Influence of manganese ions on spectroscopic and dielectric properties of LiF-SrO-B2O3 glasses

Abstract Transparent glasses, obtained through melt quenching technique, with composition 30LiF-10SrO-(60-x)B 2 O 3 -xMnO, with 0 ≤ x ≤ 3 mol% (x = 0, 1, 1.5, 2, 2.5 and 3), were characterized by X-ray diffraction (XRD) and then they were analyzed for physical, spectroscopic studies (optical absorption, electron spin resonance (ESR) and FTIR) and dielectric properties (dielectric constant e′, loss tanδ and conductivity σ ac etc.). The results were analyzed and correlated with each other in the light of local environment and oxidation states of manganese ion in the glass network. The increase in the area of optical absorption peak and ESR signal intensity indicate that both Mn 2+ and Mn 3+ ions exist in octahedral symmetry are increased with increasing MnO dopant in the glass matrix. The semi conducting nature of the glass network is found to increase due to the considerable increase in BO 3 , MnO 6 structural units whenever B 2 O 3 in the host glass is gradually replaced by MnO.