Preparation and Characterization of melt derived CaO-Sb2O3-Li2O containing borate glass for multiple application
Source abstract
Abstract
The antimicrobial efficiency, structural, optical, and electric transport properties of glasses of composition xCaO.10Li 2O.20Sb 2O 3.(70-x)B 2O 3 ( x = 0,2.5,5,7.5 and 10 mol%) and the role of CaO have been studied in this work. The amorphous phase of the glasses was confirmed through an X-ray diffraction study. The optical bandgap energy (E opt) was decreased with the addition of CaO, whereas, the refractive index values were increased. Urbach energy (∆E) of the glasses varied from 0.32 to 0.48 eV. Density (ρ) of the studied glasses was found to increase from 3.38 g/cm 3 to 3.77 g/cm 3 with CaO content. Antibacterial efficiency of the glasses was examined through a well plate method against Escherichia Coli., Salmonella in terms of zone of inhibition and it is increasing with CaO content. Glass transition temperature (T g) was decreased with increasing CaO content. NBOs play an significant role in achieving the higher order ionic conductivity. Due to the presence of Li 2O, Cole-Cole impedance plots exhibited semicircular behavior at high temperatures. FT-IR studies confirms the vibrations of B-O, B-O-B with B-O-Sb linkages in the glass.
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Research context
OpenAlex topics: Glass properties and applications · Luminescence Properties of Advanced Materials · Nuclear materials and radiation effects
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (58)
Show source-provided references
1. B. Srinivas, Ashok Bhogi, Pallati Naresh, Abdul Hameed, M. Narasimha Chary, Md. Shareefuddin,Effect of SrO and TeO2 on the physical and spectral properties of strontium tellurite boro-titanate glasses doped with Cu2+ ions,J. Non Cryst. Solids, 575(2022)121218.10.1016/j.jnoncrysol.2021.121218 ↗
2. Influence of TeO2 on the UV, electrical and structural studies of Li2O–ZnO–B2O3 glasses10.1016/j.molstruc.2020.128184 ↗
3. Salavadi Stalin, D.K.Gaikwad, M.S.Al-Buriahi. Ch.Srinivasu, Shaik Amer Ahmed, H.O.Tekin, Rahman Syed, Influence of Bi2O3/WO3 substitution on the optical, mechanical, chemical durability and gamma ray shielding properties of lithium-borate glasses, Ceram. Int., 47 (2021) 5286–5299.10.1016/j.ceramint.2020.10.109 ↗
4. Synthesis and characteristics of sol-gel bioactive SiO2-P2O5-CaO-Ag2O glasses10.1016/j.jnoncrysol.2017.09.035 ↗
5. Superstructural unit species in vitreous and crystalline alkali, alkaline earth and related boratesPhys
6. Physical, structural, optical, and radiation shielding properties of B2O3-20Bi2O3-20Na2O-Sb2O3 glasses: role of Sb2O310.1016/j.jnoncrysol.2020.120130 ↗
7. Influence of WO3 on some physical properties of MO–Sb2O3–B2O3 (M=Ca, Pb and Zn) glass system10.1016/j.jallcom.2009.06.115 ↗
8. Physical, structural, optical, and radiation shielding properties of B2O3- 20Bi2O3- 20Na2O- Sb2O3 glasses: role of Sb2O310.1016/j.jnoncrysol.2020.120130 ↗
9. Structural and femtosecond third-order nonlinear optical properties of sodium borate oxide glasses: effect of antimony10.1021/acs.jpcc.8b09466 ↗
10. Quantitative evaluation of antifungal activity of metallic oxide powders (MgO, CaO and ZnO) by an indirect conductimetric assay
11. Influence of CaO on the structure of zinc sodium tetra borate glasses containing Cu2+ ions10.1016/j.jnoncrysol.2021.120784 ↗
12. Antimicrobial activity of the metals and metal oxide nanoparticles10.1016/j.msec.2014.08.031 ↗
13. The role of CaO/SiO2 ratio and P2O5 content in gel-derived bioactive glass-polymer composites in the modulation of their bioactivity and osteoinductivity in human BMSCs10.1016/j.msec.2019.110535 ↗
14. Thermal and electrical properties of (B2O3-TeO2-Li2O-CoO) glasses10.1016/j.jnoncrysol.2018.02.010 ↗
15. Effect of Li2O content on structural and optical properties of Li2O-TeO2-As2O3-B2O3 glasses10.1016/j.jpcs.2020.109627 ↗
16. In-vitro bioactivity and antibacterial properties of CaF2‒CaO‒B2O3‒P2O5–SrO glass system-influence of Ta2O510.1016/j.jnoncrysol.2021.120881 ↗
17. Phase composition, sinterability and bioactivity of amorphous nano-CaO-SiO2-CuO powder synthesized by sol-gel technique10.1016/j.ceramint.2020.06.231 ↗
18. Choon sung lee
19. Khagendra Baral, Aize Li, and Wai-Yim Ching,Ab initio study of hydrolysis effects in single and ion-exchanged alkali aluminosilicate glasses,J. Phys. Chem. B, 10.1021/acs.jpcb.0c05875.
20. Structural, electronic and optical properties of a large random network model of amorphous SiO2 glass10.1016/j.jnoncrysol.2013.04.049 ↗
21. Ag2O doped bioactive glasses: an investigation on the antibacterial, optical, structural and impedance studies10.1016/j.jnoncrysol.2020.120361 ↗
22. Influence of zinc oxide addition on the biological activity and electrical transport properties of TeO2-Li2O-B2O3 glasses Materialia
23. Polypyrrole/Cr2O3 hybrid nanocomposites (NCs) prepared for their structural, morphological, optical and conductivity studies10.1016/j.coco.2019.04.004 ↗
24. Raman study on B2O3–CaO glasses10.1016/S0022-2860(03)00129-7 ↗
25. Role of non-bridging oxygen defect in the ionic conductivity and associated oxygen trap centers in lead-borate oxide glass: effect of structural substitution of PbO for Ag2O and Li2O modifiers10.1016/j.jnoncrysol.2018.06.033 ↗
26. Studies on Ag2O.MxOy.TeO2 (MxOy=WO3, MoO3, P2O5 and B2O3) ionic conducting glasses10.1016/S0167-2738(98)00393-2 ↗
27. Influence of CaF2 on spectroscopic studies of lead fluoro bismuth borate glasses doped with Cr3+ ions10.1016/j.jnoncrysol.2021.120705 ↗
28. Structural, thermal and optical properties of oxy-fluoro borotellurite glasses10.1016/j.jmrt.2020.01.045 ↗
29. Study of photo catalytical, antimicrobial activity, dielectric and ac impedance properties of Zn doped Mg nanoferrites synthesized from citrate gel auto combustion method10.1016/j.matchemphys.2021.125648 ↗
30. Conduction in non-crystalline systems V. Conductivity, optical absorption and photoconductivity in amorphous semiconductors10.1080/14786437008221061 ↗
31. Physical, structural, thermal, and optical spectroscopy studies of TeO2–B2O3–MoO3–ZnO–R2O (R= Li, Na, and K)/MO (M= Mg, Ca, and Pb) glasses10.1016/j.jallcom.2016.08.180 ↗
32. Influence of strontium on structure, bioactivity and corrosion behaviour of B2O3–SiO2–Na2O–CaO glasses-investigation by spectroscopic methods10.1016/j.optmat.2018.07.024 ↗
33. Triple modifier effect on physical, optical and structural properties of boro tellurite zinc lithium glasses10.1063/1.5032926 ↗
34. Synthesis, optical, structural, and radiation transmission properties of PbO/Bi2O3/B2O3/Fe2O3 glasses: an experimental and in silico study
35. Structural and spectroscopic studies on Er3+ doped boro-tellurite glasses10.1016/j.physb.2012.01.003 ↗
36. Preparation and study of optical, thermal, and antibacterialproperties of vanadate–tellurite glass10.1016/j.ceramint.2017.08.120 ↗
37. Modifier role of ZnO on the structural and transport properties of lithium boro tellurite glasses10.1016/j.jnoncrysol.2019.03.042 ↗
38. Influence of the network on conductivity in ternary CaO–Al2O3–SiO2 glasses and melts10.1016/S0022-3093(00)00423-3 ↗
39. Lithium ion conductivity in Li2O-P2O5-ZnO glass-ceramics10.1016/j.jallcom.2019.01.284 ↗
40. A.K. Jonscher, Dielectric Relaxation in Solids (Chelsea Dielectrics, London, 1983.
41. V. Prasad, L. Pavić, A. Moguš-Milanković, A. Siva Sesha Reddy, Y. Gandhi, V. Ravi Kumar, G. Naga Raju, N. Veeraiah, Influence of silver ion concentration on dielectric characteristics of Li2O-Nb2O5-P2O5 glasses. 10.1016/j.jallcom.2018.09.161.
42. Infrared reflectance spectra of lithium borate glasses10.1016/0022-3093(90)91023-K ↗
43. Infrared reflectance investigation of alkali diborate glasses10.1016/0022-3093(93)90258-Y ↗
44. Structure and nonlinear optical properties of Sb2O3-B2O3 binary glasses10.2109/jcersj.104.1008 ↗
45. Structural investigations of some bismuth–borate–vanadate glasses doped with gadolinium ions10.1007/s10854-009-9917-0 ↗
46. Borate glass structure by Raman and infrared spectroscopies10.1016/0022-2860(91)87058-P ↗
47. Thermal, optical and spectroscopic studies of boro-tellurite glass system containing ZnO10.1016/j.jnoncrysol.2015.11.028 ↗
48. A vibrational study of Lithium Borate glasses with High Li2O content
49. Physical properties of PbO-ZnO-P2O5glasses I. Infrared and raman spectra
50. Structure and Nonlinear Optical Properties of BaO-TiO2-B2O3 Glasses10.2109/jcersj.105.288 ↗
51. Structure and nonlinear optical properties of lanthanide borate glasses
52. Uncovering the phase transition of berlinite (α-AlPO4) under High Pressure: insights from first-principles calculations10.1007/s11595-021-2402-1 ↗
53. El-Aty, In Vitro bioactivity behavior of some borate glasses and their glass-ceramic derivatives containing Zn2+, Ag+ or Cu2+ by immersion in phosphate solution and their anti-microbial activity10.1007/s12633-017-9552-y ↗
54. Investigation on silver doped B2O3-SiO2-P2O5-Na2O-CaO bioglass system for biomedical applications10.1016/j.jallcom.2017.10.271 ↗
55. Bioactive glasses in the system CaO–B2O3–P2O5: preparation, structural study and in vitro evaluation10.1016/j.jnoncrysol.2006.01.042 ↗
56. In vitro studies of B2O3–SiO2–Na2O–CaO–ZnO bioactive glass system10.1016/j.jnoncrysol.2021.121164 ↗
57. Novel bioactive and biodegradable glass ceramics with high mechanical strength in the CaO – SiO2 – B2O3 system10.1002/jbm.a.20029 ↗
58. Development and in vitro characterization of sol-gel derived CaO - P2O5 - SiO2 - ZnO bioglass10.1016/j.actbio.2006.09.005 ↗