journal article·2016-05

Characterization of structural, thermal and mechanical properties of bismuth silicate glasses

B. Bochentyn, A. Warych, N. Szreder, A. Mielewczyk-Gryń, J. Karczewski, M. Prześniak-Welenc, M. Gazda, B. Kusz

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Abstract

Abstract The influence of heating and reduction processes on the structural, thermal and mechanical properties of bismuth-silicate glasses has been investigated. Two compositions of glasses: 40Bi2O3–60SiO2 (Bi0.57Si0.43Ox) and 27Bi2O3–73SiO2 (Bi0.43Si0.57Ox) were fabricated by a typical melt quenching technique. Then the reduction in hydrogen at 380 °C for 20, 42 or 67 h was performed. It was found that a 50 μm-thick layer was formed on the glass surface after reduction process. It was confirmed that this layer is formed by granules of metallic bismuth embedded in a glass matrix. The DSC measurements confirmed that melting of metallic bismuth takes place during heating of a previously reduced glass sample. It was also found that heat treatment process influences hardness and Young modulus of Bi–Si–O glass.
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Research context

OpenAlex topics: Glass properties and applications · Nuclear materials and radiation effects · Advanced ceramic materials synthesis

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