic packing on the constitution of metallic glasses10.1080/1478643031000098828 ↗
25. From clusters to phase diagrams: composition rules of quasicrystals and bulk metallic glasses10.1088/0022-3727/40/15/R01 ↗
26. Zr–Cu–Ni–Al bulk metallic glasses with superhigh glass-forming ability10.1016/j.actamat.2008.11.007 ↗
27. A new method locating good glass-forming compositions10.1016/j.jallcom.2015.05.184 ↗
28. Understanding and designing good glass formers in Zr-Al-Co-(Nb) system combining clusters and mixing entropy10.1016/j.matlet.2018.09.124 ↗
29. Formation of a Ni- and Be-free Zr-based glassy alloy in centimeter scale10.1016/j.matlet.2021.129383 ↗
30. Glass formation in Zr–Al–Fe–Cu system10.1016/j.matlet.2015.05.142 ↗
31. Zr–Al–Ni amorphous alloys with high glass transition temperature and significant supercooled liquid region10.2320/matertrans1989.31.177 ↗
32. Glass forming ability, structure and properties of Ti and Zr-intermetallic compound based alloys10.4028/www.scientific.net/KEM.40-41.319 ↗
33. A highly processable metallic glass: Zr41.2Ti13.8Cu12.5Ni10.0Be22.510.1063/1.110520 ↗
34. Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element10.2320/matertrans.46.2817 ↗
35. A valence electron concentration criterion for glass-formation ability of metallic liquids10.1063/1.1571984 ↗
36. Free volume theories of the glass transition and the special case of metallic glasses10.1007/BF00553936 ↗
37. Stabilization of metallic supercooled liquid and bulk amorphous alloys10.1016/S1359-6454(99)00300-6 ↗
38. A new approach to understanding and measuring glass formation in bulk amorphous materials10.1016/j.intermet.2004.04.032 ↗
39. Glass formation criterion for various glass-forming systems10.1103/PhysRevLett.91.115505 ↗
40. A new criterion for evaluating the glass-forming ability of bulk metallic glasses10.1016/j.msea.2006.06.053 ↗
41. A new criterion for evaluating the glass-forming ability of bulk glass forming alloys10.1016/j.jallcom.2007.05.037 ↗
42. A new criterion for predicting the glass-forming ability of bulk metallic glasses10.1016/j.jallcom.2008.07.087 ↗
43. Reaction kinetics in differential thermal analysis10.1021/ac60131a045 ↗
44. Enhanced mechanical properties of Zr-Cu-Al-Ni bulk amorphous alloys by Ag and O doping10.1016/j.jallcom.2023.170186 ↗
45. Mechanical properties and non-isothermal crystallization kinetics of novel Ti-based high-entropy bulk metallic glasses10.1016/j.jmrt.2023.02.102 ↗
46. Effect of isothermal annealing on microstructure evolution and mechanical properties of Zr50Cu34Al8Ag8 amorphous alloy10.1016/j.jnoncrysol.2023.122153 ↗
47. Temperature rise at shear bands in metallic glasses10.1038/nmat1536 ↗
48. A microscopic mechanism for steady state inhomogeneous flow in metallic glasses10.1016/0001-6160(77)90232-2 ↗
49. Difference in compressive and tensile fracture mechanisms of Zr59Cu20Al10Ni8Ti3 bulk metallic glass10.1016/S1359-6454(02)00521-9 ↗
50. Effect of Nb on glass forming ability and plasticity of (Ti–Cu)-based bulk metallic glasses10.1016/j.msea.2010.01.058 ↗