journal article·2022-01

Viscosity and fragility of selected glass-forming chalcogenides

Petr Koštál, Jaroslav Barták, Torsten Wieduwilt, Markus A. Schmidt, Jiří Málek

Publisher page

Abstract

Abstract Experimental viscosity data for (GeSe2)x(Sb2Se3)100-x melts (x = 50, 60 and 70), obtained by deploying the pressure-assisted melt filling technique (PAMFT), are presented. These data were combined with previously published literature data and fitted over a broad temperature range including glass, undercooled melt, and melt regions by the Mauro–Yue–Ellison–Gupta–Allan (MYEGA) equation. A detailed analysis of different fragility concepts for the studied glass-forming system as well as for other well-known chalcogenide glass formers is presented. On the basis of this extensive analysis, a simple procedure for carrying out viscosity data extrapolation was developed, and the validity of this procedure is discussed.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Phase-change materials and chalcogenides · Material Dynamics and Properties · Glass properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (70)

Show source-provided references
1. Applications of chalcogenide glasses in electronics and optoelectronics: a review
2. Chalcogenide glasses in Japan: a review on photoinduced phenomena10.1002/pssb.200982002 ↗
3. Amorphous and polycrystalline photoconductors for direct conversion flat panel X-ray image sensors10.3390/s110505112 ↗
4. Phase-change materials for rewriteable data storage10.1038/nmat2009 ↗
5. Raoux · 2009
6. Infrared biosensors using hydrophobic chalcogenide fibers sensitized with live cells10.1016/j.snb.2005.12.033 ↗
7. Thermodynamic determination of fragility in liquids and a fragile-to-strong liquid transition in water10.1038/19042 ↗
8. Fragile-to-strong transitions in glass forming liquids
9. An experimental critique on the existence of fragile-to-strong transition in glass-forming liquids10.1016/j.jnoncrysol.2018.05.009 ↗
10. The viscosity and structural relaxation rate of evaporated amorphous selenium10.1063/1.324603 ↗
11. Viscosity of As(20)Se(80)amorphous chalcogenide films10.1016/j.matlet.2018.06.065 ↗
12. Surface mobility in amorphous selenium and its similarities to organic molecular glasses10.1063/5.0041273 ↗
13. Comment on "An experimental critique on the existence of fragile-to-strong transition in glass-forming liquids10.1016/j.jnoncrysol.2018.12.017 ↗
14. A model for the fragility of the melts10.1023/A:1020636829278 ↗
15. Thermodynamic parameters of bonds in glassy materials from viscosity - temperature relationships10.1088/0953-8984/19/41/415107 ↗
16. Viscosity of glass-forming liquids10.1073/pnas.0911705106 ↗
17. Das temperatur-abhängigkeitsgesetz der viskosität von flüssigkeiten
18. Analysis of recent measurements of the viscosity of glasses10.1111/j.1151-2916.1925.tb16731.x ↗
19. Die Abhängigkeit der Viscosität von der Temperatur bei unterkühlten Flüssigkeiten10.1002/zaac.19261560121 ↗
20. Non-Newtonian flow of an ultralow-melting chalcogenide liquid in strongly confined geometry10.1063/1.4921708 ↗
21. Hybrid optical fibers - an innovative platform for in-fiber photonic devices10.1002/adom.201500319 ↗
22. Optical properties of photonic crystal fiber with integral micron-sized Ge wire10.1364/OE.16.017227 ↗
23. Pressure-assisted melt-filling and optical characterization of Au nano-wires in microstructured fibers10.1364/OE.19.012180 ↗
24. Viscosity of chalcogenide glass-formers10.1080/09506608.2018.1564545 ↗
25. Universality in the non-Newtonian viscous flow behavior of AsxSe1-x liquids: results from capillary rheometry10.1016/j.jnoncrysol.2016.09.019 ↗
26. Analysis of viscosity data in As2Se3, Se and Se95Te5 chalcogenide melts using the pressure assisted melt filling technique10.1016/j.jnoncrysol.2019.01.037 ↗
27. Viscosity of (GeSe2)(x)(Sb2Se3)(1-x) undercooled melts10.1016/j.jnoncrysol.2007.06.009 ↗
28. Effect of Disorder on Diffusion and Viscosity in Condensed Systems10.1016/0022-3093(88)90396-1 ↗
29. Perspective on the glass-transition10.1016/0022-3697(88)90002-9 ↗
30. Entropy and fragility in super-cooling liquids10.6028/jres.102.013 ↗
31. Theory of relaxation in viscous-liquids and glasses10.1063/1.447697 ↗
32. Elastic interpretation of the glass transition in aluminosilicate liquids10.1103/PhysRevB.85.144203 ↗
33. Communication: observation of ultra-slow relaxation in supercooled selenium and related glass-forming liquids10.1063/1.5022787 ↗
34. Investigation of the shear relaxation behavior of As-Se liquids within the framework of entropic and elastic models of viscous flow10.1016/j.jnoncrysol.2020.119959 ↗
35. Strong and fragile plastic crystals10.1051/jcp/1985820773 ↗
36. Correlation index (T-G-alpha - T-G-beta)/T-G-alpha and activation-energy ratio delta-epsilon(a-alpha)/delta-epsilon(a-beta) as parameters characterizing the structure of liquid and glass10.1016/0038-1098(94)00851-5 ↗
37. Nemilov · 1995
38. Viscosity of pure liquids. I. Non-polymerised fluids10.1039/tf9433900048 ↗
39. Universality of the high-temperature viscosity limit of silicate liquids10.1103/PhysRevB.83.212202 ↗
40. Scholze · 1991
41. International Organization for Standardization, Glass - Viscosity and viscometric fixed points Part 8: determination of (dilatometric) transformation temperature 1987.
42. Springer handbook of glass
43. Relaxation in liquids, polymers and plastic crystals - strong fragile patterns and problems10.1016/0022-3093(91)90266-9 ↗
44. Observation of a dynamical crossover in the shear relaxation processes in supercooled selenium near the glass transition10.1063/1.5086173 ↗
45. Fragility and thermodynamics in nonpolymeric glass-forming liquids10.1063/1.2244551 ↗
46. Nonexponential relaxations in strong and fragile glass formers10.1063/1.466117 ↗
47. Rheology and plasticization of polyvinyl chloride10.1351/pac197126020241 ↗
48. Correlation of fragility of supercooled liquids with elastic properties of glasses10.1103/PhysRevE.71.061501 ↗
49. Study of viscosity of glassy system Se-As (russ
50. An upper limit to kinetic fragility in glass-forming liquids
51. Viscosity of Se-Te glass-forming system10.1515/pac-2014-0901 ↗
52. Viscous flow in simple organic liquids10.1021/j100660a023 ↗
53. High-temperature flow behavior of glass-forming liquids - free-volume interpretation10.1063/1.1680531 ↗
54. Formation of glasses from liquids and biopolymers10.1126/science.267.5206.1924 ↗
55. Impurity dependence of the viscosity of liquid selenium10.1080/13642818208246443 ↗
56. Dynamics of glass-forming liquids. V. On the link between molecular dynamics and configurational entropy10.1063/1.476348 ↗
57. Viscous flow and the viscosity of melts and glasses
58. Viscosity of silica10.1063/1.1515132 ↗
59. A thermodynamic connection to the fragility of glass-forming liquids10.1038/35070517 ↗
60. Viscosity of selenium melt10.1016/j.jnoncrysol.2010.09.032 ↗
61. Analysis of crystal growth and viscosity in Ge-Sb-Se-Te undercooled melts10.1016/j.jnoncrysol.2018.10.048 ↗
62. Extended study on crystal growth and viscosity in Ge-Sb-Se bulk glasses and thin films10.1021/acs.jpcb.7b04429 ↗
63. Viscosity and structure of As-S glasses (russ.)
64. Viscosity and structure of As2X3-AsI3 glasses (russ.)
65. Properties and structure of glasses in the system arsenic-sulfur10.1016/0022-3093(71)90069-X ↗
66. S.V. Nemilov, Valence structure, viscous and elastic properties of As-S melts (russ.), Fiz. Chim. Stekla, 5 (1979) 398–409.
67. Viscosity of amorphous selenium doped by antimony (russ.)
68. Viscosity of glassy selenium from 0°C to 100°C10.1007/BF01512275 ↗
69. Viscosity of glasses in the system As-Se, As-Se-S, As-Se-Te and As-Se-Tl (jpn.)10.2472/jsms.19.145 ↗
70. Temperature dependence of viscous properties of amorphous selenium (russ.)