journal article·2022-02

The non-isothermal crystallization kinetics and mechanism of FeGaGeBCu alloy

Lu Guo, Qianke Zhu, Zhe Chen, Kewei Zhang, Yong Jiang

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Abstract

Abstract In this paper, Fe76Ga5Ge5B13Cu1 ribbon was prepared by melt spinning method and its thermal stability and non-isothermal crystallization kinetics were analyzed. It is found that the primary crystallization phase is α-Fe(Ga,Ge), following by the precipitation of Fe-B compounds. Besides, Kissinger and Ozawa methods were utilized to calculate the initial activation energy Ex and apparent activation energy Ea. The results show that Ex1 > Ea1, which is due to that the diffusion of Ga and Ge is difficult during the nucleation process but left a channel for the subsequent diffusion of atoms. In addition, Avrami index n was calculated by Johnson-Mehl-Avrami-Kolmogorov (JMAK) model and the crystallization mechanism of Fe76Ga5Ge5B13Cu1 alloy was analyzed. For the alloy with grains or clusters embedded in the amorphous matrix, it is concluded that the annealing condition with a higher heating rate is more conducive to obtain homogeneous nanocrystalline and improve soft magnetic properties.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Metallic Glasses and Amorphous Alloys · Magnetic Properties of Alloys · Microstructure and Mechanical Properties of Steels

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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