Nanocrystallization of fresnoite glass. II. Analysis of homogeneous nucleation kinetics

Abstract We analyzed internal (homogeneous) nucleation rates in an almost stoichiometric fresnoite (2BaO · TiO 2 · 2SiO 2 ) glass using the classical nucleation theory (CNT) with experimental viscosity data and calculated thermodynamic quantities. Assuming, first, that the nucleus-melt surface energy is size and temperature-independent, σ ≡ σ ∞ , the CNT offered a good description of the temperature dependence of the steady-state nucleation rate I st ( T ) over a wide temperature range, above and below T g , but failed to predict the pre-exponential factor, confirming previous tests performed on other silicate glasses. The congruence between theory and experiment was restored with a (fitted) temperature-dependent σ . The main thermodynamic and kinetic parameters of the CNT were investigated to explain the extremely high nucleation rates measured in this glass: I max ∼ 10 16 m −3 s −1 ( T max ≈ 740 °C, T g ≈ 710 °C). The viscosity at T max was found to be quite close to that of other silicate glasses that display homogeneous nucleation, such as Na 2 O · 2CaO · 3SiO 2 and 2Na 2 O · CaO · 3SiO 2 . Therefore, the lowest thermodynamic barrier for nucleation in fresnoite glass, as compared with other silicate glasses, is responsible for these high crystal nucleation rates.