journal article·2009-07Open access

Some considerations to optimize the synthesis procedure and the structural quality of mesostructured silicas

Verónica R. Elías, Mónica E. Crivello, Eduardo R. Herrero, Sandra G. Casuscelli, Griselda A. Eimer

Journal of Non-Crystalline Solids· Volume 355· Issue 22-23

Abstract

Two methods for the preparation of highly ordered MCM-41 silica are discussed. The quality of the structure was optimized by adequate stirring of the reaction mixture containing low concentration of surfactant, followed by heating at 70 °C for 3 h under stirring. Besides this energetically favorable procedure allowed to obtain structures very stable upon calcination. The role of the ethanol and the hydroxide source in the synthesis process is also analyzed.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Mesoporous Materials and Catalysis · Zeolite Catalysis and Synthesis · Polyoxometalates: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (43)

Show source-provided references
1. Soler-Illia · Chem. Rev. · 2002 · 102 · 409310.1021/cr0200062 ↗
2. Loy · Chem. Rev. · 1995 · 95 · 143110.1021/cr00037a013 ↗
3. Yanagiswa · Bull. Chem. Soc. Jpn. · 1990 · 63 · 98810.1246/bcsj.63.988 ↗
4. J. Beck, C. Chu, I. Johnson, C. Kresge, M. Leonowicz, W. Roth, J. Vartuli, WO 91/11390, 1991.
5. Kresge · Nature · 1992 · 359 · 71010.1038/359710a0 ↗
6. Beck · J. Am. Chem. Soc. · 1992 · 114 · 1083410.1021/ja00053a020 ↗
7. Inagaki · J. Chem. Soc. Chem. Commun. · 1993 · 68010.1039/c39930000680 ↗
8. Vartuli · Chem. Mater. · 1994 · 6 · 231710.1021/cm00048a018 ↗
9. Tanev · Science · 1995 · 271 · 126710.1126/science.271.5253.1267 ↗
10. Bagshaw · Science · 1995 · 269 · 124210.1126/science.269.5228.1242 ↗
11. Schmidt · Micropor. Mater. · 1995 · 3 · 44310.1016/0927-6513(94)00055-Z ↗
12. Corma · Chem. Rev. · 1997 · 97 · 237310.1021/cr960406n ↗
13. Schüth · Adv. Mater. · 2002 · 14 · 62910.1002/1521-4095(20020503)14:9<629::AID-ADMA629>3.0.CO;2-B ↗
14. Vallet-Regi · Chem. Mater. · 2001 · 13 · 30810.1021/cm0011559 ↗
15. Koch · Micropor. Mesopor. Mater. · 1998 · 25 · 12710.1016/S1387-1811(98)00184-X ↗
16. Hoppe · Micropor. Mater. · 1997 · 8 · 26710.1016/S0927-6513(96)00085-5 ↗
17. Wu · Science · 1994 · 264 · 1756
18. Moller · Chem. Mater. · 1998 · 10 · 295010.1021/cm980243e ↗
19. Wu · Chem. Mater. · 1994 · 6 · 110910.1021/cm00044a008 ↗
20. Stucky · Mol. Cryst. Lyq. Cryst. · 1994 · 240 · 18710.1080/10587259408029730 ↗
21. Chen · Micropor. Mater. · 1995 · 4 · 110.1016/0927-6513(94)00077-9 ↗
22. Cheng · Langmuir · 1995 · 11 · 281510.1021/la00007a075 ↗
23. Inagaki · Bull. Chem. Soc. Jpn. · 1996 · 69 · 144910.1246/bcsj.69.1449 ↗
24. Huo · Chem. Mater. · 1996 · 8 · 114710.1021/cm960137h ↗
25. Huo · Nature · 1994 · 368 · 31710.1038/368317a0 ↗
26. Huo · Science · 1995 · 208 · 132410.1126/science.268.5215.1324 ↗
27. Liu · J. Col. Int. Sci. · 2008 · 319 · 37710.1016/j.jcis.2007.11.025 ↗
28. Grün · Micropor. Mesopor. Mater. · 1999 · 27 · 20710.1016/S1387-1811(98)00255-8 ↗
29. Eimer · Appl. Catal. · 2006 · 298 · 23210.1016/j.apcata.2005.10.006 ↗
30. Eimer · Catal. Today · 2008 · 133 · 63910.1016/j.cattod.2007.12.096 ↗
31. Gallis · Chem. Mater. · 1995 · 9 · 203510.1021/cm970482m ↗
32. Landry · Chem. Mater. · 2001 · 13 · 160010.1021/cm000373z ↗
33. Monnier · Science · 1993 · 261 · 129910.1126/science.261.5126.1299 ↗
34. Huo · Chem. Mater. · 1997 · 9 · 1410.1021/cm960464p ↗
35. Iler · 1979 · vol. 680
36. Cundy · Micropor. Mesopor. Mater. · 2007 · 66 · 14310.1016/j.micromeso.2003.08.021 ↗
37. Laha · Micropor. Mesopor. Mater. · 2002 · 53 · 16310.1016/S1387-1811(02)00337-2 ↗
38. Murata · Catal. Today · 2004 · 91/91 · 3910.1016/j.cattod.2004.03.006 ↗
39. Gregg · 1982
40. Barret · J. Am. Chem. Soc. · 1951 · 73 · 37310.1021/ja01145a126 ↗
41. Landau · Micropor. Mesopor. Mater. · 1999 · 33 · 14910.1016/S1387-1811(99)00133-X ↗
42. Eimer · Catal. Commun. · 2003 · 4 · 11810.1016/S1566-7367(03)00008-6 ↗
43. Eimer · Catal. Lett. · 2002 · 78 · 110.1023/A:1014924332500 ↗