DataVXJournal of Nanoparticle ResearchPaper
journal article·2026-02

Synthesis, characterizations, dielectric, and thermal conductivity analysis of acid and amine functionalized graphene oxide nanostructures

Devendra Patel, Shyama Prasad Mahapatra

Journal of Nanoparticle Research· Volume 28· Issue 2
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Nanomaterials

OpenAlex topics: Thermal properties of materials · Power Transformer Diagnostics and Insulation · Graphene research and applications

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References (75)

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1. Ghadei SK, Sankaran KJ, Sakthivel R (2025) Hybrid nano-interfacial engineering of special-wettable surfaces for advanced oil/water separation: multifunctional strategies and future directions. Results Surf Interfaces 19:100526. https://doi.org/10.1016/J.RSURFI.2025.10052610.1016/J.RSURFI.2025.100526 ↗
2. Stehle YY, Barnum TJ, Schujman S et al (2025) Plasma-induced tailoring of graphene oxide surfaces for electrochemical applications: functionalization and etching. ACS Appl Electron Mater 7:6635–6645. https://doi.org/10.1021/acsaelm.5c0093910.1021/acsaelm.5c00939 ↗
3. Sun L, yue, Yu D hao, Yang L et al (2022) Improvements in multifunctional graphene oxide-based separation membranes: mechanism, modification and properties. Mater Today Commun 33:104274. https://doi.org/10.1016/J.MTCOMM.2022.10427410.1016/J.MTCOMM.2022.104274 ↗
4. Pasindu V, Yapa P, Dabare S, Munaweera I (2025) Multifunctional transition metal oxide/graphene oxide nanocomposites for catalytic dye degradation, renewable energy, and energy storage applications. RSC Adv 15:33162–33186. https://doi.org/10.1039/D5RA04806K10.1039/D5RA04806K ↗
5. Sahoo S, Bhuyan M, Sahoo D (2023) Tuning of dielectric and magnetic performance of graphene oxide via defect regulation by metal oxide nanoparticle for high temperature device. J Alloys Compd 935:168097. https://doi.org/10.1016/J.JALLCOM.2022.16809710.1016/J.JALLCOM.2022.168097 ↗
6. Addayeva Z, Muradov M, Eyvazova G et al (2025) Effect of temperature and AC field duration on the dielectric behavior of PVA/GO/FeGaInS 4 nanocomposites. RSC Adv 15:49307–49319. https://doi.org/10.1039/D5RA06744H10.1039/D5RA06744H ↗
7. Ahamad T, Ahmed AS (2023) Influence of graphene oxide on the dielectric properties of biogenically synthesized ZnO nanoparticles. Hybrid Advances 3:100059. https://doi.org/10.1016/J.HYBADV.2023.10005910.1016/J.HYBADV.2023.100059 ↗
8. Ramamoorthy H, Buapan K, Chiawchan T et al (2021) Exploration of the temperature-dependent correlations present in the structural, morphological and electrical properties of thermally reduced free-standing graphene oxide papers. J Mater Sci 56:15134–15150. https://doi.org/10.1007/s10853-021-06262-w10.1007/s10853-021-06262-w ↗
9. Liu J, Chen S, Liu Y, Zhao B (2022) Progress in preparation, characterization, surface functional modification of graphene oxide: a review. J Saudi Chem Soc 26:101560. https://doi.org/10.1016/J.JSCS.2022.10156010.1016/J.JSCS.2022.101560 ↗
10. Mushahary N, Sarkar A, Basumatary F et al (2024) Recent developments on graphene oxide and its composite materials: from fundamentals to applications in biodiesel synthesis, adsorption, photocatalysis, supercapacitors, sensors and antimicrobial activity. Results Surf Interfaces 15:100225. https://doi.org/10.1016/J.RSURFI.2024.10022510.1016/J.RSURFI.2024.100225 ↗
11. Kumar P, Penta S, Mahapatra SP (2020) Synthesis and dielectric relaxation spectroscopy of graphene oxide nanoparticles: effects of frequency, thickness, and temperature. J Electron Mater 49:5801–5807. https://doi.org/10.1007/s11664-020-08355-910.1007/s11664-020-08355-9 ↗
12. Ghosh TN, Bhunia AK, Pradhan SS et al (2024) 2D nanomaterial–polymer composite: optical and structural properties along with room temperature enhanced dielectric response and magnetic behaviour of graphene oxide doped polyvinylpyrrolidone nanocomposites. J Mater Sci Mater Electron 35:1124. https://doi.org/10.1007/s10854-024-12881-110.1007/s10854-024-12881-1 ↗
13. Ghosh TN, Bhunia AK, Pradhan SS, Sarkar SK (2020) Electric modulus approach to the analysis of electric relaxation and magnetodielectric effect in reduced graphene oxide–poly(vinyl alcohol) nanocomposite. J Mater Sci Mater Electron 31:15919–15930. https://doi.org/10.1007/s10854-020-04153-510.1007/s10854-020-04153-5 ↗
14. Sharma A, Khanal S, Suvedi D et al (2026) The role of nanofluids in enhancing thermal management and biomedical applications: a review. Therm Sci Eng Prog 69:104437. https://doi.org/10.1016/J.TSEP.2025.10443710.1016/J.TSEP.2025.104437 ↗
15. Bansal A, Sharma GP, Singh R (2023) Thermal properties of graphene oxide nanofluids. Indian J Phys 97:3003–3010. https://doi.org/10.1007/s12648-023-02671-610.1007/s12648-023-02671-6 ↗
16. Zhang H, Wang S, Lin Y et al (2017) Stability, thermal conductivity, and rheological properties of controlled reduced graphene oxide dispersed nanofluids. Appl Therm Eng 119:132–139. https://doi.org/10.1016/j.applthermaleng.2017.03.06410.1016/j.applthermaleng.2017.03.064 ↗
17. Shahriary L, Athawale AA (2014) Graphene oxide synthesized by using modified Hummers approach. Int J Renew Energy Environ Eng 2:58–63
18. Peng S, Liu C, Fan X (2015) Surface modification of graphene oxide by carboxyl-group: preparation, characterization, and application for proteins immobilization. Integr Ferroelectr 163:42–53. https://doi.org/10.1080/10584587.2015.104032810.1080/10584587.2015.1040328 ↗
19. Jeyaseelan A, Ghfar AA, Naushad Mu, Viswanathan N (2021) Design and synthesis of amine functionalized graphene oxide for enhanced fluoride removal. J Environ Chem Eng 9:105384. https://doi.org/10.1016/j.jece.2021.10538410.1016/j.jece.2021.105384 ↗
20. Sharma G, Khullar V, Soni S (2023) Experimental analysis of stability, thermal conductivity and photothermal behaviour of amine functionalised graphene oxide nanofluid. J Mater Res 38:4465–4476. https://doi.org/10.1557/s43578-023-01160-010.1557/s43578-023-01160-0 ↗
21. Ai F, Zhong Y, Hu X, Yan X (2016) Characterization on the exfoliation degree of graphite oxide into graphene oxide by UV-visible spectroscopy. J Wuhan Univ Technol-Mater Sci Ed 31:515–518. https://doi.org/10.1007/s11595-016-1401-010.1007/s11595-016-1401-0 ↗
22. Rattana CS, Witit-anun N et al (2012) Preparation and characterization of graphene oxide nanosheets. Procedia Eng 32:759–764. https://doi.org/10.1016/j.proeng.2012.02.00910.1016/j.proeng.2012.02.009 ↗
23. M. D. P, S. CF, Gnanamani A (2018) Preparation, characterization and reusability efficacy of amine-functionalized graphene oxide-polyphenol oxidase complex for removal of phenol from aqueous phase. RSC Adv 8:38416–38424. https://doi.org/10.1039/C8RA06364H10.1039/C8RA06364H ↗
24. Brusko V, Khannanov A, Rakhmatullin A, Dimiev AM (2024) Unraveling the infrared spectrum of graphene oxide. Carbon N Y 229:119507. https://doi.org/10.1016/j.carbon.2024.11950710.1016/j.carbon.2024.119507 ↗
25. Zhang C, Dabbs DM, Liu L-M et al (2015) Combined effects of functional groups, lattice defects, and edges in the infrared spectra of graphene oxide. J Phys Chem C 119:18167–18176. https://doi.org/10.1021/acs.jpcc.5b0272710.1021/acs.jpcc.5b02727 ↗
26. Kumar R, Kumar M, Kumar A et al (2019) Surface modification of graphene oxide using esterification. Mater Today Proc 18:1556–1561. https://doi.org/10.1016/j.matpr.2019.06.62610.1016/j.matpr.2019.06.626 ↗
27. Stobinski L, Lesiak B, Malolepszy A et al (2014) Graphene oxide and reduced graphene oxide studied by the XRD, TEM and electron spectroscopy methods. J Electron Spectrosc Relat Phenom 195:145–154. https://doi.org/10.1016/j.elspec.2014.07.00310.1016/j.elspec.2014.07.003 ↗
28. Luo D, Zhang X (2018) The effect of oxygen–containing functional groups on the H2 adsorption of graphene–based nanomaterials: experiment and theory. Int J Hydrogen Energy 43:5668–5679. https://doi.org/10.1016/j.ijhydene.2018.01.16410.1016/j.ijhydene.2018.01.164 ↗
29. Claramunt S, Varea A, López-Díaz D et al (2015) The importance of interbands on the interpretation of the raman spectrum of graphene oxide. J Phys Chem C 119:10123–10129. https://doi.org/10.1021/acs.jpcc.5b0159010.1021/acs.jpcc.5b01590 ↗
30. López-Díaz D, López Holgado M, García-Fierro JL, Velázquez MM (2017) Evolution of the raman spectrum with the chemical composition of graphene oxide. J Phys Chem C 121:20489–20497. https://doi.org/10.1021/acs.jpcc.7b0623610.1021/acs.jpcc.7b06236 ↗
31. Safie NE, Azam MA (2022) Understanding the structural properties of feasible chemically reduced graphene. AIMS Mater Sci 9:617–627. https://doi.org/10.3934/matersci.202203710.3934/matersci.2022037 ↗
32. Ghosh TN, Pradhan SS, Sarkar SK, Bhunia AK (2021) On the incorporation of the various reduced graphene oxide into poly(vinyl alcohol) nano-compositions: comparative study of the optical, structural properties and magnetodielectric effect. J Mater Sci Mater Electron 32:19157–19178. https://doi.org/10.1007/s10854-021-06435-y10.1007/s10854-021-06435-y ↗
33. Sharma N, Sharma V, Jain Y et al (2017) Synthesis and characterization of graphene oxide (GO) and reduced graphene oxide (rGO) for gas sensing application. Macromol Symp. https://doi.org/10.1002/masy.20170000610.1002/masy.201700006 ↗
34. Timochenco L, Costa-Almeida R, Bogas D et al (2021) High-yield production of nano-lateral size graphene oxide by high-power ultrasonication. Materials 14:1916. https://doi.org/10.3390/ma1408191610.3390/ma14081916 ↗
35. Rakshit S, Mondal KG, Kar BS et al (2025) Enhanced structural, optical and electrical properties of Cu2O and CuO nanoparticles for electrochemical energy storage devices. J Alloys Compd 1024:180274. https://doi.org/10.1016/j.jallcom.2025.18027410.1016/j.jallcom.2025.180274 ↗
36. Pelin M, Fusco L, León V et al (2017) Differential cytotoxic effects of graphene and graphene oxide on skin keratinocytes. Sci Rep 7:40572. https://doi.org/10.1038/srep4057210.1038/srep40572 ↗
37. Li J, Wang X, Mei K-C et al (2021) Lateral size of graphene oxide determines differential cellular uptake and cell death pathways in Kupffer cells, LSECs, and hepatocytes. Nano Today 37:101061. https://doi.org/10.1016/j.nantod.2020.10106110.1016/j.nantod.2020.101061 ↗
38. Rakshit S, Das SK, Samanta A et al (2025) Tuning structural, linear and nonlinear optical properties of chemically precipitated ZnO nanomaterials: efficient sunlight-driven photodegradation of methylene blue. J Mater Sci Mater Electron 36:1687. https://doi.org/10.1007/s10854-025-15778-910.1007/s10854-025-15778-9 ↗
39. Şenarslan E, Sağlam M (2024) Voltage-frequency dependence of the complex dielectric and electric modulus and the determination of the interface-state density distribution from the capacitance-frequency measurements of Al/p-Si/Al and Al/V2O5/p-Si/Al structures. Appl Phys A Mater Sci Process 130:641. https://doi.org/10.1007/s00339-024-07758-310.1007/s00339-024-07758-3 ↗
40. Chouhan H, Prasad S, Parida BN, Parida RK (2025) Enhanced transport, dielectric and magnetic properties of Ni-doped (YFeO 3) 0.5 (BaTiO 3) 0.5 perovskite for NTC thermistor and multifunctional applications. Mater Adv 6:4778–4794. https://doi.org/10.1039/D4MA01233J10.1039/D4MA01233J ↗
41. Singh S, Kaur A, Kaur P, Singh L (2023) High-temperature dielectric relaxation and electric conduction mechanisms in a LaCoO 3 -modified Na 0.5 Bi 0.5 TiO 3 system. ACS Omega 8:25623–25638. https://doi.org/10.1021/acsomega.3c0449010.1021/acsomega.3c04490 ↗
42. Altındal Yerişkin S, Taşçıoğlu İ, Badali Y (2024) Frequency-dependent dielectric, electric modulus, and ac conductivity features of Au/n-Si Schottky diodes (SDs) with PVC and (PVC:Graphite/Graphene-Oxide) interlayer. J Phys D Appl Phys 57:315104. https://doi.org/10.1088/1361-6463/ad456410.1088/1361-6463/ad4564 ↗
43. Sukdev MSP (2025) Structural, optical, and electrical response of MgO nanoparticles synthesized via co-precipitation method for electronic applications. J Mater Sci Mater Electron 36:1707. https://doi.org/10.1007/s10854-025-15769-w10.1007/s10854-025-15769-w ↗
44. Joshi S, Shukla A, Kumar N, Choudhary RNP (2025) Study of structural, morphological, dielectric, and magnetic properties of complex material for multifunctional applications. Eur Phys J Plus 140:959. https://doi.org/10.1140/epjp/s13360-025-06904-x10.1140/epjp/s13360-025-06904-x ↗
45. Yadav A, Sahoo S, Chin WK et al (2025) Synthesis, structural, dielectric, electrical, and magnetic characterization of Dysprosium orthoferrite nanoparticles. ACS Omega 10:36931–36945. https://doi.org/10.1021/acsomega.4c1009210.1021/acsomega.4c10092 ↗
46. Zhu L (2014) Exploring strategies for high dielectric constant and low loss polymer dielectrics. J Phys Chem Lett 5:3677–3687. https://doi.org/10.1021/jz501831q10.1021/jz501831q ↗
47. Hota SS, Panda D, Panda R et al (2025) Dielectric characteristics and energy storage capabilities of PVDF-based composite incorporating 2D GnP nanofiller. Results Eng 26:105593. https://doi.org/10.1016/j.rineng.2025.10559310.1016/j.rineng.2025.105593 ↗
48. Zhang J, Weng GJ, Xia X, Fang C (2020) A theory of frequency dependence and sustained high dielectric constant in functionalized graphene-polymer nanocomposites. Mech Mater 144:103352. https://doi.org/10.1016/j.mechmat.2020.10335210.1016/j.mechmat.2020.103352 ↗
49. Sun H, Zhang H, Liu S et al (2018) Interfacial polarization and dielectric properties of aligned carbon nanotubes/polymer composites: the role of molecular polarity. Compos Sci Technol 154:145–153. https://doi.org/10.1016/j.compscitech.2017.11.00810.1016/j.compscitech.2017.11.008 ↗
50. Lebda HI, Atyia HE, Habashy DM (2024) From experimentation to prediction: comprehensive study of dielectric properties through experimental research and theoretical modeling. J Mater Sci Mater Electron 35:1017. https://doi.org/10.1007/s10854-024-12746-710.1007/s10854-024-12746-7 ↗
51. Ranjan R, Kumar R, Kumar N et al (2011) Impedance and electric modulus analysis of Sm-modified Pb(Zr0.55Ti0.45)1–x/4O3 ceramics. J Alloys Compd 509:6388–6394. https://doi.org/10.1016/j.jallcom.2011.03.00310.1016/j.jallcom.2011.03.003 ↗
52. Ohki Y (2022) Broadband complex permittivity and electric modulus spectra for dielectric materials research. IEEJ Trans Electr Electron Eng 17:958–972. https://doi.org/10.1002/tee.2356510.1002/tee.23565 ↗
53. Behera B, Nayak P, Choudhary RNP (2007) Impedance spectroscopy study of NaBa2V5O15 ceramic. J Alloys Compd 436:226–232. https://doi.org/10.1016/j.jallcom.2006.07.02810.1016/j.jallcom.2006.07.028 ↗
54. Yakuphanoglu F (2007) Electrical conductivity and electrical modulus properties of α, ω-dihexylsexithiophene organic semiconductor. Phys B Condens Matter 393:139–142. https://doi.org/10.1016/j.physb.2006.12.07510.1016/j.physb.2006.12.075 ↗
55. Saji J, Khare A, Mahapatra SP (2015) Impedance and dielectric spectroscopy of nano-graphite reinforced silicon elastomer nanocomposites. Fibers Polym 16:883–893. https://doi.org/10.1007/s12221-015-0883-210.1007/s12221-015-0883-2 ↗
56. Majeed Khan MA, Siwach R, Kumar S et al (2021) Frequency and temperature dependence of dielectric permittivity/electric modulus, and efficient photocatalytic action of Fe-doped CeO2 NPs. J Alloys Compd 856:158127. https://doi.org/10.1016/j.jallcom.2020.15812710.1016/j.jallcom.2020.158127 ↗
57. Mubasher MM, Ali M (2021) Structural, dielectric and electric modulus studies of MnFe2O4/(MWCNTs)x nanocomposites. J Mater Eng Perform 30:4494–4503. https://doi.org/10.1007/s11665-021-05721-410.1007/s11665-021-05721-4 ↗
58. Sen S, Choudhary RNP (2004) Impedance studies of Sr modified BaZr0.05Ti0.95O3 ceramics. Mater Chem Phys 87:256–263. https://doi.org/10.1016/j.matchemphys.2004.03.00510.1016/j.matchemphys.2004.03.005 ↗
59. Koval V, Viola G, Zhang M et al (2024) Dielectric relaxation and conductivity phenomena in ferroelectric ceramics at high temperatures. J Eur Ceram Soc 44:2886–2902. https://doi.org/10.1016/j.jeurceramsoc.2023.12.01510.1016/j.jeurceramsoc.2023.12.015 ↗
60. Chiu F-C (2014) A review on conduction mechanisms in dielectric films. Adv Mater Sci Eng 2014:1–18. https://doi.org/10.1155/2014/57816810.1155/2014/578168 ↗
61. Ter-Ovanessian B, Galipaud J, Marcelin S et al (2024) Dielectric bi-layer model for electrochemical impedance spectroscopy characterisation of oxide film. Electrochim Acta 492:144307. https://doi.org/10.1016/j.electacta.2024.14430710.1016/j.electacta.2024.144307 ↗
62. Rehman A, Khalid M, Younas M et al (2025) Structural, dielectric, and impedance spectroscopic studies of (Zn0.4Mn0.4Ni0.2Ce0.2Fe1.8O4)1-x/(MWCNTs)x nanocomposites for energy storage applications. Ceram Int 51:6078–6090. https://doi.org/10.1016/j.ceramint.2024.12.05410.1016/j.ceramint.2024.12.054 ↗
63. Pattanayak S, Parida BN, Das PR, Choudhary RNP (2013) Impedance spectroscopy of Gd-doped BiFeO3 multiferroics. Appl Phys A Mater Sci Process 112:387–395. https://doi.org/10.1007/s00339-012-7412-610.1007/s00339-012-7412-6 ↗
64. Wang ZL, Tang DW, Liu S et al (2007) Thermal-conductivity and thermal-diffusivity measurements of nanofluids by 3ω method and mechanism analysis of heat transport. Int J Thermophys 28:1255–1268. https://doi.org/10.1007/s10765-007-0254-310.1007/s10765-007-0254-3 ↗
65. Singh A (2008) Thermal conductivity of nanofluids. Def Sci J 58:600–607. https://doi.org/10.14429/dsj.58.168210.14429/dsj.58.1682 ↗
66. Soltan YI, Nasser MS, Almomani F et al (2024) Thermal conductivity of different materials nanofluids nanofluids of MXenes, metal organic frameworks, and other nanostructured materials in heat transfer applications: review. J Mater Res Technol 31:2723–2761. https://doi.org/10.1016/j.jmrt.2024.07.02310.1016/j.jmrt.2024.07.023 ↗
67. Keklikcioglu Cakmak N (2020) The impact of surfactants on the stability and thermal conductivity of graphene oxide de-ionized water nanofluids. J Therm Anal Calorim 139:1895–1902. https://doi.org/10.1007/s10973-019-09096-610.1007/s10973-019-09096-6 ↗
68. Das NK, Santra S, Naik PK et al (2023) Evaluation of thermophysical properties and thermal performance of amine-functionalized graphene oxide/deep eutectic solvent nanofluids as heat-transfer media for desalination systems. ACS Sustain Chem Eng 11:5376–5389. https://doi.org/10.1021/acssuschemeng.2c0632510.1021/acssuschemeng.2c06325 ↗
69. Dai J, Zhai Y, Li Z, Wang H (2024) Mechanism of enhanced thermal conductivity of hybrid nanofluids by adjusting mixing ratio of nanoparticles. J Mol Liq 400:124518. https://doi.org/10.1016/j.molliq.2024.12451810.1016/j.molliq.2024.124518 ↗
70. Goyal M (2024) A model approach for determination of thermal conductivity variation in nanomaterials using Kapitza resistance effect. Phys B Condens Matter 677:415727. https://doi.org/10.1016/j.physb.2024.41572710.1016/j.physb.2024.415727 ↗
71. Shafiq A, Iqbal MA, Sindhu TN et al (2025) Synthesis, thermophysical behavior, and environmental implications of nanofluids: a comprehensive review. Results in Engineering 28:107763. https://doi.org/10.1016/j.rineng.2025.10776310.1016/j.rineng.2025.107763 ↗
72. Filho RSR, Brites CDS, He R et al (2025) Thermal diffusivity of nanofluids: a simplified temperature oscillation approach. Physics of Fluids 37:. https://doi.org/10.1063/5.025204410.1063/5.0252044 ↗
73. Djentoe YG, Widiasto FY, Effendi HTD et al (2025) Synergistic thermal and surface area properties of Al2O3–TiO2/water hybrid nanofluids. Case Stud Chem Environ Eng 11:101102. https://doi.org/10.1016/j.cscee.2025.10110210.1016/j.cscee.2025.101102 ↗
74. Esfahani MR, Languri EM, Nunna MR (2016) Effect of particle size and viscosity on thermal conductivity enhancement of graphene oxide nanofluid. Int Commun Heat Mass Transfer 76:308–315. https://doi.org/10.1016/j.icheatmasstransfer.2016.06.00610.1016/j.icheatmasstransfer.2016.06.006 ↗
75. Nguyen Q, Rizvandi R, Karimipour A et al (2020) A novel correlation to calculate thermal conductivity of aqueous hybrid graphene oxide/silicon dioxide nanofluid: synthesis, characterizations, preparation, and artificial neural network modeling. Arab J Sci Eng 45:9747–9758. https://doi.org/10.1007/s13369-020-04885-w10.1007/s13369-020-04885-w ↗