Newly-developed pseudo-high entropy amorphous alloys: Structure/microstructure evolution, mechanical and corrosion properties.
Source abstract
Abstract
International audience ; The influence of devitrification on microstructure, corrosion, and mechanical properties of two new FeCrMoNbB and FeCrMoNiB pseudo-high entropy (PHE) amorphous alloys have been investigated to be used as coatings. Amorphous ribbons produced by melt spinning were heat-treated to simulate crystallization. Amounts of amorphous phases were kept at high temperatures and crystallized in multi-principal element bcc or FCC phases and borides. A 500 μm thick physically simulated coating of commercial-grade precursors using spray forming was produced to infer their viability. The Nb-PHE alloy's coating was nearly amorphous. Ribbons' hardness and elastic modulus evaluated by nanoindentation depended on annealing temperatures and were remarkably high. Potentiodynamic polarization curves in chlorine-rich solution at different pHs showed outstanding corrosion resistance in amorphous conditions. After devitrification, both compositions preserved excellent corrosion behavior up to ~700 • C. Pitting corrosion was absent. Resistance to corrosion and wear indicates that these materials are promising for coating applications.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: High Entropy Alloys Studies · High-Temperature Coating Behaviors · Metallic Glasses and Amorphous Alloys
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (76)
Show source-provided references
1. Ferry · 2005 · 46
2. 2018 · 3
3. Non-crystalline structure in solidified gold–silicon alloys10.1038/187869b0 ↗
4. Microstructural development in equiatomic multi-component alloys10.1016/j.msea.2003.10.257 ↗
5. Synthesis of Fe–Cr–Mo–C–B–P bulk metallic glasses with high corrosion resistance10.1016/S1359-6454(01)00366-4 ↗
6. Synthesis and characterization of bulk amorphous steels10.1016/j.jnoncrysol.2008.02.009 ↗
7. Stabilization of metallic supercooled liquid and bulk amorphous alloys10.1016/S1359-6454(99)00300-6 ↗
8. Hardness, magnetism and passivation of Fe-Si-B-Nb glasses10.1016/j.jnoncrysol.2021.120830 ↗
9. Potentiodynamic and potentiostatic investigation on the passivation of Fe based glassy alloys in alkaline solution10.1016/j.jallcom.2020.157573 ↗
10. Slurry erosion-corrosion behaviour of high-velocity oxy-fuel (HVOF) sprayed Fe-based amorphous metallic coatings for marine pump in sand-containing NaCl solutions10.1016/j.corsci.2011.05.062 ↗
11. Fe-based amorphous coatings: structures and properties10.1016/j.tsf.2013.08.029 ↗
12. Pitting initiation in Fe-based amorphous coatings10.1016/j.actamat.2012.04.005 ↗
13. Microstructure, mechanical properties and corrosion performance of Fe44Cr15Mo14Co7C10B5Si5 thin film metallic glass deposited by DC magnetron sputtering10.1016/j.jnoncrysol.2019.119718 ↗
14. Corrosion property and biocompatibility evaluation of Fe–Zr–Nb thin film metallic glasses10.1016/j.tsf.2019.137615 ↗
15. Wear behavior and corrosion properties of Fe-based thin film metallic glasses10.1016/j.jallcom.2015.07.256 ↗
16. Investigation of nano- and micro-scale structural evolution and resulting corrosion resistance in plasma sprayed Fe-based (Fe-Cr-B-C-P) amorphous coatings10.1016/j.surfcoat.2020.126058 ↗
17. Corrosion properties of Fe-Cr-Nb-B amorphous alloys and coatings10.1016/j.surfcoat.2014.06.022 ↗
18. Experimental and thermodynamic investigation of the microstructural evolution of a boron-rich Fe-Cr-Nb-B alloy10.1016/j.jallcom.2017.04.153 ↗
19. Challenges in optimizing the resistance to corrosion and wear of amorphous Fe-Cr-Nb-B alloy containing crystalline phases10.1016/j.jnoncrysol.2020.120537 ↗
20. Partial crystallization and corrosion resistance of amorphous Fe-Cr-M-B (M = Mo, Nb) alloys10.1016/j.jnoncrysol.2010.04.051 ↗
21. Microstructure and wear behavior of Fe-based amorphous HVOF coatings produced from commercial precursors10.1016/j.surfcoat.2016.10.057 ↗
22. Influence of chromium concentration and partial crystallization on the corrosion resistance of FeCrNiB amorphous alloys10.1016/j.matchar.2021.111369 ↗
23. Corrosion resistance of Fe-based amorphous alloys10.1016/j.jallcom.2012.12.130 ↗
24. Characterization and corrosion resistance of boron-containing-austenitic stainless steels produced by rapid solidification techniques10.3390/ma11112189 ↗
25. Crystallization, phase evolution and corrosion of Fe-based metallic glasses: an atomic-scale structural and chemical characterization study10.1016/j.actamat.2014.02.027 ↗
26. Element-resolved corrosion analysis of stainless-type glass-forming steels10.1126/science.1230081 ↗
27. Effects of crystallization on the corrosion resistance of Fe-based amorphous coatings10.1016/j.corsci.2012.02.003 ↗
28. Synthesis of Fe-Cr-Mo-C-B-P bulk metallic glasses with high corrosion resistance10.1016/S1359-6454(01)00366-4 ↗
29. Challenges in optimizing the resistance to corrosion and wear of amorphous Fe-Cr-Nb-B alloy containing crystalline phases10.1016/j.jnoncrysol.2020.120537 ↗
30. High-entropy alloys: a critical review10.1080/21663831.2014.912690 ↗
31. Peculiarities and usefulness of multi-component bulk metallic alloys10.1016/j.jallcom.2016.11.228 ↗
32. Effect of high-order multi-component on formation and properties of Zr-based bulk glassy alloys10.1016/j.jallcom.2015.03.078 ↗
33. Crystallization process and glass stability of an Fe48Cr15Mo14C15B6Tm2 bulk metallic glass10.1103/PhysRevB.78.144205 ↗
34. Mechanical properties of soft magnetic (Fe0.76Si0.096B0.084P0.06)100−xCux (x=0 and 0.1) bulk glassy alloys10.2320/matertrans.ME200833 ↗
35. Corrosion resistance of Fe-Cr-based amorphous alloys : an overview10.1016/j.jnoncrysol.2016.04.009 ↗
36. Effects of Cr, Ni and Cu on the corrosion behavior of low carbon microalloying steel in a Cl- containing environment10.1016/j.jmst.2012.12.013 ↗
37. Corrosion resistance of amorphous and nanocrystalline Fe-M-B (M=Zr, Nb) alloys10.1016/S0022-3093(00)00174-5 ↗
38. Mo microalloying effect on the glass-forming ability, magnetic, mechanical and corrosion properties of (Fe0.76Si0.096B 0.084P0.06)100-xMox bulk glassy alloys10.1016/j.jallcom.2011.04.081 ↗
39. Effects of Cr contents in Fe-based bulk metallic glasses on the glass forming ability and the corrosion resistance10.1016/j.matchemphys.2008.08.057 ↗
40. Glass-forming ability, thermal properties, and corrosion resistance of Fe-based (Fe, Ni, Mo, Cr)-P-C-B metallic glasses10.1016/j.jnoncrysol.2017.09.028 ↗
41. Study of the correlation between pitting corrosion and the component ratio of the dual phase in duplex stainless steel welds10.1016/j.corsci.2013.04.033 ↗
42. D.D. Coimbrão, G. Zepon, G.Y. Koga, D.A. Godoy Pérez, F.H. Paes de Almeida, V. Roche, J.C. Lepretre, A.M. Jorge, C.S. Kiminami, C. Bolfarini, A. Inoue, W.J. Botta, Corrosion properties of amorphous, partially, and fully crystallized Fe68Cr8Mo4Nb4B16 alloy, J. Alloys Compd. 826 (2020) 154123, 10.1016/j.jallcom.2020.154123.10.1016/j.jallcom.2020.154123 ↗
43. Corrosion behavior of nickel alloyed and austempered ductile irons in 3.5% sodium chloride10.1016/j.corsci.2010.05.006 ↗
44. Influence of boron addition on the microstructure and the corrosion resistance of CoCrMo alloy10.3390/met9030307 ↗
45. Hardness, magnetism and passivation of Fe-Si-B-Nb glasses10.1016/j.jnoncrysol.2021.120830 ↗
46. Microstructural investigation of Fe \ \ Cr \ \ Nb \ \ B amorphous /nanocrystalline coating produced by HVOF
47. Fabrication and characterization of supersonic plasma sprayed Fe-based amorphous metallic coatings10.1016/j.matdes.2016.08.003 ↗
48. Microstructure and corrosion behavior of Fe-based amorphous composite coatings developed by atmospheric plasma spraying10.1016/j.jallcom.2019.05.046 ↗
49. Formation and corrosion behavior of Fe-based amorphous metallic coatings prepared by detonation gun spraying10.1016/S1003-6326(10)60123-9 ↗
50. Formation of Fe-based glassy matrix composite coatings by laser processing10.1016/j.surfcoat.2013.12.049 ↗
51. An overview of thermally sprayed Fe-Cr-Nb-B metallic glass coatings: from the alloy development to the coating’s performance against corrosion and wear10.1007/s11666-022-01371-7 ↗
52. The effect of heat treatment and cyclic loading on nanoindentation behaviour of FeSiB amorphous alloy10.1016/j.matdes.2015.12.136 ↗
53. Nanoindentation creep behavior of an Fe–Cr–Mo–B–C amorphous coating via atmospheric plasma spraying10.1016/j.intermet.2021.107411 ↗
54. Plastic deformation behavior of Fe-Co-B-Si-Nb-Cr bulk metallic glasses under nanoindentation10.1016/j.jallcom.2013.10.097 ↗
55. Normal contact of inelastic solids
56. Plasticity characteristic obtained through hardness measurement10.1016/0956-7151(93)90122-9 ↗
57. Improved core model of the indentation for the experimental determination of mechanical properties of elastic-plastic materials and its application10.1016/j.mechmat.2020.103545 ↗
58. Beneficial effect of reversed austenite on the intergranular corrosion resistance of martensitic stainless steel10.1016/j.corsci.2019.02.020 ↗
59. Measurement of hardness and elastic modulus by instrumented indentation: advances in understanding and refinements to methodology10.1557/jmr.2004.19.1.3 ↗
60. Application of the improved inclusion core model of the indentation process for the determination of mechanical properties of materials10.3390/cryst7030087 ↗
61. High-entropy ceramic thin films; a case study on transition metal diborides10.1016/j.scriptamat.2018.02.008 ↗
62. New compositions of Fe–Co–Nb–B–Y BMG with wide supercooled liquid range, over 100 K10.1016/j.jmrt.2020.06.035 ↗
63. The supercooled liquid region span of Fe-based bulk metallic glasses10.1016/j.jallcom.2009.10.059 ↗
64. Glass-formation and corrosion properties of Fe-Cr-Mo-C-B glassy ribbons with low Cr content10.1016/j.jallcom.2013.12.245 ↗
65. Role of Nb in glass formation of Fe-Cr-Mo-C-B-Nb BMGs10.1016/j.jallcom.2014.03.095 ↗
66. RIR — measurement and use in quantitative XRD10.1017/S0885715600013257 ↗
67. Nanoindentation studies of shear banding in fully amorphous and partially devitrified metallic alloys10.1016/j.msea.2003.10.032 ↗
68. Nanoindentation studies of strain rate sensitivity in bulk metallic glasses10.1016/j.jnoncrysol.2021.120852 ↗
69. Fe-based bulk metallic glass matrix composite with large plasticity10.1016/j.scriptamat.2009.10.024 ↗
70. The correlation between mechanical properties and structure of Fe-Ni-P-B amorphous alloys: ab initio molecular dynamics simulations10.1016/j.jnoncrysol.2018.03.021 ↗
71. Strain gradient in micro-hardness testing and structural relaxation in metallic glasses10.1002/adem.201400423 ↗
72. Datasets on the measurement of mechanical properties of ferrite and austenite constitutive phases using nanoindentation and micro hardness techniques
73. Microstructure to magnetic properties and nanoindentation mapping of mechanical properties relationship in amorphous and partially crystallized Fe–Si–B–P-type alloy10.1016/j.jallcom.2019.06.065 ↗
74. Review of the recent development in metallic glass and its composites10.3390/met11121933 ↗
75. Micro/nano ductile-phases reinforced Fe-based bulk metallic glass matrix composite with large plasticity10.1016/j.msea.2017.09.036 ↗
76. On the significance of the H/E ratio in wear control: a nanocomposite coating approach to optimised tribological behaviour10.1016/S0043-1648(00)00488-9 ↗