A comparative study on the physical and spectral (optical, EPR and FTIR) properties of NaF-CdO-B2O3 and KF-CdO-B2O3 glass systems doped with manganese ions
Source abstract
Abstract
The glass systems with the composition xMF-(40-x) CdO-59.5B 2O 3, (M=Na, K and x= 5, 10, 15, 20, 25, 30 and 35 mol %) doped with 0.5 mol % of MnO 2 were prepared using the melt quenching method. The glasses were analysed using XRD, UV-VIS, EPR and FTIR spectra. The optical band gap (E g) values of the glass systems were observed to increase from 3.21 eV [NFCBM1] to 3.48 eV [NFCBM7] and 2.56eV [KFCBM1] to 3.31 eV [KFCBM7] with increase of NaF/KF concentration which may be due to decreasing of the number of non bridging oxygens. The (Δg) values suggest the presence of Mn 2+ ions in octahedrally coordinated complex and the A values suggest that the bond between Mn 2+ ions and its ligand filed is ionic. The BO 4 atoms were increased in both NaF and KF containing glasses with increase in NaF/KF concentration.
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Research context
OpenAlex topics: Glass properties and applications · Luminescence Properties of Advanced Materials · Phase-change materials and chalcogenides
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (73)
Show source-provided references
1. Effect of Ag2O/V2O5 substitution on the radiation shielding ability of tellurite glass system via XCOM approach and FLUKA simulations10.1088/1402-4896/abf26a ↗
2. Effect of chromium oxide on the physical, optical, and radiation shielding properties of lead sodium borate glasses10.1016/j.jnoncrysol.2020.120171 ↗
3. Spectroscopic properties of alkali alkaline earth borate glasses doped with Fe3+ ions10.1007/s41779-019-00426-3 ↗
4. Thermal and structural characterization of lithium borate glasses doped with Fe (III) ions: the role of alkaline earths10.1016/j.optmat.2020.110345 ↗
5. The effects of TeO2 on polarizability, optical transmission, and photon/neutron attenuation properties of boro-zinc-tellurite glasses10.1007/s10904-021-01933-2 ↗
6. Fabrication, optical and radiation shielding properties of BaO-TeO2-B2O3-Cr2O3 glass system10.1016/j.ijleo.2022.168877 ↗
7. Study of the radiation attenuation properties of MgO-Al2O3-SiO2-Li2O-Na2O glass system10.1007/s41779-021-00687-x ↗
8. Investigation of barium borate glasses for radiation shielding applications10.1007/s00339-019-3254-9 ↗
9. Synthesis, thermal, optical, mechanical and radiation-attenuation characteristics of borate glass system modified by Bi2O3/MgO10.1007/s00339-022-05475-3 ↗
10. Structural and optical properties of CuO doped lithium borate glasses
11. Effect of SrO and TeO2 on the physical and spectral properties of strontium tellurite boro-titanate glasses doped with Cu2+ ions10.1016/j.jnoncrysol.2021.121218 ↗
12. Influence of manganese ions on physical and spectroscopic properties of mixed alkali-alkaline earth oxide borate glasses10.1016/j.ijleo.2021.167810 ↗
13. Mechanical and radiation shielding properties of tellurite glasses doped with ZnO and NiO10.1016/j.ceramint.2020.04.240 ↗
14. Simulating the radiation shielding properties of TeO2–Na2O–TiO glass system using PHITS Monte Carlo code10.1016/j.commatsci.2021.110566 ↗
15. Amorphous alloys with high Fe content for radiation shielding applications10.1016/j.radphyschem.2021.109386 ↗
16. Effects of MgO addition on the radiation attenuation properties of 45S5 bioglass system at the energies of medical interest: an in silico study10.1007/s41779-021-00605-1 ↗
17. The correlation between the structural, optical, and electrical properties in mixed alkali fluoroborate glasses containing vanadium ions10.1016/j.jnoncrysol.2017.08.031 ↗
18. Glasses in the NaPO3-WO3-NaF ternary system: preparation, physical properties and structural studies10.1016/j.jnoncrysol.2018.10.043 ↗
19. Influence of titanium ionson dielectric and other physical properties of AF-PbO-B2O3 glasses
20. Structural and optical studies of Rare earth-free Bismuth Silicate glasses for white light generation10.1016/j.jlumin.2018.05.023 ↗
21. Broad-band 1. 5 μm emission of Er3+ ions in bismuth-based oxide glasses for potential WDM amplifier10.1016/S0022-2313(99)00352-X ↗
22. Thermal stability and optical properties of a novel Tm3+ doped fluor tellurite glass10.1016/S1002-0721(14)60197-6 ↗
23. Structure and properties of CdO–B2O3 and CdO–MnO–B2O3 glasses; criteria of getting the fraction of four coordinated boron atoms from infrared spectra10.1016/j.physb.2017.09.019 ↗
24. Elastic, optical and structural features of wide range of CdO- Na2B4O7 glasses
25. Structural, thermal and optical properties of TeO2-ZnO-CdO-BaO glasses doped with VO2+10.1016/j.saa.2015.03.085 ↗
26. Different property studies with network improvement of CdO doped alkali borate glass10.1016/j.jnoncrysol.2018.03.051 ↗
27. Heavy-metal oxide glass10.1111/j.1151-2916.1992.tb05581.x ↗
28. Structural FTIR spectra and thermal properties of CdO–B2O3 glasses doped with LiF, CaF2 or TiO2, together with X-ray diffraction and SEM investigations of their glass–ceramic derivatives”
29. Optical and structural properties of Mn2+ doped PbGeO3–SbPO4 glasses and glass–ceramics10.1016/j.jnoncrysol.2015.04.022 ↗
30. “B2O3-BaCO3-Li2O3 glass system doped with CoO4: Structure, optical, and radiation shielding properties”10.1016/j.physb.2019.411717 ↗
31. Bi2O3 reinforced B2O3+Sb2O3+Li2O3: composition, physical, linear optical characteristics, and photon attenuation capacity
32. A study on optical properties of MnO doped borobismuthate glasses
33. Effect of alkaline earths on spectroscopic and structural properties of Cu2+ions-doped lithium borate glasses10.1016/j.jnoncrysol.2015.06.012 ↗
34. Physical properties, optical band gaps and radiation shielding parameters exploration for Dy3+-doped alkali/mixed alkali multicomponent borate glasses10.1134/S1087659618040119 ↗
35. Role of aluminum on the physical and spectroscopic properties of chromium-doped strontium alumino borate glasses10.1142/S0217979218500959 ↗
36. The role of sodium fluoride on CdO‑B2O3 glasses doped with chromium ions10.1007/s00339-019-3181-9 ↗
37. Investigation of optical, structural, FTIR and magnetic properties of Sn substituted Zn0.98Mn0.02O nanoparticles”10.1016/j.ceramint.2015.12.140 ↗
38. Li2O-LiF-ZnF2-B2O3-P2O5: MnO glasses–thermal, structural, optical and luminescence characteristics”10.1016/j.optmat.2015.11.035 ↗
39. Electron Spin Resonance and optical absorption spectroscopic studies of manganese centers in aluminium lead borate glasses10.1016/j.saa.2012.08.023 ↗
40. Dependence of the structure, optical, and dynamic properties of novel cadmium phosphate glass on vanadium content10.1016/j.jmrt.2020.10.007 ↗
41. Allowed and forbidden hyperfine structure of Mn2+ ions in sodium tetraborate glasses-an EPR and optical study10.1016/j.physb.2004.12.021 ↗
42. Site symmetry of Mn(II) and Co(II) in zinc phosphate glass10.1016/S0022-3697(03)00286-5 ↗
43. Switching of TiO2-V2O5-P2O5 glasses10.1016/S0022-3093(87)80687-7 ↗
44. Conduction in non-crystalline systems V. Conductivity, optical absorption and photoconductivity in amorphous semiconductors10.1080/14786437008221061 ↗
45. The long-wavelength edge of photographic sensitivity and of the electronic absorption of solids10.1103/PhysRev.92.1324 ↗
46. Physical and spectroscopic studies on manganese ions in lead halo borate glasses
47. States in the gap10.1016/0022-3093(72)90194-9 ↗
48. Optical band gap studies on (55−x)Na2O–xPbO–45P2O5 (SLP) glass system10.1016/S0925-3467(00)00033-1 ↗
49. Structural investigations of phosphate glasses: a detailed infrared study of the x(PbO)-(1−x) P2O5 vitreous system10.1007/BF00356615 ↗
50. Electronic oxide polarizability and optical basicity of simple oxides. I10.1063/1.360962 ↗
51. Classification of simple oxides: a polarizability approach10.1006/jssc.2001.9378 ↗
52. Bonding and ion–ion interactions of Mn2+ ions in fluoride-phosphate and boro-silicate glasses probed by EPR and fluorescence spectroscopy10.1016/j.jnoncrysol.2011.02.017 ↗
53. Spectroscopy of 3d Complexes10.1002/9780470166130.ch3 ↗
54. EPR spectroscopy of Cu2+ and Mn2+ in borate glasses
55. Spectroscopic investigations of manganese ions in microwave-prepared NaPO3-PbO glasses10.1016/S0022-3697(97)00178-9 ↗
56. The role of halides on a chromium ligand field in lead borate glasses10.1088/2053-1591/aa8d7e ↗
57. Optical spectroscopy of chromium doped bismuth-lithium borate glasses10.1016/j.jnoncrysol.2021.120665 ↗
58. Paramagnetic resonance of divalent manganese incorporated in various lattices10.1039/df9551900118 ↗
59. Electron paramagnetic resonance and photoluminescence studies of LaMgAl11O19:Mn2+ green phosphors10.1007/s11664-014-3351-7 ↗
60. Investigation of structural, physical and optical properties of CeO2–Bi2O3–B2O3 glasses10.1016/j.physb.2012.06.043 ↗
61. Optical and electrical properties of manganese doped-alkali metaphosphate glasses
62. EPR and optical properties of lithium disilicate glasses and glass–ceramics doped with Mn2+ ions10.1016/j.jallcom.2011.09.031 ↗
63. Spectroscopic studies on Fe3+ and Mn2+ doped SrB4O7 glasses10.1016/j.physb.2011.05.043 ↗
64. Structural, thermal, dielectric and ac conductivity properties of lithium fluoro-borate optical glasses10.1016/j.ceramint.2011.10.084 ↗
65. Physical, optical and structural studies of copper-doped lead oxychloro borate glasses10.1007/s12034-018-1604-4 ↗
66. A review on infrared spectroscopy of borate glasses with effects of different additives
67. Spectroscopic studies of Bi2O3–Li2O–ZnO–B2O3 glasses10.1016/j.solidstatesciences.2007.09.017 ↗
68. Elastic properties and structural studies on lead–boro–vanadate glasses10.1016/j.jnoncrysol.2007.07.011 ↗
69. Shielding behavior of MoO3-doped lead borate glasses towards gamma irradiation assessed through collective optical, FTIR, and ESR spectral analysis”10.1016/j.radphyschem.2021.109537 ↗
70. Impact of vanadium ions in barium borate glass10.1016/j.saa.2014.08.012 ↗
71. Preparation and optical properties of borate glass doped with MnO2
72. IR analysis of borate glasses containing three alkali oxides10.2306/scienceasia1513-1874.2013.39.278 ↗
73. Influence of europium ions on structure and crystallization properties of bismuth borate glasses and glass ceramics10.1016/j.jnoncrysol.2008.09.010 ↗