Ge-free chalcogenide glasses based on Ga-Sb-Se and their stabilization by iodine incorporation
Source abstract
Abstract
Abstract In this paper, we report the existence of new bulk chalcogenide glasses free of germanium and transparent up to 18 μm. The investigation of the Ga-Sb-Se ternary diagram has allowed bringing out the presence of a small glassy domain mainly formed for compositions with low contents of Ga. Thermal, optical and mechanical characteristics of these glasses have been studied. In order to enhance the low stability against crystallization pure iodine was successfully added. At last, structural analysis by Raman spectroscopy was performed to point out the iodine addition effect.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Phase-change materials and chalcogenides · Glass properties and applications · Chalcogenide Semiconductor Thin Films
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References (26)
Show source-provided references
1. Chalcogenide glasses
2. Ga-Sb-Se material for low-power phase change memory10.1063/1.3669699 ↗
3. Effect of gallium environment on infrared emission in Er3+-doped gallium-antimony-sulfur glasses10.1038/srep41168 ↗
4. Ga-Sb-S chalcogenide glasses for mid-infrared applications10.1111/jace.14025 ↗
5. Freely adjusted properties in Ge-S based chalcogenide glasses with iodine incorporation10.1016/j.infrared.2015.01.015 ↗
6. Optical and mechanical properties of glasses ans glass-ceramics based on the Ge-Ga-Se system10.1111/j.1551-2916.2008.02684.x ↗
7. Thermal properties of ternary Ge-Sb-Se chalcogenide glass for use in molded lens applications10.1016/j.jnoncrysol.2015.04.003 ↗
8. Influence of gallium and alkali halide addition on the optical and thermo-mechanical properties of GeSe2-Ga2Se3 glass10.1007/s00339-007-4081-y ↗
9. Structure of glasses in the pseudobinary system Ga(2)Se(3)-GeSe(2): violation of chemical order and 8-N coordination rule10.1021/jp410017k ↗
10. Theoretical electric dipole moments and dissociation energies for ground states of GaH-BrH10.1063/1.451025 ↗
11. The effects of Te, I atoms on the properties and structure of Ge-As-Se system glasses10.1016/0022-3093(94)00629-6 ↗
12. Molded glass-ceramics for infrared applications10.1111/j.2041-1294.2011.00037.x ↗
13. Formation of complex structural units and structure of some chalco-halide glasses10.1016/j.jnoncrysol.2003.09.042 ↗
14. Photosensibility of pulsed laser deposited Ge-Sb-Se thin films10.1364/OME.5.000781 ↗
15. Sharp Raman anomalies and broken adiabaticity at a pressure induced transition from band to topological insulator in Sb2Se310.1103/PhysRevLett.110.107401 ↗
16. Sb2Se3 under pressure
17. Thermoanalytical properties and structure of (As2Se3)100−x(Sb2Se3)x glasses by Raman and 77Se MAS NMR using a multivariate curve resolution approach10.1016/j.jnoncrysol.2015.10.044 ↗
18. Structure nonlinear properties, and photosensibility of (GeSe2)100−x(Sb2Se3)x glasses10.1364/OME.4.000525 ↗
19. Structure and properties of the pure and Pr3+-doped Ge25Ga5Se70 and Ge30Ga5Se65 glasses10.1016/S0022-3093(00)00066-1 ↗
20. Glass formation, physico-chemical properties, and structure of glasses based on Ga2S3-GeS2-Sb2S310.1016/j.jnoncrysol.2010.08.029 ↗
21. Raman spectroscopy of gaseous GaCl3 and GaI310.1063/1.432860 ↗
22. Raman scattering in amorphous Ge and III–V compounds10.1016/0022-3093(72)90132-9 ↗
23. Investigation of stability of (Ge, Sn)-(S or Se)4/2 cluster vibrational spectra10.1016/0022-3093(83)90311-3 ↗
24. Thermomechanical and structural characterization of GeSe2-Sb2Se3-ZnSe glasses10.1016/S0167-577X(02)00710-3 ↗
25. Effect of the substitution of S for Se on the structure of the glasses in the system Ge0.23Sb0.07S0.70−xSex10.1016/j.jpcs.2005.08.090 ↗
26. Optical waveguide based on amorphous Er3+-doped Ga–Ge–Sb–S(Se) pulsed laser deposited thin films10.1016/j.tsf.2010.03.030 ↗