journal article·2019-10

Density, elastic constants and indentation hardness of hydrous soda-lime-silica glasses

P. Kiefer, R. Balzer, J. Deubener, H. Behrens, T. Waurischk, S. Reinsch, R. Müller

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Abstract

Abstract The effect of structural water on density, elastic constants and microhardness of water-bearing soda-lime-silica glasses of up to 21.5 mol% total water is studied. It is found that the Poisson ratio and the water content are positively correlated, while density and the elastic moduli decrease with increasing water content. Vickers hardness decreases by approximately 27% from the dry to the most hydrous glass. For water fractions 3 mol% linear dependencies are found. To distinguish the effect of structural water and environmental water, indentations were performed in toluene, nitrogen gas and air. Time-dependent softening was evident for testing dry glasses in humid atmospheres as well as for tests of hydrous glasses in dry atmospheres. This indicates that the response times of dissolved water species are effectively equal in both scenarios.
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OpenAlex topics: Glass properties and applications · Building materials and conservation · Material Dynamics and Properties

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