journal article·2015-11

Influence of niobium on laser de-vitrification of Fe–Si–B based amorphous magnetic alloys

Talukder Alam, Tushar Borkar, Sameehan S. Joshi, Shravan Katakam, X. Chen, Narendra B. Dahotre, Raju V. Ramanujan, Rajarshi Banerjee

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Abstract

Abstract Laser annealing of Fe77.5Si13.5B9 and Fe76.5Si13.5B9Cu1 amorphous melt-spun ribbons was carried out. In both alloys, it was found that devitrification occurred, leading to the nucleation of a high density of refined α-Fe(Si) nanocrystals within the amorphous matrix. Interestingly, when laser processed under identical conditions, Fe74.5Si13.5B9Nb3, and Fe73.5Si13.5B9Nb3Cu1 (FINEMET) amorphous melt-spun ribbons did not exhibit devitrification or copper clustering. Differences in the magnetic properties were observed, with the Fe77.5Si13.5B9 and Fe76.5Si13.5B9Cu1 alloys exhibiting higher saturation magnetization (MS) and higher coercivity (HC) values while Fe74.5Si13.5B9Nb3, and Fe73.5Si13.5B9Nb3Cu1 alloys exhibited lower values of both these properties. These results clearly reveal the enhanced stability of the amorphous phase due to the addition of Nb in Fe–Si–B based melt-spun samples.
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Research context

OpenAlex topics: Metallic Glasses and Amorphous Alloys · High Entropy Alloys Studies · Mineralogy and Gemology Studies

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References (31)

Show source-provided references
1. A study of the crystallization behavior of an amorphous Fe 77.5 Si 13.5 B 9 alloy
2. Crystallization of glassy Fe 80 B 20-x Si x (0⩽ x⩽ 12) alloys10.1016/0304-8853(92)90064-U ↗
3. Nucleation kinetics of primary crystallization products in FeSiB metallic glasses10.1007/BF01151830 ↗
4. Crystallization characterisics in the Fe Si B glassy ribbon system10.1016/S0921-5093(96)10567-0 ↗
5. New position sensor based on ultraacoustic standing waves in FeSiB amorphous wires10.1016/S0924-4247(99)00081-3 ↗
6. Solid state dendrite formation in an amorphous magnetic Fe 77.5 Si 13.5 B 9 alloy observed by in situ hot stage transmission electron microscopy10.1063/1.2201049 ↗
7. Grain size dependence of coercivity and permeability in nanocrystalline ferromagnets10.1109/20.104389 ↗
8. Nanocrystalline soft magnetic alloys10.1016/S1567-2719(97)10007-5 ↗
9. New Fe-based soft magnetic alloys composed of ultrafine grain structure10.1063/1.342149 ↗
10. Cu clustering and Si partitioning in the early crystallization stage of an Fe 73.5 Si 13.5 B 9 Nb 3 Cu 1 amorphous alloy10.1016/S1359-6454(98)00392-9 ↗
11. Small-angle neutron scattering and differential scanning calorimetry studies on the copper clustering stage of Fe–Si–B–Nb–Cu nanocrystalline alloys10.1016/S1359-6454(00)00277-9 ↗
12. Atom probe study of the crystallization process of an Fe 73.5 Si 13.5 B 9 Nb 3 Cu 1 amorphous alloy10.1016/0169-4332(93)90344-B ↗
13. Atom probe studies of nanocrystalline microstructural evolution in some amorphous alloys10.2320/matertrans1989.36.909 ↗
14. On the formation of nanocrystals in the soft magnetic alloy Fe 73.5 Nb 3 Cu 1 Si 13.5 B 910.1016/S1359-6454(97)00436-9 ↗
15. A model for nucleation of nanocrystals in the soft magnetic alloy Fe 73.5 Nb 3 Cu 1 Si 13.5 B 910.1016/S0965-9773(97)00091-3 ↗
16. Microstructural observations of the crystallization of amorphous Fe–Si–B based magnetic alloys10.1016/j.tsf.2005.10.016 ↗
17. Micromagnetic theory of phase transitions in inhomogeneous ferromagnets III. Non-local Landau–Ginzburg theory10.1002/pssb.2221010233 ↗
18. Atom probe tomography study of ultrahigh nanocrystallization rates in FeSiNbBCu soft magnetic amorphous alloys on rapid annealing10.1016/j.actamat.2014.01.031 ↗
19. Influence of Nb on the first stage of crystallization in Fe 86−×Nb×B 14 amorphous alloys10.1016/j.msea.2004.05.013 ↗
20. Laser-induced thermal and spatial nanocrystallization of amorphous Fe–Si–B alloy10.1016/j.scriptamat.2011.12.028 ↗
21. Stress-induced selective nano-crystallization in laser-processed amorphous Fe–Si–B alloys10.1080/09500839.2012.704416 ↗
22. Improved soft magnetic properties by laser de-vitrification of Fe–Si–B amorphous magnetic alloys10.1016/j.matlet.2014.02.002 ↗
23. Laser assisted crystallization of ferromagnetic amorphous ribbons: a multimodal characterization and thermal model study10.1063/1.4829279 ↗
24. Laser patterning of Fe–Si–B amorphous ribbons in magnetic field10.1007/s00339-014-8512-2 ↗
25. Katakam · 2014
26. Rapid tooling by laser powder deposition: process simulation using finite element analysis10.1016/j.actamat.2005.05.003 ↗
27. 1997
28. An experimentally based thermo-kinetic hardening model for high power direct diode laser cladding10.1016/j.jmatprotec.2011.02.006 ↗
29. Kannatey-Asibu · 2009 · vol. 4
30. Comparison of the crystallization behavior of Fe–Si–B–Cu and Fe–Si–B–Cu–Nb–based amorphous soft magnetic alloys10.1007/s11661-014-2239-8 ↗
31. Modern soft magnets: amorphous and nanocrystalline materials10.1016/j.actamat.2012.10.040 ↗