journal article·2021-07

Hardness, magnetism and passivation of Fe-Si-B-Nb glasses

H. Zhang, Z.C. Yan, Q. Chen, Y. Feng, Z.G. Qi, H.Z. Liu, X.Y. Li, W.M. Wang

Publisher page

Abstract

Abstract Nb is a noble and important element for the Fe based glass manufacture. The mechanical properties, magnetic properties and corrosion behavior of (Fe78Si9B13)100-xNbx (x = 0, 7 and 10) glassy ribbons have been studied by various experimental methods. With the addition of Nb element, the hardness of the Fe-based glasses increases and their coercivity decreases, which is attributed to the ordering tendency of atomic structure by adding Nb atoms. In the potentiodynamic polarization and Mott-Schottky plots, Fe-based glassy ribbons with x = 7 and 10 have a wide passivation platform and an n-type semiconductive surface, while the ribbon with x = 0 does not. By XPS analysis, Nb and B tend to segregate beneath the ribbon surface and form the stable passive film. The Nb addition can improve the hardness, soft magnetism and corrosion resistance of Fe based glasses and will help us to seek for the new type Fe based glasses.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Metallic Glasses and Amorphous Alloys · Advanced Surface Polishing Techniques · Magnetic Properties and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (52)

Show source-provided references
1. Fabrication and hyperthermia effect of magnetic functional fluids based on amorphous particles10.1016/j.apsusc.2015.01.023 ↗
2. Element-resolved corrosion analysis of stainless-type glass-forming steels10.1126/science.1230081 ↗
3. Fe- and Co-based bulk glassy alloys with ultrahigh strength of over 4000 MPa10.1016/j.intermet.2006.01.038 ↗
4. Synthesis of Fe–Cr–Mo–C–B–P bulk metallic glasses with high corrosion resistance10.1016/S1359-6454(01)00366-4 ↗
5. Ductility improvement of amorphous steels: roles of shear modulus and electronic structure10.1016/j.actamat.2007.09.011 ↗
6. Enhancing the acid orange dye degradation efficiency of Mg-based glassy alloys with introducing porous structure and zinc oxide10.1016/j.jallcom.2020.154817 ↗
7. Role of maze like structure and Y2O3 on Al-based amorphous ribbon surface in MO solution degradation10.1016/j.molliq.2020.114318 ↗
8. Magnetic, electrical and plastic properties of Fe76Nb2Si13B9, Fe75Ag1Nb2Si13B9 and Fe75Cu1Nb2Si13B9 amorphous alloys10.1016/j.jallcom.2011.05.070 ↗
9. Kinetic study of non-isothermal crystallization in Fe78Si9B13 metallic glass10.1016/j.jallcom.2009.05.076 ↗
10. Magnetic properties of CoFeSiB powders, suspensions, and in rigid matrix10.1109/TMAG.2009.2033557 ↗
11. New Fe-based soft magnetic alloys composed of ultrafine grain structure10.1063/1.342149 ↗
12. Application of Fe78Si9B13 amorphous particles in magnetorheological fluids10.1039/C5RA24106E ↗
13. A practical anodic and cathodic curve intersection model to understand multiple corrosion potentials of Fe-based glassy alloys in OH− contained solutions
14. Ferrofluids based on Co-Fe-Si-B amorphous nanoparticles10.1016/j.apsusc.2016.12.145 ↗
15. Electro/magnetic shielding effectiveness of soft magnetic Fe80Nb6B14 amorphous alloy10.1016/j.jmatprotec.2008.05.026 ↗
16. Fe-based soft magnetic alloys composed of ultrafine grain structure10.2320/matertrans1989.31.307 ↗
17. Structure modification and recovery of amorphous Fe(73.5)Si(13.5)B9Nb3Cu1 magnetic ribbons after autoclave treatment: SAXS and thermodynamic analysis10.1016/j.jmst.2018.09.010 ↗
18. Crystallization, phase evolution and corrosion of Fe-based metallic glasses: an atomic-scale structural and chemical characterization study10.1016/j.actamat.2014.02.027 ↗
19. Severe corrosion behavior of Fe78Si9B13 glassy alloy under magnetic field10.1016/j.jnoncrysol.2014.03.030 ↗
20. Partial crystallization and corrosion resistance of amorphous Fe-Cr-M-B (M=Mo, Nb) alloys10.1016/j.jnoncrysol.2010.04.051 ↗
21. Corrosion behavior of Fe-based ferromagnetic (Fe, Ni)–B–Si–Nb bulk glassy alloys in aqueous electrolytes10.1016/j.jnoncrysol.2008.06.009 ↗
22. Unique corrosion behavior of Fe78Si9B13 glassy alloy with different circumferential speeds under various chloride ion levels10.1016/j.jallcom.2014.01.086 ↗
23. Design and characterization of a high-power induction module at megahertz repetition rate burst mode10.1016/j.nima.2007.06.016 ↗
24. Corrosion behavior of Cu-Zr-Ti-Nb bulk glassy alloys10.2320/matertrans.44.749 ↗
25. Corrosion-resistant amorphous Fe-C alloys containing chromium and/or molybdenum10.1016/0022-3093(79)90147-9 ↗
26. Bulk glassy Fe–Cr–Mo–C–B alloys with high corrosion resistance10.1016/S0010-938X(02)00002-1 ↗
27. Tailoring the corrosion behavior of Fe-based metallic glasses through inducing Nb-triggered netlike structure
28. Nb doping in laser-cladded Fe25Co25Ni25(B0.7Si0.3)25 high entropy alloy coatings: microstructure evolution and wear behavior10.1016/j.surfcoat.2020.126321 ↗
29. Optimization of thermal stability and soft-magnetic properties of FeSiBPCuNb alloys by Nb content tuning10.1016/j.jallcom.2014.11.042 ↗
30. Potentiodynamic and potentiostatic investigation on the passivation of Fe based glassy alloys in alkaline solution
31. Electrochemical frequency modulation and inductively coupled plasma atomic emission spectroscopy methods for monitoring corrosion rates and inhibition of low alloy steel corrosion in HCl solutions and a test for validity of the Tafel extrapolation method10.1016/j.corsci.2009.01.006 ↗
32. Testing validity of the Tafel extrapolation method for monitoring corrosion of cold rolled steel in HCl solutions – experimental and theoretical studies10.1016/j.corsci.2009.08.055 ↗
33. Corrosion behavior of monophasic and multiphasic Al50Au50 ribbons in AlCl3 + HCl solution10.1016/j.corsci.2019.108398 ↗
34. The influence of preparation conditions on the structural properties and hardness of diamond-like carbon films, prepared by plasma source ion implantation10.3390/coatings10040360 ↗
35. Micromechanical properties of steel corrosion products in concrete studied by nano-indentation technique
36. Nano-indentation investigation on the local softening of equiaxed zone in 2060-T8/2099-T83 aluminum-lithium alloys T-joints welded by double-sided laser beam welding10.1016/j.jallcom.2018.05.014 ↗
37. Low friction coefficient of superhard nc-TiC/a-C:H nanocomposite coatings deposited by filtered cathodic vacuum arc10.1088/2053-1591/ab2e9c ↗
38. Improving the glass formation ability and magnetic properties by Nb in Fe-Si-B-P-Cu-Nb nanocrystalline alloys10.1016/j.mseb.2020.114942 ↗
39. Semiconductor properties and protective role of passive films of iron base alloys10.1016/j.corsci.2006.05.020 ↗
40. Electrochemical corrosion behavior of nanocrystallized bulk 304 stainless steel10.1016/j.electacta.2006.06.023 ↗
41. Micro-electrochemical characterization and Mott–Schottky analysis of corrosion of welded X70 pipeline steel in carbonate/bicarbonate solution10.1016/j.electacta.2009.09.001 ↗
42. Electrochemical behaviour of passive film formed on the surface of Ti-6Al-4V alloys fabricated by electron beam melting10.1016/j.corsci.2018.09.010 ↗
43. The effect of simulated concrete pore solution composition and chlorides on the electronic properties of passive films on carbon steel rebar10.1016/j.corsci.2016.01.027 ↗
44. The electronic structure of passive films formed on stainless steels10.1016/0010-938X(95)00084-W ↗
45. Corrosion mechanism of amorphous alloy strengthened stainless steel composite fabricated by selective laser melting10.1016/j.corsci.2019.108241 ↗
46. Passivation and electrochemical behavior of 316L stainless steel in chlorinated simulated concrete pore solution10.1016/j.apsusc.2016.12.180 ↗
47. The influence of silicate and sulphate anions on the anodic corrosion and the transpassivity of iron and silicon-rich steel in concentrated KOH solution10.1016/j.corsci.2012.07.019 ↗
48. The anodic surface film and hydrogen evolution on Mg10.1016/j.corsci.2015.05.047 ↗
49. Sol-gel/polyelectrolyte active corrosion protection system10.1002/adfm.200800630 ↗
50. The anodic dissolution of magnesium in chloride and sulphate solutions10.1016/S0010-938X(97)00090-5 ↗
51. Niobium addition enhancing the corrosion resistance of nanocrystalline Ti5Si3 coating in H2SO4 solution10.1016/j.actamat.2013.10.040 ↗
52. Effect of Nb on microstructure and high temperature oxidation resistance of austenitic heat resistant steel