journal article·2021-02

Optical characteristics and luminescence of amorphous BaTiO3 thin films doped with Eu3+

K.T. Lee, R.A.M. Osman, P. Poopalan

Publisher page

Abstract

Abstract Sol-gel spin coated BaTiO3:Eu3+ thin films on fused silica substrate were thermally annealed between 400°C and 800°C. The multilayer films were doped with Eu3+ which was limited to 10 mol % doping concentration. Standard physical and optical characterizations were performed in addition to excitation-emission and UVPL spectroscopy. The films were amorphous at temperatures below 600°C and exhibited stronger luminescence at 613.0 nm (5D0 → 7F2) than crystalline films. Optical energy band-gap ranged from 3.825 eV (crystalline) to 4.325 eV (amorphous) and the amorphous films’ CIE showed excellent red coordinates whilst red/orange (R/O) asymmetry ratio shows tailored emission color is possible.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Glass properties and applications · Photorefractive and Nonlinear Optics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (45)

Show source-provided references
1. Fluorescence and energy transfer between Eu3+ and Sm3+ in single doped and co-doped borate glass10.1016/j.jnoncrysol.2017.03.010 ↗
2. Luminescence properties of Dy3+ doped zinc-aluminum-sodium-phosphate (ZANP) glasses for white light applications10.1016/j.ijleo.2015.08.001 ↗
3. Luminescence properties of Dy3+ doped different fluoro-phosphate glasses for solid state lighting applications10.1016/j.molstruc.2014.09.080 ↗
4. Luminescence and energy transfer in Dy3+/Eu3+ co-doped aluminosilicate oxyfluoride glasses and glass-ceramics10.1016/j.jallcom.2017.11.077 ↗
5. Kinetics of fluorescence properties of Eu3+ ion in strontium-aluminium-bismuth-borate glasses10.1016/S1002-0721(14)60195-2 ↗
6. Judd-Ofelt analysis and spectral properties of Dy3+ ions doped niobium containing tellurium calcium zinc borate glasses10.1016/j.optcom.2013.09.044 ↗
7. Energy transfer from Ce3+ to Tb3+, Dy3+ and Eu3+ in Na3Y(BO3)210.1016/S1002-0721(14)60525-1 ↗
8. Theoretical spectra identification and fluorescent properties of reddish orange Sm-doped BaTiO3 phosphors10.1016/j.jallcom.2015.04.087 ↗
9. Luminescence studies of perovskite structured titanates: a review10.1134/S0030400X15060156 ↗
10. Structural characterization and thermoluminescence studies of UV irradiated and Eu3+ activated BaZr0.25Ti0.75O3 powders10.1016/j.mssp.2015.12.030 ↗
11. White emitting Dy3+ activated perovskite titanates and energy transfer by Eu3+ codoping10.1016/j.ceramint.2017.06.058 ↗
12. Luminescent characteristics of Ba3Y2(BO3)4:Eu3+ phosphor for white LED10.1016/S1002-0721(08)60034-4 ↗
13. Dyes and Pigments Dy/Eu co-doped CsGd(MoO 4)2 phosphor with tunable photoluminescence properties for near-UV WLEDs applications10.1016/j.dyepig.2016.10.016 ↗
14. Photoluminescence properties of red emitting Ba3Bi2(PO4)4 : Eu3+ phosphor for WLEDs applications10.1016/j.jlumin.2018.04.054 ↗
15. A novel highly efficient single-composition tunable white-light-emitting LiCa3MgV3O12:Eu3+ phosphor10.1016/j.dyepig.2018.02.047 ↗
16. Preparation and luminescent properties of Eu-doped BaTiO3 thin films by sol-gel process10.1016/S1468-6996(03)00027-5 ↗
17. Effective sensitization of Eu3+ and energy transfer in Sm3+/Eu3+ co-doped ZPBT glasses for CuPc based solar cell and w-LED applications10.1016/j.jlumin.2017.09.049 ↗
18. Fluorescence spectra and crystal field analysis of BaMoO4: Eu3+ phosphors for white light-emitting diodes10.1016/j.saa.2013.12.007 ↗
19. Photoluminescence studies of Eu3+ activated SrTiO3 nanophosphor prepared by solution combustion approach10.1016/j.ijleo.2017.07.003 ↗
20. Optical properties of sonochemically synthesized rare earth ions doped BaTiO3 nanophosphors: probable candidate for white light emission10.1016/j.jlumin.2013.11.071 ↗
21. Eu-doped BaTiO3 powder and film from sol-gel process with polyvinylpyrrolidone additive10.3390/ijms10094088 ↗
22. Hydrothermal Synthesis and Characterization of Europium-doped Barium Titanate Nanocrystallites10.1007/BF03353732 ↗
23. Structural, photoluminescent, and dielectric properties of Eu3+-doped Ba0.7Sr0.3TiO3 thin films10.1016/j.cap.2015.03.025 ↗
24. Structural, optical, and photoluminescent properties of sol-gel derived Eu-doped Ba1-xSrxTiO3 thin films10.1007/s10854-015-2847-0 ↗
25. Theoretical and experimental study on the photoluminescence in BaTiO3 amorphous thin films prepared by the chemical route10.1016/S0022-2313(03)00014-0 ↗
26. Effects of site substitutions and concentration on the structural, optical and visible photoluminescence properties of Er doped BaTiO3 thin films prepared by RF magnetron sputtering10.1016/j.optmat.2015.04.036 ↗
27. Optical properties of amorphous Ba0.7Sr0.3TiO3 thin films obtained by metal organic decomposition technique10.1016/j.tsf.2006.03.051 ↗
28. Characterization of optical properties of amorphous BaTiO3 nanothin films10.1016/j.jnoncrysol.2009.08.030 ↗
29. Optical properties of Ba0.5Sr0.5TiO3 thin films grown on MgO substrates by pulsed laser deposition10.1016/j.ceramint.2003.12.136 ↗
30. Preparation and optical properties of barium titanate thin films10.1016/j.physb.2011.06.041 ↗
31. Europium incorporated barium titanate thin films for optical applications10.1007/s10854-014-1903-5 ↗
32. Thickness dependence of structural, optical and luminescence properties of BaTiO3 thin films prepared by RF magnetron sputtering10.1007/s10854-015-2781-1 ↗
33. Effects of Nd-doping on optical and photovoltaic properties of barium titanate thin films prepared by sol–gel method10.1016/j.materresbull.2013.04.048 ↗
34. Band-gap energies of sol-gel-derived SrTiO3 thin films10.1063/1.1423788 ↗
35. Three-dimensional quantum-size effect in chemically deposited cadmium selenide films10.1103/PhysRevB.36.4215 ↗
36. Novel red perovskite phosphor Ca2AlNbO6:Eu3+ for white light-emitting diode application10.1016/j.physb.2011.09.037 ↗
37. A novel double perovskite tellurate Eu3+-doped Sr2MgTeO6 red-emitting phosphor with high thermal stability10.1016/j.optlastec.2017.11.046 ↗
38. Synthesis and luminescence properties of a novel red-emitting phosphor Ba3La(PO4)3:Eu3+ for solid-state lighting10.1016/j.jallcom.2013.04.150 ↗
39. Synthesis and luminescent properties of UV-excited thermal stable red-emitting phosphor Ba3Lu(PO4)3: Eu3+ for NUV LED10.1016/j.optmat.2013.12.024 ↗
40. New orange-red phosphor Sr9Sc(PO4)7:Eu3+ for NUV-LEDs application10.1016/j.jallcom.2013.10.116 ↗
41. A novel pure red phosphor Ca8MgLu(PO4)7:Eu3+ for near ultraviolet white light-emitting diodes10.1016/j.ceramint.2015.04.023 ↗
42. Highly efficient Eu-activated KGd(WO4)(PO4) red-emitting phosphors with superior thermal stability for solid-state lighting10.1016/j.ceramint.2017.05.123 ↗
43. Photoluminescence studies of high-efficient red-emitting K2Y(WO4)(PO4):Eu3+ phosphor for NUV LED10.1016/j.materresbull.2015.09.003 ↗
44. A study of the effects of europium doping and calcination on the luminescence of titania phosphor materials10.1021/jp0041196 ↗
45. Understanding the photoluminescence behaviour in nano CaZrO3:Eu3+ pigments by Judd-Ofelt intensity parameters10.1016/j.dyepig.2017.12.022 ↗